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    • 57. 发明授权
    • Polymer printing
    • 聚合物印刷
    • US4732829A
    • 1988-03-22
    • US672500
    • 1984-11-19
    • Donald Sullivan
    • Donald Sullivan
    • B23K35/22G03F7/16H05K3/00H05K3/12H05K3/28G03C3/00
    • B23K35/224G03F7/16H05K3/281H05K2203/056H05K2203/0577H05K2203/066H05K2203/0759H05K3/0079H05K3/1216Y10S430/136
    • Improved printing with polymers is achieved by interposing a liquid layer conforming to rough substrate surfaces and possibly exhibiting different characteristics from an outer surface polymer layer. This is particularly advantageous in printed wiring board (PWB) manufacture requiring solder mask coating. Thus, a two layer composite polymer coating is provided. One inner adhesive photopolymer layer is applied to the PWB in the liquid state, displacing air from PWB surface. The outer layer of the composite therefore can be epoxy, dry film or liquid polymer. Dry film thus carried on a thin plastic sheet may be overlaminated onto a liquid inner layer already on the substrate, without the need for a vacuum laminator to eliminate bubbles or a plasticizing heat step to conform the dry film to the surface. The dry film solder mask so laminated is then exposed through a phototransparency to harden the light struck dry film solder mask and light struck inner layer photopolymer, thereby cojoining the dry film solder mask, inner layer and PWB surface. A solvent washout step removes unexposed dry film solder mask and unexposed inner layer photopolymer. This provides a faster process, requires less equipment, and improves adhesion to metal conductors. This embodiment gives a high resolution product with good solder mask qualities. The outer layer need not be photoimaged. Thus, pre-patterned epoxy solder masks may be printed on the carrier sheet, partially hardened and overlaminated in registor onto liquid photopolymer-coated PWB, then exposed to light source through a phototransparency and through the pre-patterned solder mask, thereby permanently adhering the outer layer to PWB. The composite coating can be a combination of known solder mask materials, dry film, UV-curable liquid polymers and thermal-curing epoxy, chosen for desired characteristics including electrical performance, printing resolution and cost.
    • 用聚合物改进的印刷通过插入符合粗糙的基材表面的液体层并且可能表现出与外表面聚合物层不同的特性来实现。 这在需要焊接掩模涂层的印刷电路板(PWB)制造中是特别有利的。 因此,提供了两层复合聚合物涂层。 一个内部粘合剂光聚合物层以液态施加到PWB,从PWB表面排出空气。 因此,复合材料的外层可以是环氧树脂,干膜或液体聚合物。 因此携带在薄塑料片上的干膜可以被覆盖在已经在基材上的液体内层上,而不需要真空层压机以消除气泡或塑化加热步骤以使干膜符合表面。 然后将如此层压的干膜焊接掩模通过光透明物曝光以硬化受光的干膜焊接掩模和轻质内层光聚合物,从而将干膜焊接掩模,内层和PWB表面相互连接。 溶剂洗涤步骤除去未曝光的干膜焊接掩模和未曝光的内层光聚合物。 这提供了更快的过程,需要更少的设备,并且改善对金属导体的粘合性。 本实施例给出了具有良好焊接掩模质量的高分辨率产品。 外层不需要光刻。 因此,预先图案化的环氧焊料掩模可以印刷在载体片上,部分硬化并在转移器中叠层在液体光聚合物涂布的PWB上,然后通过光透明性和通过预图案化的焊接掩模暴露于光源,从而永久粘附 外层到PWB。 复合涂层可以是已知的焊接掩模材料,干膜,UV可固化液体聚合物和热固化环氧树脂的组合,其被选择用于期望的特性,包括电性能,印刷分辨率和成本。