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51. 发明授权

US5114743A Method of making nitride and oxide electrodes on a solid electrolyte 失效
标题翻译：在固体电解质上制备氮化物和氧化物电极的方法
公开(公告)号：US5114743A
公开(公告)日：1992-05-19
申请号：US438067
申请日：1989-11-20
申请人： Neill Weber
发明人： Neill Weber
IPC分类号： C04B35/113 , C04B41/50 , C04B41/87 , H01G9/00 , H01G9/21
CPC分类号： H01G9/21 , C04B35/113 , C04B41/009 , C04B41/5025 , C04B41/5062 , C04B41/87
摘要： A method is disclosed for bonding nitride and oxide film electrodes on ceramic substrates, which can be used in thermo electric generators. Hydride powders in suspension are coated on a substrate, and heated to selected temperatures for selected periods of times in alternating atmospheres of hydrogen and nitrogen, or oxygen. The method produces satisfactory film electrodes, including electrodes which are greater than 10 microns in thickness.
摘要翻译：公开了一种用于将氮化物和氧化物膜电极接合在可用于热发电机的陶瓷衬底上的方法。将悬浮液中的氢化物粉末涂覆在基材上，并在氢气和氮气或氧气的交替气氛中加热至选定温度选定的时间。该方法产生令人满意的膜电极，包括厚度大于10微米的电极。

52. 发明授权

US5085948A Alkali metal thermoelectric power generator 失效
标题翻译：碱金属热电发电机
公开(公告)号：US5085948A
公开(公告)日：1992-02-04
申请号：US647413
申请日：1991-01-29
申请人： Moriaki Tsukamoto , Hisamichi Inoue
发明人： Moriaki Tsukamoto , Hisamichi Inoue
IPC分类号： H02N3/00 , H01G9/00 , H01G9/21 , H01M10/39
CPC分类号： H01G9/21 , H01M10/3909
摘要： Disclosed is an alkali metal thermoelectric power generator comprising a plurality of thermoelectric converters, which are connected in electrical series to one another by an external electronic conductor device, each of the converters converting thermal energy into electrical energy by utilizing the phenomenon that an alkali metal, arranged on each side of a solid electrolyte, diffuses across the electrolyte if the density thereof on one side of the electrolyte differs from that on the other side of the same. The generator further comprises a piping consisting of a plurality of connection pipes for returning the alkali metal condensed in a second spatial region of each thermoelectric converter to a first spatial region thereof through a common pump. Further, the respective open ends of the connection pipes, which connect the respective first regions of the converters to one another, are positioned in those portions of the respective first regions where only the vapor phase alkali metal exists.
摘要翻译：公开了一种碱金属热电发电机，其包括通过外部电子导体装置彼此电连接的多个热电转换器，每个转换器通过利用碱金属，布置在固体电解质的每一侧上，如果电解质一侧的密度不同于另一侧的密度，则扩散到电解质上。发电机还包括由多个连接管道组成的管道，用于将通过共用泵将在每个热电转换器的第二空间区域中冷凝的碱金属返回到其第一空间区域。此外，将转换器的各个第一区域彼此连接的连接管的各自的开放端部位于仅存在气相碱金属的各个第一区域的那些部分。

53. 发明授权

US4686320A Electronically and ionically conducting electrodes for thermoelectric generators 失效
标题翻译：用于热电发电机的电子和离子导电电极
公开(公告)号：US4686320A
公开(公告)日：1987-08-11
申请号：US813891
申请日：1985-12-27
申请人： Robert F. Novak , Neill Weber
发明人： Robert F. Novak , Neill Weber
IPC分类号： H02N3/00 , C23C4/10 , C23C4/18 , H01G9/00 , H01G9/21 , H02N11/00 , H01L35/14
CPC分类号： H01G9/21 , H01M10/39
摘要： A composite article comprising a porous cermet electrode on a dense solid electrolyte and method of making same. The cerment electrode comprises beta-type-alumina and refractory metal.
摘要翻译：一种复合制品，其包含在致密固体电解质上的多孔金属陶瓷电极及其制造方法。陶瓷电极包括β型氧化铝和难熔金属。

