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    • 51. 发明授权
    • Plasma nitrided titanium and titanium alloy products
    • 等离子氮化钛和钛合金产品
    • US5443663A
    • 1995-08-22
    • US235171
    • 1994-04-29
    • Efstathius Meletis
    • Efstathius Meletis
    • C23C8/24C23C8/36C22C14/00
    • C23C8/24C23C8/36
    • The present invention relates to ion nitriding of pure titanium or titanium-containing alloys at low pressure by intensifying the glow discharge. Plasma intensification was produced by thermionic emission in conjunction with a triode glow discharge system. Effective ion nitriding can be achieved by employing the present invention at relatively low temperatures (480.degree. C.) and with significantly enhanced compound layer growth kinetics compared to the conventional nitriding techniques. Processed Ti and Ti-6Al-4V developed a surface layer of TiN followed by a Ti.sub.2 N layer and an interstitial nitrogen diffusion zone. Processed specimens showed a three fold increase in surface hardness. Surface roughness was found to be a function of the degree of plasma intensification. Processing of Ti-6Al-4V resulted in a higher wear, corrosion and wear-corrosion resistance. The present invention indicates that ion nitriding with intensified glow discharge has a great potential as a surface modification method for Ti and Ti alloys. Materials nitriding by the present invention having the properties defined above are suitable for use as orthopaedic implant devices as well as other applications of titanium and titanium alloys requiring resistance to wear and corrosion.
    • 本发明涉及通过强化辉光放电在低压下对纯钛或含钛合金的离子渗氮。 通过热电子发射与三极管辉光放电系统结合产生等离子体增强。 通过在相对较低的温度(480℃)下采用本发明并且与常规氮化技术相比,可显着提高化合物层生长动力学,可以实现有效的离子渗氮。 加工的Ti和Ti-6Al-4V开发了TiN的表面层,然后是Ti2N层和间隙氮扩散区。 加工样品的表面硬度增加了三倍。 发现表面粗糙度是等离子体增强度的函数。 Ti-6Al-4V的加工导致更高的磨损,腐蚀和耐磨损性。 本发明表明,加强辉光放电的离子氮化作为Ti和Ti合金的表面改性方法具有很大的潜力。 具有上述性质的本发明氮化的材料适合用作矫形植入装置以及需要耐磨损和腐蚀的钛和钛合金的其它应用。
    • 57. 发明授权
    • Rapid thermochemical treatment automatic installation
    • 快速热化学处理自动安装
    • US4915361A
    • 1990-04-10
    • US248139
    • 1988-09-23
    • Oliver SchwebelDenis Lebeaupin
    • Oliver SchwebelDenis Lebeaupin
    • B65G47/80C21D1/00C21D9/00C23C8/20C23C8/24C23C14/56F27B19/02
    • C23C14/568C21D9/0018
    • A rapid thermochemical treatment automatic installation for a charge constituted by parts, intended particularly for the mechanical industry, which includes a plurality of treatment modules such as an induction preheating module, thermochemical treatment modules, a quenching module, a device for carrying out the loading and unloading of the parts stacked in columns and a transfer device of the columns of parts between the various treatment modules. The installation includes a fixed circular plate on the periphery of which are distributed various treatment modules, which are suspended beneath the lower surface of the plate, which plate is formed with openings which can be tightly closed for the introduction of the parts to be treated in the respective modules, and a mobile disc rotably and coaxially mounted above the fixed plate, the mobile disc receiving the transfer device so that the transfer device can be brought successively above the loading/unloading station and the access station to the various modules for respectively introducing in the installation a column of parts to be treated, transferring the column of parts to be treated, transferring the column successively to the various modules and extracting from the installation the column of parts after treatment.
    • 一种用于特别用于机械工业的部件的电荷的快速热化学处理自动安装,其包括多个处理模块,例如感应预热模块,热化学处理模块,淬火模块,用于执行装载的装置和 堆放在柱上的部件的卸载和各种处理模块之间的各列的转移装置。 该装置包括在其周边上的固定圆板,其分布有各种处理模块,其悬挂在板的下表面下方,该板形成有可以紧密关闭的开口,用于将待处理的部件引入 相应的模块和可旋转地并同轴地安装在固定板上方的移动盘,移动盘接收传送装置,使得传送装置可以连续地在加载/卸载站和接入站之上连接到各个模块,以分别引入 在安装中要处理的一列零件,转移待处理的零件列,将柱连续转移到各种模块,并从处理后从安装柱中提取零件。
    • 60. 发明授权
    • Surface treating method and apparatus
    • 表面处理方法和装置
    • US4786526A
    • 1988-11-22
    • US66483
    • 1987-05-29
    • Tohru AraiJunji EndoHiromasa Takeda
    • Tohru AraiJunji EndoHiromasa Takeda
    • C23C8/20C23C8/06C23C8/24C23C10/08C23C10/14C23C16/32C23C16/34C23C16/448B05D1/22
    • C23C16/34C23C16/32C23C16/4488C23C8/06Y10S118/05
    • A method and apparatus for forming a layer of a carbide or nitride of, for example, titanium or vanadium on the surface of material to be treated in a fluidized bed furnace. A refractory powder for forming a fluidized bed, a vessel or vessels filed with powder of a treating agent, and the material to be treated are placed in the furnace. The treating agent includes powder of at least one carbide or nitride forming metal or alloy and powder of at least one compound selected from the group consisting of chlorides, fluorides, bromides, iodides and boro-fluorides of alkali and alkaline earth metals and/or at least one of an ammonium halide and a metal halide. A fluidizing gas is introduced into the furnace under heat to form a fluidized bed in which the surface of the material to be treated is treated. The vessel or vessels are placed in the furnace in a spaced-apart relation from the material to be treated, so that no powder of the treating agent may adhere to the surface of the material to be treated.
    • PCT No.PCT / JP86 / 00360 Sec。 371日期1987年5月29日 102(e)日期1987年5月29日PCT提交1986年7月14日PCT公布。 公开号WO87 / 0207300 日期:1987年4月9日。一种用于在流化床炉中在待处理材料的表面上形成例如钛或钒的碳化物或氮化物层的方法和装置。 将用于形成流化床的耐火材料粉末,装有处理剂粉末的容器和容器以及被处理材料放入炉中。 处理剂包括至少一种碳化物或氮化物形成金属或合金的粉末和至少一种选自碱金属和碱土金属的氯化物,氟化物,溴化物,碘化物和硼氟化物的化合物和/或在 卤化铵和金属卤化物中的至少一种。 在加热下将流化气体引入炉中以形成待处理材料的表面的流化床。 容器或容器以与待处理材料间隔开的关系放置在炉中,使得处理剂的粉末不会粘附到待处理材料的表面。