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    • 60. 发明授权
    • Process, modified rubbers and rubber compositions
    • 工艺,改性橡胶和橡胶组合物
    • US5001171A
    • 1991-03-19
    • US260631
    • 1988-10-21
    • Georg G. BohmDaniel F. Graves
    • Georg G. BohmDaniel F. Graves
    • C08J3/20C08K5/32C08K5/3442C08K5/35
    • C08K5/3442C08J3/203C08K5/32C08K5/35C08J2321/00
    • It now has been found that uncured modified rubber compositions comprising mixtures of elastomers and a reinforcing filler can be prepared having improved properties. More particularly, such uncured modified rubber compositions can be prepared by a process which comprises the steps of(A) preparing a first mixture comprising an elastomer, at least one reinforcing filler and at least one chemical agent capable of promoting the formation of filler-elastomer linkages;(B) preparing a second mixture comprising(i) an elastomer, at least one reinforcing filler and at least one chemical agent capable of promoting the formation of filler-elastomer linkages, wherein at least one of the elastomer, filler or chemical agent in the second mixture is different from the elastomer, filler or chemical agent in the first mixture; or(ii) an elastomer and at least one reinforcing filler; or(iii) at least one reinforcing filler and at least one chemical agent capable of promoting the formation of filler-elastomer linkages; or(iv) an elastomer and at least one chemical agent capable of promoting the formation of filler-elastomer linkages; and(C) blending the first and second mixtures to form a third mixture. Examples of such useful chemical agents include aromatic furazan oxides, heterocyclic di-N-oxides, 1-hydroxy-benzimidazole-3-oxide compounds, 1,3-dihydroxy-benzimidazolinone compounds, and aromatic nitroso compounds.The invention also includes filled vulcanizates prepared by vulcanizing the uncured modified rubber compositions prepared in accordance with the above method. Rubber articles and portions thereof made from such vulcanizates such as tires, hoses, belts, treads, sidewalls and the like are also within the scope of the present invention as well as methods of reducing the rolling resistance of tires.
    • 现在已经发现,可以制备包含弹性体和增强填料的混合物的未固化的改性橡胶组合物,其具有改进的性能。 更具体地,这种未固化的改性橡胶组合物可以通过包括以下步骤的方法制备:(A)制备包含弹性体,至少一种增强填料和至少一种能够促进形成填料 - 弹性体的化学试剂的第一混合物 联系 (B)制备第二混合物,其包含(i)弹性体,至少一种增强填料和至少一种能够促进形成填料 - 弹性体键的化学试剂,其中至少一种弹性体,填料或化学试剂在 第二混合物不同于第一混合物中的弹性体,填料或化学试剂; 或(ii)弹性体和至少一种增强填料; 或(iii)至少一种增强填料和至少一种能够促进形成填料 - 弹性体键的化学试剂; 或(iv)弹性体和至少一种能促进形成填料 - 弹性体键的化学试剂; 和(C)混合第一和第二混合物以形成第三混合物。 这种有用的化学试剂的实例包括芳族呋喃氧化物,杂环二-N-氧化物,1-羟基 - 苯并咪唑-3-氧化物,1,3-二羟基 - 苯并咪唑啉酮化合物和芳族亚硝基化合物。 本发明还包括通过硫化根据上述方法制备的未固化的改性橡胶组合物制备的填充硫化橡胶。 由这种硫化橡胶制成的橡胶制品及其部分,例如轮胎,软管,皮带,胎面,侧壁等也在本发明的范围内,以及降低轮胎的滚动阻力的方法。