54. 发明授权

US4410605A Thermal galvanic cells 失效
公开(公告)号：US4410605A
公开(公告)日：1983-10-18
申请号：US314519
申请日：1981-10-26
申请人： Robert L. Peck
发明人： Robert L. Peck
IPC分类号： H01G9/00 , H01G9/21 , H01M6/36 , H01M14/00
CPC分类号： H01G9/21 , H01M14/00 , H01M6/36
摘要： The efficiency of thermal galvanic cells is enhanced by establishing a temperature gradient along the electrodes, in addition to the temperature gradient between the electrodes, and/or by optimizing electrode geometry. Optimization of electrode geometry may comprise segmenting the electrodes while retaining the desired total electrode area or controlling the depth of immersion of the electrodes into the electrolyte. Further performance improvement may be obtained through the addition of a silica containing material and/or a thermal barrier to the electrolyte.

55. 发明授权

US4310402A Gas tight sealant for zirconia sensors 失效
标题翻译：气密密封胶氧化锆传感器
公开(公告)号：US4310402A
公开(公告)日：1982-01-12
申请号：US204144
申请日：1980-11-05
申请人： Arnold O. Isenberg , David F. Bradley
发明人： Arnold O. Isenberg , David F. Bradley
IPC分类号： G01N27/407 , G01N27/413 , H01G9/00 , H01G9/21 , H01M2/08 , H01M8/02 , G01N27/58
CPC分类号： H01G9/21 , G01N27/4073 , H01M2/08 , H01M8/0271
摘要： In a high temperature gas measuring device consisting of a zirconia oxide solid electrolyte cell bonded to a support member, a sealant exhibiting a thermal coefficient of expansion comparable to zirconia and a melting point in excess of 1000.degree. C. is used to seal the cell to the support member. The preferred sealants which meet these requirements include:(1) 3 MgO.sup.. Al.sub.2 O.sub.3.sup.. 6 SiO.sub.2(2) 52% Nd.sub.4 (SiO.sub.4).sub.3, 48% Ca.sub.2 SiO.sub.4(3) 57% La.sub.4 (SiO.sub.4).sub.3, 43% Ca.sub.2 SiO.sub.4(4) 50% Y.sub.4 (SiO.sub.4).sub.3, 50% Ca.sub.2 SiO.sub.4(5) (a) La.sub.2 O.sub.3.sup.. Al.sub.2 O.sub.3 : 50 mol % of each (b) 40% La.sub.2 O.sub.3.sup.. 60% Al.sub.2 O.sub.3.
摘要翻译：在由结合到支撑构件的氧化锆固体电解质电池组成的高温气体测量装置中，使用与氧化锆相当并且熔点超过1000℃的膨胀热膨胀系数的密封剂将电池密封到支撑构件。满足这些要求的优选密封剂包括：（1）3 MgO.Al2O3.6SiO 2（2）52％Nd4（SiO4）3,48％Ca2SiO4（3）57％La4（SiO4）3,43％Ca2SiO4（4） 50％Y4（SiO4）3,50％Ca2SiO4（5）（a）La2O3.Al2O3：50％（b）40％La2O3.60％Al2O3。

56. 发明授权

US4220692A Internal geometry of alkali metal thermoelectric generator devices 失效
标题翻译：碱金属热电发电装置内部几何形状
公开(公告)号：US4220692A
公开(公告)日：1980-09-02
申请号：US016240
申请日：1979-02-28
申请人： Thomas K. Hunt
发明人： Thomas K. Hunt
IPC分类号： H01L37/00 , H01G9/00 , H01G9/21 , H02N3/00 , H01M4/36
CPC分类号： H01G9/21
摘要： Electrolyte geometry in alkali metal thermoelectric generator devices that alters the view thereof seen by cooler condenser regions provides an increase in power generating area without undesirably concomitant increase in radiation heat transfer area.
摘要翻译：碱性金属热电发电装置中的电解质几何形状改变了由冷凝器区域所看到的视图，提供了发电区域的增加，而辐射传热面积却不伴随着增加。

