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61. 发明申请

US20060052550A1 Method for the production of tetrahydrofuran copolymers 失效
公开(公告)号：US20060052550A1
公开(公告)日：2006-03-09
申请号：US10537962
申请日：2003-12-16
申请人： Martin Haubner , Rolf Pinkos
发明人： Martin Haubner , Rolf Pinkos
IPC分类号： C08G59/14
CPC分类号： C08G65/20 , C08G65/2666
摘要： The present invention provides a process for preparing polyoxyalkylene glycols of a certain molecular weight in one stage by copolymerizing tetrahydrofuran and alpha,omega-diols as the comonomer in the presence of a heteropolyacid and of a hydrocarbon, by distilling off a mixture of water and this hydrocarbon from the copolymerization, which comprises terminating the polymerization when this molecular weight is attained by adding water, comonomer, butanediol or butanediol-water mixtures.

62. 发明申请

US20050176972A1 Catalytic hydrogenation over rhenium-containing catalysts supported on activated carbon 失效
标题翻译：通过负载在活性炭上的含铼催化剂进行催化氢化
公开(公告)号：US20050176972A1
公开(公告)日：2005-08-11
申请号：US11104408
申请日：2005-04-13
申请人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Schunk , Joachim Wulff-Doring , Frank Stein , Thomas Nobel , Sylvia Huber
发明人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Schunk , Joachim Wulff-Doring , Frank Stein , Thomas Nobel , Sylvia Huber
IPC分类号： B01J21/18 , B01J23/656 , B01J23/89 , C07C29/17 , C07D307/26 , C07C31/18
CPC分类号： C07C29/177 , B01J21/18 , B01J23/6567 , B01J23/8986 , C07C2601/20 , C07C31/207 , C07C31/20 , C07C31/133
摘要： In a process for preparing alcohols by catalytic hydrogenation of carbonyl compounds over a catalyst comprising rhenium on activated carbon, the catalyst used comprises rhenium (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5, platinum (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5 and, if appropriate, at least one further metal selected from among Zn, Cu, Ag, Au, Ni, Fe, Ru, Mn, Cr, Mo, W and V in a weight ratio to the activated carbon of from 0 to 0.25, and the activated carbon has been nonoxidatively pretreated. It is also possible to prepare ethers and lactones if the hydrogen pressure is not more than 25 bar. In this case, the activated carbon in the catalyst may also have been nonoxidatively pretreated.
摘要翻译：在通过羰基化合物催化氢化羰基化合物的方法中，所用的催化剂包括铼在活性炭上的催化剂，所用的催化剂包括铼（以金属计）与活性炭的重量比为0.0001至0.5，铂（以金属计算），活性炭的重量比为0.0001〜0.5，如果合适，选自Zn，Cu，Ag，Au，Ni，Fe，Ru，Mn，Cr，Mo，W和V中的至少一种以上的金属活性炭的重量比为0至0.25，并且活性炭已经被非氧化预处理。如果氢气压力不超过25巴，也可制备醚和内酯。在这种情况下，催化剂中的活性炭也可以被非氧化预处理。

63. 发明授权

US06673920B2 Method for the production of N-alkenyl-amides 失效
标题翻译：制备N-烯基酰胺的方法
公开(公告)号：US06673920B2
公开(公告)日：2004-01-06
申请号：US10168211
申请日：2002-06-19
申请人： Thomas Preiss , Arnd Böttcher , Rolf Pinkos , Rudolf Erich Lorenz
发明人： Thomas Preiss , Arnd Böttcher , Rolf Pinkos , Rudolf Erich Lorenz
IPC分类号： C07D22310
CPC分类号： C07D207/267 , C07C231/08 , C07D211/76 , C07D223/10
摘要： A process for preparing N-alkenyl-amides by reacting the corresponding NH-amides with acetylenes in the liquid phase in the presence of basic alkali metal compounds and of a cocatalyst comprises using as the cocatalyst diols of the general formula (I) where X is branched or unbranched alkylene selected from the group consisting of where R1 to R6 are independently hydrogen or C1- to C4-alkyl; or branched or unbranched cyclic alkylene of 3 to 14 carbon atoms including 3 to 12 ring carbon atoms, their monoalkenyl ethers, their dialkenyl ethers or mixtures thereof.
摘要翻译：在碱性碱金属化合物和助催化剂存在下，通过使液相中相应的NH-酰胺与乙炔反应来制备N-烯基酰胺的方法包括使用通式（I）的助催化剂二醇，其中X支化或非支链的亚烷基，其中R 1至R 6独立地为氢或C 1至C 4 - 烷基;包含3至12个环碳原子的3至14个碳原子的支链或非支链环状亚烷基，它们的单链烯基醚，它们的二链烯基醚或其混合物。

