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51. 发明申请

US20080103066A1 Use of mineral oils to reduce fluid loss for viscoelastic surfactant gelled fluids 有权
标题翻译：使用矿物油减少粘弹性表面活性剂凝胶液的流失
公开(公告)号：US20080103066A1
公开(公告)日：2008-05-01
申请号：US11970389
申请日：2008-01-07
申请人： Tianping Huang , James Crews
发明人： Tianping Huang , James Crews
IPC分类号： C09K8/035
CPC分类号： C09K8/68 , C09K2208/26 , C09K2208/30
摘要： Fluids viscosified with viscoelastic surfactants (VESs) may have their fluid loss properties improved with at least one mineral oil which has a viscosity greater than 20 cps at ambient temperature. The mineral oil may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the mineral oil is added to the fluid after it has been substantially gelled in an amount between about 0.2 to about 10% by volume.
摘要翻译：用粘弹性表面活性剂（VES）粘稠的流体可以在至少一种在环境温度下粘度大于20cps的矿物油改善其流体损失性能。矿物油可以最初分散在液体的内部不连续相中。在一个非限制性实施方案中，矿物油在其基本上以约0.2至约10体积％的量凝胶化之后加入到流体中。

52. 发明申请

US20070151726A1 Methods and Compositions for Diverting Acid Fluids in Wellbores 有权
标题翻译：在井筒中转移酸性液体的方法和组合
公开(公告)号：US20070151726A1
公开(公告)日：2007-07-05
申请号：US11689203
申请日：2007-03-21
申请人： James Crews , Tianping Huang
发明人： James Crews , Tianping Huang
IPC分类号： E21B43/22 , E21B43/27
CPC分类号： C09K8/72 , C09K8/602 , C09K8/68 , C09K8/74 , C09K2208/26 , C09K2208/30
摘要： Viscoelastic surfactant (VES) gelled aqueous fluids containing a VES, an internal breaker, and optionally a viscosity enhancer are useful as diverting fluid for directing placement of an acid into a subterranean formation, where the acid is injected subsequent to introducing the VES gelled fluid. These VES-based diverting fluids have faster and more complete clean-up than polymer-based diverting fluids. The viscosity enhancers may include pyroelectric particles and/or piezoelectric particles. The VES gelled fluid may optionally contain a fluid loss agent which increases the viscosity of the fluid and/or facilitates development of an external viscous VES fluid layer (e.g. a pseudo-filter cake) on the formation face. The VES gelled fluid may also optionally contain an agent that stabilizes the viscosity of the fluid, for instance at high temperatures, such as MgO, Mg(OH)2, CaO, Ca(OH)2, NaOH, and the like.
摘要翻译：粘弹性表面活性剂（VES）含有VES，内部破碎剂和任选的粘度增强剂的凝胶水性流体可用作转向流体，用于将酸引入地下地层中，其中在引入VES凝胶流体之后注入酸。这些基于VES的转向流体比基于聚合物的转移流体更快，更完整地清理。粘度增强剂可以包括热电颗粒和/或压电颗粒。 VES凝胶化流体可以任选地含有流体损失剂，其增加流体的粘度和/或促进形成面上的外部粘性VES流体层（例如伪滤饼）的显影。 VES凝胶状流体还可任选地含有稳定流体粘度的试剂，例如在高温下，例如MgO，Mg（OH）2，CaO，Ca（OH） 2N，NaOH等。

