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    • 4. 发明授权
    • Novel compositions based on indanthrone blue pigments
    • 基于阴丹士蓝色颜料的新型组合物
    • US4692189A
    • 1987-09-08
    • US887776
    • 1986-07-21
    • Fridolin BablerEdward E. JaffeBernhard Medinger
    • Fridolin BablerEdward E. JaffeBernhard Medinger
    • C09B63/00C08K5/3442C08K5/3465C09B67/22C09D7/12C09D11/02C04B14/00
    • C09B67/0034
    • A composition comprising(a) an indanthrone blue pigment of formula I ##STR1## and (b) a sulfonated indanthrone blue derivative of formula II ##STR2## wherein X.sup..sym. is H.sup..sym. or a group of the formula M.sup.n.sym. /n or N.sup..sym. (R)(R.sub.1)(R.sub.2)(R.sub.3), M is a monovalent, divalent or trivalent metal cation, n is 1, 2 or 3, each of R, R.sub.1, R.sub.2 and R.sub.3 is independently hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.6 cycloalkyl, phenyl or phenyl which is substituted by C.sub.1 -C.sub.18 alkyl, or R.sub.2 and R.sub.3, together with the linking nitrogen atom, are a pyrrolidine, imidazoline, piperidine, piperazine or morpholine radical, or R.sub.1, R.sub.2 and R.sub.3, together with the linking nitrogen atom, are a pyrrole, pyridine, picoline, pyrazine, quinoline or isoquinoline radical, and m is a value from 0.2 to 3.When used in varnishes, pigment mixtures of this kind are distinguished in particular by increased color strength, improved rheology and high gloss.
    • 一种组合物,其包含(a)式I的阴丹士蓝蓝颜料(I)和(b)式II的磺化阴丹酮蓝衍生物其中X(+)是H(+)或基团 式中Mn(+)/ n或N(+)(R)(R1)(R2)(R3),M为一价,二价或三价金属阳离子,n为1,2或3, R 1,R 2和R 3独立地是氢,C 1 -C 18 - 烷基,C 5 -C 6环烷基,苯基或被C 1 -C 18烷基取代的苯基,或者R 2和R 3与连接氮原子一起是吡咯烷,咪唑啉,哌啶, 哌嗪或吗啉基,或R 1,R 2和R 3与连接氮原子一起为吡咯,吡啶,甲基吡啶,吡嗪,喹啉或异喹啉基,m为0.2至3.当用于清漆时,颜料 这种混合物特别通过增加着色强度,改善的流变性和高光泽来区分。
    • 10. 发明授权
    • Solid solutions of pyrrolo-(3,4-C)-pyrroles with quinacridones
    • 吡咯并(3,4-C) - 吡咯与喹吖啶酮的固溶体
    • US4810304A
    • 1989-03-07
    • US119523
    • 1987-11-12
    • Edward E. JaffeFridolin Babler
    • Edward E. JaffeFridolin Babler
    • C09B67/22C08K5/00
    • C09B67/0033
    • Solid solutions of pyrrolo-[3,4-c]-pyrroles and quinacridones which contain(a) at least one compound of the formulae ##STR1## in which A and B are independently of each other one of the groups of the formulae ##STR2## in which R.sub.1 and R.sub.2 are independently of each other hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -alkoxy, --SR.sub.3, --N(R.sub.3).sub.2 --CF.sub.3, --CN or a group of the formulae ##STR3## R.sub.3 is C.sub.1 -C.sub.5 -alkyl and R.sub.4 and R.sub.5 are independently of each other hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C hd 5-alkoxy, --SR.sub.3 or --CN, and(b) at least one linear quinacridone compound of the formulae ##STR4## in which W, X, Y and Z are independently of one another halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -alkoxy and i, k, m and n is zero, 1 or 2, the X-ray diffraction diagrams of the solid solutions differing from the sum of the X-ray diffraction diagrams of the individual components.These solid solutions are highly suitable for use as pigments for colouring high molecular weight organic material.
    • 吡咯并[3,4-c]吡咯和喹吖啶酮的固溶体,其包含(a)至少一种式(I)或(IMAGE)(II)的化合物,其中A和B各自独立地 其中R 1和R 2彼此独立地为氢,卤素,C 1 -C 5 - 烷基,C 1 -C 5 - 烷氧基,-SR 3,-N(R 3) 2-CF 3,-CN或式的基团R 3是C 1 -C 5 - 烷基,R 4和R 5彼此独立地为氢,卤素,C 1 -C 5 - 烷基,C 1 -C 6 5-烷氧基,-SR 3或-CN,和(b)至少一种下式的直链喹吖啶酮化合物:(IV)图像36 ... OOHNHNe00 / 246 .. 其中W,X,Y和Z彼此独立地为卤素,C 1 -C 5 - 烷基,C 1 -C 5 - 烷氧基和i,k ,m和n为零,1或2,固溶体的X射线衍射图不同于各个组分的X射线衍射图之和。 这些固溶体非常适合用作着色高分子量有机材料的颜料。