64. 发明授权

US06303836B1 Method for producing 2-cyclododecyl-1-propanol 失效
标题翻译： 2-环十二烷基-1-丙醇的制备方法
公开(公告)号：US06303836B1
公开(公告)日：2001-10-16
申请号：US09424258
申请日：1999-12-01
申请人： Klaus Ebel , Rolf Pinkos
发明人： Klaus Ebel , Rolf Pinkos
IPC分类号： C07C3520
CPC分类号： C07C51/353 , C07C29/149 , C07C67/347 , C07C2601/20 , C07C53/134 , C07C69/608 , C07C31/133
摘要： 2-Cyclododecyl-propanol [sic], which is in demand as musk scent, is prepared in an advantageous industrial process by reacting cyclododecene with an excess of propionic acid or of a propionic acid derivative in the presence of catalytic amounts of a free-radical initiator, and subsequently catalytically hydrogenating the 2-cyclododecylpropionic acid which is formed or the corresponding 2-cyclododecylpropionic acid derivatives.
摘要翻译：在有利的工业过程中，通过使环十二烯与过量的丙酸或丙酸衍生物在催化量的自由基存在下反应制备作为麝香香味的2-环十二烷基 - 丙醇[sic] 引发剂，随后催化氢化形成的2-环十二烷基丙酸或相应的2-环十二烷基丙酸衍生物。

65. 发明授权

US06284917B1 Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores 有权
公开(公告)号：US06284917B1
公开(公告)日：2001-09-04
申请号：US09581843
申请日：2000-06-19
申请人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
发明人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
IPC分类号： C07C6974
CPC分类号： C08K5/12 , C07C51/36 , C07C67/303 , C07C69/75 , C07C2601/14 , C07C61/09
摘要： A process for hydrogenating a benzenepolycarboxylic acid or a derivative thereof or a mixture of two or more thereof by bringing the benzenepolycarboxylic acid or the derivative thereof or the mixture of two or more thereof into contact with a hydrogen-containing gas is carried out in the presence of a catalyst which comprises as active metal at least one metal of transition group VIII of the Periodic Table alone or together with at least one metal of transition group I or VII of the periodic table applied to a support which contains macropores with the proviso that if dimethyl terephthalate is hydrogenated, the hydrogenation using a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table applied to a support, where the support has a mean pore diameter of at least 50 nm and a BET surface area of at most 30 m2/g and the amount of the active metal is from 0.01 to 30% by weight, based on the total weight of the catalyst, and the ratio of the surface areas of the active metal and the catalyst support is less than 0.05, and/or a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a support, where from 10 to 50% of the pore volume of the support is formed by macropores having a pore diameter in the range from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support is formed by mesopores having a pore diameter in the range from 2 to 50 nm, where the sum of the pore volumes adds up to 100%, is excluded, and novel hydrogenation products, obtainable by hydrogenating benzenepolycarboxylic acid (derivatives) as well as their use as plasticizers in plastics.