53. 发明授权

US06994166B2 Composition and method for diversion agents for acid stimulation of subterranean formations 失效
标题翻译：用于地下地层酸刺激的转移剂的组成和方法
公开(公告)号：US06994166B2
公开(公告)日：2006-02-07
申请号：US10602230
申请日：2003-06-24
申请人： Tianping Huang , Paul M. McElfresh
发明人： Tianping Huang , Paul M. McElfresh
IPC分类号： E21B43/27 , E21B33/138
CPC分类号： C09K8/72 , Y10S507/933
摘要： It has been discovered that solid, particulate dicarboxylic acids are useful as diverting agents in methods for acidizing subterranean formations to improve the uniformity of the acid treatments (acid displacement) by diverting acid to intervals of relatively less permeability. Particularly suitable solid, particulate dicarboxylic acids include, but are not necessarily limited to, those insoluble in both aqueous and hydrocarbon liquids, but which are soluble in mutual solvents or alcohol blends. These acids may have melting points of from about 180 to about 300° F. (about 82 to about 149° C.), formula molecular weights of from 146 to 400, and mesh sizes of from about 20 mesh to about 400 mesh (about 841 to about 38 microns). Particular dicarboxylic acids that fit this description include, but are not necessarily limited to, dodecanedioic acid, undecanedioic acid, decanedioic acid, azelaic acid, suberic acid, and mixtures thereof.
摘要翻译：已经发现，固体颗粒二羧酸在用于酸化地下地层的方法中可用作转向剂，以通过将酸转移到相对较小渗透性的间隔来改善酸处理的均匀性（酸置换）。特别合适的固体颗粒二羧酸包括但不一定限于不溶于水和烃液体但可溶于相互溶剂或醇共混物的那些。这些酸可以具有约180至约300°F（约82至约149℃）的熔点，146至400的分子式分子量和约20目至约400目（约 841至约38微米）。符合该描述的特定二羧酸包括但不一定限于十二烷二酸，十一烷二酸，癸二酸，壬二酸，辛二酸及其混合物。

54. 发明授权

US08815089B2 Wastewater purification with nanoparticle-treated bed 有权
标题翻译：用纳米颗粒处理床进行废水净化
公开(公告)号：US08815089B2
公开(公告)日：2014-08-26
申请号：US13542887
申请日：2012-07-06
申请人： Tianping Huang , James B. Crews
发明人： Tianping Huang , James B. Crews
IPC分类号： B01D39/06
CPC分类号： B01J20/22 , B01J20/0211 , B01J20/0244 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/28004 , B01J20/28007 , B01J20/3204 , B01J20/3236 , B01J20/3289 , B01J20/3425 , B01J20/3433 , B01J20/3475 , B01J2220/46 , B01J2220/66 , B82Y30/00 , C02F1/001 , C02F1/281 , C02F1/288 , C02F2101/32 , C02F2303/18 , C02F2305/08 , Y10T428/25 , Y10T428/252 , Y10T428/256 , Y10T428/258 , Y10T428/259
摘要： Nanoparticle-treated particle packs, such as sand beds, may effectively filter and purify liquids such as waste water. When tiny contaminant particles in waste water flow through the particle pack, the nanoparticles will capture and hold the tiny contaminant particles within the pack due to the nanoparticles' surface forces, including, but not necessarily limited to van der Waals and electrostatic forces. Coating agents such as alcohols, glycols, polyols, vegetable oil, and mineral oils may help apply the nanoparticles to the particle surfaces in the filter beds or packs.
摘要翻译：纳米颗粒处理的颗粒包装，例如砂床，可以有效地过滤和净化诸如废水的液体。当废水中的微小污染物颗粒流过粒子包时，由于纳米颗粒的表面力，纳米颗粒将捕获并保持微粒污染物颗粒，包括但不一定限于范德华力和静电力。包衣剂如醇，二醇，多元醇，植物油和矿物油可以帮助将纳米颗粒施加到过滤床或包装中的颗粒表面。

55. 发明授权

US08551926B2 Stabilizing emulsified acids for carbonate acidizing 有权
公开(公告)号：US08551926B2
公开(公告)日：2013-10-08
申请号：US13781276
申请日：2013-02-28
申请人： Tianping Huang , James B. Crews , John R. Willingham , Richard A. Mitchell , Kushal Seth
发明人： Tianping Huang , James B. Crews , John R. Willingham , Richard A. Mitchell , Kushal Seth
IPC分类号： C09K8/14 , E21B43/16
CPC分类号： C09K8/72 , C09K8/74 , C09K2208/10
摘要： Emulsified acids have been used to increase production rates of oil and gas in carbonate reservoirs through acid fracturing and matrix acidizing operations. An emulsifier is used to emulsify the aqueous acid with an oil, usually diesel. Very small particles, such as colloidal clay particles and/or nanoparticles increase the stability of the emulsified acids over an elevated temperature range.