57. 发明授权

US3704221A Medium for ionic transport 失效
标题翻译：离子运输中介
公开(公告)号：US3704221A
公开(公告)日：1972-11-28
申请号：US3704221D
申请日：1967-11-09
申请人： MCCULLY CHARLES ROLAND , ROLAND A MCCULLY
发明人： MCCULLY CHARLES ROLAND , MCCULLY ROLAND A
IPC分类号： H01G9/00 , H01G9/21 , H01M2/16 , H01M8/00 , H01M10/36 , H01M12/08 , B01K3/10
CPC分类号： H01G9/21 , H01M2/1613 , H01M2/1653 , H01M2/1686 , H01M8/00 , H01M10/36 , H01M12/085 , Y02E60/128
摘要： IN AN ELECTROCHEMICAL DEVICE, SUCH AS A GALVANIC CELL, OR AN ELECTROYLIC CELL, THERE IS PROVIDED A NON-AQUEOUS MEDIUM WHICH SERVES AS A BARRIER TO LIQUID FLOW WHILE PERMITTING TRANSPORT OF IONS. THE MEDIUM IS MADE OF A POROUS INERT RETENTION AGENT IMPREGNATED WITH A NON-AQUEOUS SOLUTION OF AN IONIC MATERIAL CONTAINING THE ION TO BE TRANSPORTED. IN MOST CASES, THE POROUS INERT RETENTION AGENT IS MADE OF MINERAL FIBERS, WHICH MAY BE BONDED TOGETHER BY A FLUOROCARBON RESIN. LESS PREFERABLY, A POROUS STRUCTURE OF MINERAL PARTICLES BONDED TOGETHER BY A FLUOROCARBON RESIN MAY BE SUBSTITUTED FOR THE FIBROUS MATTE.

58. 发明授权

US3508968A Thermoelectric device 失效
公开(公告)号：US3508968A
公开(公告)日：1970-04-28
申请号：US3508968D
申请日：1962-05-28
申请人： ENERGY CONVERSION DEVICES INC
发明人： OVSHINSKY STANFORD R
IPC分类号： H01G9/00 , H01G9/21 , H01L35/00 , H01L35/14 , H01L35/32 , H01M
CPC分类号： H01G9/21 , H01L35/00 , H01L35/14 , H01L35/32

59. 发明授权

US3186872A Continuous gas concentration cell energy conversion 失效
标题翻译：连续气体浓度电池能量转换
公开(公告)号：US3186872A
公开(公告)日：1965-06-01
申请号：US17273062
申请日：1962-02-12
申请人： BLAND EWING
发明人： BLAND EWING
IPC分类号： H01G9/00 , H01G9/21 , H01M8/18
CPC分类号： H01G9/21 , H01M8/182 , Y02E60/528

60. 发明授权

US11942282B1 Thermally sensitive state change ionic redox transistor 有权
公开(公告)号：US11942282B1
公开(公告)日：2024-03-26
申请号：US17374029
申请日：2021-07-13
申请人： National Technology & Engineering Solutions of Sandia, LLC
发明人： David Scott Ashby , Elliot James Fuller , Albert Alec Talin , Yiyang Li
IPC分类号： G11C13/00 , G11C11/54 , H01G9/21 , H01G9/22 , H01G9/025 , H01G9/035 , H01G9/28
CPC分类号： H01G9/22 , G11C11/54 , H01G9/21 , H01G9/025 , H01G9/035 , H01G9/28
摘要： A thermally sensitive ionic redox transistor comprises a channel, a reservoir layer, and an electrolyte layer disposed between the channel and the reservoir layer. A conductance of the channel is varied by changing concentration of ions in the channel layer. The electrolyte layer is configured to undergo a state change at a state transition temperature. Below the state transition temperature, ions in the electrolyte layer are substantially immobile. Above the state transition temperature, ions can move freely between the reservoir layer and the channel across the electrolyte layer in response to a voltage being applied between the channel and the reservoir layer. When the device is cooled below the state transition temperature or temperature range, the ions are trapped in one or more of the layers because the electrolyte layer loses its ionic conductivity. A state of the redox transistor can be read by measuring the conductance of the channel.

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