66. 发明授权

US06262317B1 Process for preparing 1,4-butanediol by catalytic hydrogenation of 1,4-butinediol 有权
标题翻译：通过1,4-丁二醇的催化氢化制备1,4-丁二醇的方法
公开(公告)号：US06262317B1
公开(公告)日：2001-07-17
申请号：US09284209
申请日：1999-04-09
申请人： Rainer Becker , Franz Josef Bröcker , Gerd Kaibel , Rolf Pinkos , Joachim Wulff-Döring
发明人： Rainer Becker , Franz Josef Bröcker , Gerd Kaibel , Rolf Pinkos , Joachim Wulff-Döring
IPC分类号： C07C2700
CPC分类号： C07C29/172 , B01J8/025 , B01J8/0278 , B01J8/06 , B01J8/065 , B01J19/006 , B01J19/2465 , B01J19/249 , B01J19/26 , B01J2208/00283 , B01J2208/021 , B01J2219/00103 , B01J2219/0011 , B01J2219/00777 , B01J2219/185 , B01J2219/1943 , B01J2219/2462 , B01J2219/2469 , B01J2219/2474 , B01J2219/2477 , B01J2219/2479 , B01J2219/2481 , B01J2219/30 , B01J2219/30475 , C07C31/207
摘要： A process for preparing 1,4-butanediol by continuous catalytic hydrogenation of 1,4-butynediol comprises reacting 1,4-butynediol with hydrogen in the liquid continuous phase in the presence of a heterogeneous hydrogenation catalyst at from 20 to 300° C., a pressure of from 1 to 200 bar and values of the liquid-side volumetric mass transfer coefficient kLa of from 0.1 s−1 to 1 s−1 a) using a catalyst suspended in the reaction medium, where if a packed bubble column is employed this is operated in the upflow mode and at a ratio of gas leaving the reaction vessel to gas fed to the reaction vessel of from 0.99:1 to 0.4:1, or b) passing the liquid and gas in cocurrent in an upward direction through a fixed-bed reactor operated in the gas-circulation mode while maintaining a ratio of the gas fed to the reaction vessel to gas leaving the reaction vessel of from 0.99:1 to 0.4:1.
摘要翻译：通过1,4-丁炔二醇的连续催化氢化制备1,4-丁二醇的方法包括在非均相氢化催化剂存在下，在20-300℃下，使1,4-丁炔二醇与液体连续相中的氢反应，使用悬浮在反应介质中的催化剂，1至200巴的压力和液体侧体积传质系数kLa的值为0.1s-1至1s-1a），其中如果使用填充气泡塔，则在向上流动模式下操作，并且以从0.99:1至0.4:1的气体流入反应容器的气体的比率），使液体和气体沿向上的方向并流通过固定 - 在气体循环模式下操作的床反应器，同时保持供给反应容器的气体与离开反应容器的气体的比例为0.99:1至0.4:1。

67. 发明授权

US06204417B1 Method for producing aliphatic alcohols 有权
标题翻译：生产脂肪醇的方法
公开(公告)号：US06204417B1
公开(公告)日：2001-03-20
申请号：US09423876
申请日：1999-11-15
申请人： Rolf Fischer , Rolf Pinkos , Joachim Wulff-Döring
发明人： Rolf Fischer , Rolf Pinkos , Joachim Wulff-Döring
IPC分类号： C07C3118
CPC分类号： C07C29/149 , B01J23/56 , B01J23/6567 , B01J23/89 , C07C31/12 , C07C31/207 , C07C31/125 , C07C31/20
摘要： In a process for preparing aliphatic alcohols by hydrogenating aliphatic carboxylic acids or anhydrides or esters thereof or lactones in the presence of a catalyst comprising Pt and Re, in the form of the metal or an oxide in each case, the catalyst further comprises at least one further element from the groups 5 to 12 and 14 and the lanthanides of the Periodic Table of the Elements in the form of the metal or an oxide.
摘要翻译：在通过在包含Pt和Re的催化剂的存在下，在每种情况下以金属或氧化物的形式加氢脂族羧酸或其酸酐或其酯或内酯的方法中，催化剂还包含至少一种第5〜12和14族的元素，元素周期表的镧系元素为金属或氧化物。

