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    • 54. 发明授权
    • Liquefaction processes and systems and liquefaction process intermediate compositions
    • 液化过程和系统以及液化过程中间体组合物
    • US09388364B1
    • 2016-07-12
    • US14738563
    • 2015-06-12
    • Battelle Memorial Institute
    • Andrew J. SchmidtTodd R. HartJustin M. BillingGary D. MaupinRichard T. HallenDaniel B. Anderson
    • C11B1/12C11B3/00B01J19/24
    • C11B1/12C10G1/002C10G1/006C10G1/008C10G1/02C10G31/06C10G31/09C10G2300/1011C11B3/008C11B13/00Y02P30/20Y02W30/74
    • Liquefaction processes are provided that can include: providing a biomass slurry solution having a temperature of at least 300° C. at a pressure of at least 2000 psig; cooling the solution to a temperature of less than 150° C.; and depressurizing the solution to release carbon dioxide from the solution and form at least part of a bio-oil foam. Liquefaction processes are also provided that can include: filtering the biomass slurry to remove particulates; and cooling and depressurizing the filtered solution to form the bio-oil foam. Liquefaction systems are provided that can include: a heated biomass slurry reaction zone maintained above 300° C. and at least 2000 psig and in continuous fluid communication with a flash cooling/depressurization zone maintained below 150° C. and between about 125 psig and about atmospheric pressure. Liquefaction systems are also provided that can include a foam/liquid separation system. Liquefaction process intermediate compositions are provided that can include a bio-oil foam phase separated from an aqueous biomass solids solution.
    • 提供液化方法,其可以包括:在至少2000psig的压力下提供具有至少300℃的温度的生物质浆料溶液; 将溶液冷却至小于150℃的温度; 并将溶液减压以从溶液中释放二氧化碳,并形成生物油泡沫体的至少一部分。 还提供了液化方法,其可以包括:过滤生物质浆料以除去微粒; 并将过滤的溶液冷却和减压以形成生物油泡沫体。 提供了液化系统,其可以包括:保持在300℃以上且至少2000psig的加热的生物质浆料反应区,并与保持在150℃以下和约125psig和约125psig之间的闪蒸冷却/减压区连续流体连通 气压。 还提供了可以包括泡沫/液体分离系统的液化系统。 提供液化方法中间体组合物,其可以包括从含水生物质固体溶液中分离的生物油泡沫相。
    • 58. 发明申请
    • METHOD FOR PREPARING SHUT DOWN OF PROCESS AND EQUIPMENT FOR PRODUCING LIQUID HYDROCARBONS
    • 制备液化石油气的方法和设备的制备方法
    • US20150259606A1
    • 2015-09-17
    • US14417956
    • 2013-08-29
    • STEEPER ENERGY APS
    • Steen Brummerstedt Iversen
    • C10G1/06B01J19/24C10G1/00B01J19/00
    • C10G1/065B01J19/0013B01J19/24B01J2219/00051B01J2219/00162B01J2219/24C10G1/008C10G3/40C10G3/50C10G3/60C10G2300/4031C10G2300/42C10G2300/805Y02P30/20
    • The invention relates to a continous process for converting carbonaceous material contained in one or more feed-stocks into a liquid hydrocarbon product, said feedstocks including the carbonaceous material being in a feed mixture including one or more fluids, said fluids including water, the process comprising: converting at least part of the carbonaceous material by: pressurising the feed mixture to an operational pressure in the range 150-400 bar, heating the feed mixture to an operational temperature in the range 300-450° C., and maintaining said pressurized and heated feed mixture in the desired pressure and temperature ranges in a reaction zone for a predefined time; cooling the feed mixture to a temperature in the range 25-200° C. and expanding the feed mixture to a pressure in the range of 1-70 bar, thereby causing the carbonaceous material to be converted to a liquid hydrocarbon product; and separating from the converted feed mixture a fraction comprising liquid hydrocarbon product; where in a state of discontinued operation the inflow of feed mixture is terminated and the system is filled with a fluid; where the pressure and temperature is set to a predetermined desired level, where the temperature and the pressure are altered to the predetermined lower level at a pre determined rate and where the pressure during the altering is constantly kept at a level above the saturation pressure for the fluid at a given temparature.
    • 本发明涉及将包含在一种或多种原料中的含碳材料转化为液态烃产品的连续方法,所述原料包括含碳材料,其包含一种或多种流体的进料混合物,所述流体包括水,该方法包括 :通过以下方式转化至少部分的碳质材料:将进料混合物加压至150-400巴的操作压力,将进料混合物加热至300-450℃的操作温度,并保持所述加压和 加热的进料混合物在所需的压力和温度范围内在反应区中预定的时间; 将进料混合物冷却至25-200℃的温度,并将进料混合物膨胀至1-70巴的压力,从而使碳质材料转化为液态烃产物; 并从转化的进料混合物中分离出包含液态烃产物的馏分; 在处于停止运行状态的情况下,进料混合物的流入终止,并且系统充满流体; 其中压力和温度被设定为预定的期望水平,其中温度和压力以预定速率改变到预定的较低水平,并且其中改变期间的压力恒定地保持在高于饱和压力的水平 流体在给定的温度。