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    • 54. 发明授权
    • Molding expandable styrene polymer particles
    • 成型可发性苯乙烯聚合物颗粒
    • US4113672A
    • 1978-09-12
    • US848972
    • 1977-11-07
    • Walter O. Pillar
    • Walter O. Pillar
    • C08J9/16C08J9/00
    • C08J9/0014C08J9/0052C08J2325/00
    • Expandable styrene polymer particles having reduced flammability are made by incorporating from 0.1 to 15 weight percent of non-polymeric organic halogen compounds into the polymer during impregnation of the polymer particles with a blowing agent in aqueous suspension. The addition of 0.001 to 0.5 weight percent of dialkyl tin maleates or fumarates during the impregnation step produces expandable styrene polymer particles with greatly improved molding characteristics such as reduced pruning tendency, increased mold fusion, and greater dimensional stability. Addition of a synergistic amount of 0.001 to 0.4 weight percent of a hindered phenolic antioxidant with the tin compounds gives improved molding characteristics with retention of polymer molecular weight.
    • 通过在水性悬浮液中用发泡剂浸渍聚合物颗粒期间,通过将0.1至15重量%的非聚合有机卤素化合物引入聚合物中来制备具有降低的可燃性的可发性苯乙烯聚合物颗粒。 在浸渍步骤期间添加0.001至0.5重量%的马来酸二烷基锡或富马酸盐产生可扩展的苯乙烯聚合物颗粒,其具有极大改善的成型特性,例如减少的修剪趋势,增加的模具熔合和更大的尺寸稳定性。 与锡化合物一起添加0.001至0.4%(重量)的受阻酚类抗氧化剂,提供了改进的成型特性并保持了聚合物分子量。