68. 发明授权

US06194624B1 Hydrogenation of polyenes to monoenes 失效
标题翻译：将多烯氢化成单烯
公开(公告)号：US06194624B1
公开(公告)日：2001-02-27
申请号：US09444316
申请日：1999-11-22
申请人： Rolf Pinkos
发明人： Rolf Pinkos
IPC分类号： C07C502
CPC分类号： C07C5/05 , C07C2523/46
摘要： A process for hydrogenating polyenes, especially 1,5,9-cyclododecatriene, to the corresponding monoenes, especially cyclododecene, using homogeneous ruthenium catalysts comprises hydrogenating in the presence of a carboxylic acid, advantageously a C1-C20 monocarboxylic acid, a C2-C6 dicarboxylic acid, cyclohexylcarboxylic acid, benzoic acid, terephthalic acid, phthalic acid or phenylacetic acid, especially acetic acid, propionic acid, succinic acid or adipic acid or a C12-C20 fatty acid. The homogeneous ruthenium catalyst is advantageously generated in situ prior to the hydrogenation. The in situ generation is carried out in the additional presence of CO or formaldehyde and the hydrogenation in the additional presence of triphenylphosphine.
摘要翻译：使用均匀的钌催化剂将多烯，特别是1,5,9-环十二碳三烯氢化成相应的单烯，特别是环十二碳烯的方法包括在羧酸存在下，有利的是C 1 -C 20一元羧酸，C 2 -C 6二羧酸酸，环己基羧酸，苯甲酸，对苯二甲酸，邻苯二甲酸或苯乙酸，特别是乙酸，丙酸，琥珀酸或己二酸或C 12 -C 20脂肪酸。均匀的钌催化剂有利地在氢化之前原位产生。原位产生在CO或甲醛的另外存在下进行，并且在另外存在三苯基膦的情况下进行氢化。

69. 发明授权

US06169189A Process for preparing tetrahydrofuran from dialkoxybutenes 失效
标题翻译：从二烷氧基丁烯制备四氢呋喃的方法
公开(公告)号：US06169189A
公开(公告)日：2001-01-02
申请号：US09180482
申请日：1998-11-12
申请人： Rolf Fischer , Rolf Pinkos , Martin Sch{umlaut over (a)}fer , Arthur Höhn , Peter Schwab
发明人： Rolf Fischer , Rolf Pinkos , Martin Sch{umlaut over (a)}fer , Arthur Höhn , Peter Schwab
IPC分类号： C07D30708
CPC分类号： C07C41/18 , C07C41/26 , C07C41/32 , C07D307/08 , C07C43/15 , C07C43/13
摘要： A process for preparing tetrahydrofuran, which comprises reacting 1,4-butenediol diethers of the formulae I and/or II RO—CH2—CH═CH—CH2—OR I RO—CH2—CH2═CH—CH2—OR II, where the R radicals can be identical or different and are C1-C15-alkyl or cycloalkyl radicals, C6-C12-aryl radicals or C7-C15-aralkyl radicals, with water and hydrogen at from 20 to 300° C. under from 1 to 300 bar in the presence of catalysts or catalyst combinations which comprise components which are both capable of hydrogenation and have acidic or basic centers and a novel process for preparing 1,4-butanediol diethers of the formula I by metathesis are described.
摘要翻译：一种制备四氢呋喃的方法，其包括使式I和/或II的1,4-丁烯二醇二醚反应，其中R基团可以相同或不同，为C 1 -C 15 - 烷基或环烷基，C 6 -C 12 - 芳基或C 7 -C 15 - 芳烷基，其中水和氢在20-300℃，在1-300巴下，在催化剂或催化剂组合的存在下，其包含能够氢化并具有酸性或碱性中心的组分，以及新颖的描述了通过复分解制备式I的1,4-丁二醇二醚的方法。

70. 发明授权

US6093857A Preparation of cyclopentanols 失效
标题翻译：环戊醇的制备
公开(公告)号：US6093857A
公开(公告)日：2000-07-25
申请号：US928524
申请日：1997-09-12
申请人： Rolf Fischer , Rolf Pinkos , Norbert Rieber , Michael Schulz , Joaquim Henrique Teles
发明人： Rolf Fischer , Rolf Pinkos , Norbert Rieber , Michael Schulz , Joaquim Henrique Teles
IPC分类号： B01J27/128 , B01J27/138 , B01J31/02 , B01J31/12 , C07B61/00 , C07C67/04 , C07C69/06 , C07C35/06
CPC分类号： C07C67/04 , C07C29/1285 , C07C2101/08
摘要： A process for preparing cyclopentyl formates of the formula (II) ##STR1## by reacting cyclopentenes of the formula (I) ##STR2## where R.sup.1, R.sup.2 and R.sup.3, independently of one another, are hydrogen atoms or C.sub.1-8 -alkyl,with formic acid in the presence of an acid catalyst.
摘要翻译：通过使式（I）的环戊烯与其中R1，R2和R3彼此独立地为氢原子或C1-8烷基的环戊烯与甲酸在存在下反应制备式（II）的环戊基甲酸酯的方法，酸催化剂。

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