56. 发明授权

US08550166B2 Self-adjusting in-flow control device 失效
标题翻译：自调节流量控制装置
公开(公告)号：US08550166B2
公开(公告)日：2013-10-08
申请号：US12506810
申请日：2009-07-21
申请人： Richard Yingqing Xu , Tianping Huang
发明人： Richard Yingqing Xu , Tianping Huang
IPC分类号： E21B43/08 , E21B43/14 , E21B34/06
CPC分类号： E21B34/08
摘要： Devices, systems and related methods control a flow of a fluid between a wellbore tubular and a formation using a flow control device having a flow space formed therein; and a flow control element positioned in flow space. The flow control element may be configured to flex between a first radial position and a second radial position to in response to a pressure differential along the flow space.
摘要翻译：装置，系统和相关方法使用具有形成在其中的流动空间的流量控制装置来控制井筒管和地层之间的流体流动; 以及位于流动空间中的流量控制元件。流量控制元件可以被配置为响应于沿着流动空间的压差而在第一径向位置和第二径向位置之间弯曲。

57. 发明授权

US08544565B2 Lost circulation control fluids for naturally fractured carbonate formations 有权
$Lost circulation control fluids for naturally fractured carbonate formations$
标题翻译：天然裂缝碳酸盐岩层的循环控制流体失控
公开(公告)号：US08544565B2
公开(公告)日：2013-10-01
申请号：US12907529
申请日：2010-10-19
申请人： Tianping Huang , James B. Crews , David E. Clark
发明人： Tianping Huang , James B. Crews , David E. Clark
IPC分类号： E21B21/00 , E21B33/138 , C09K8/06
CPC分类号： C09K8/508 , C09K8/12 , C09K2208/30
摘要： Compositions including relatively low reactivity acids and having a pH of from about 2 to about 5, mixed with viscoelastic surfactants (VESs) and internal breakers may serve as fluids, in a non-limiting embodiment as drilling fluids, to open underground hydrocarbon reservoirs with carbonate contents of 10 wt % or above. The fluids initially have low viscosities. After the fluid flows out of the drill bit, the acids react with carbonates in the formation thereby increasing the pH of the fluids causing the VES to gel the fluid at the bottom of the hole and within the formation rock. Even when the subterranean formation contains naturally-occurring fractures, the viscosified fluid will reduce fluid loss into the formation. After drilling through the targeted formation, internal breakers in the viscosified fluids will break down the fluids to permit their removal, and production of the well with very little or no near well bore damage.
摘要翻译：与粘弹性表面活性剂（VES）和内部破碎剂混合的包含相对较低反应性酸和约2至约5的pH的组合物在非限制性实施方案中可用作钻井液，用碳酸盐开放地下储层含量10重量％以上。液体最初具有低粘度。在流体从钻头流出之后，酸与地层中的碳酸盐反应，从而增加流体的pH，导致VES凝结孔底部和地层岩内的流体。即使当地下地层含有天然裂缝时，粘稠流体也会减少流体进入地层的流失。在通过目标地层钻井后，粘稠流体中的内部破碎物将分解流体，以允许其移除，并且井的产生很少或没有接近井眼损坏。

58. 发明授权

US08430165B2 Increasing the viscosity of viscoelastic fluids 有权
标题翻译：增加粘弹性流体的粘度
公开(公告)号：US08430165B2
公开(公告)日：2013-04-30
申请号：US12783190
申请日：2010-05-19
申请人： Tianping Huang , James B. Crews , Gaurav Agrawal
发明人： Tianping Huang , James B. Crews , Gaurav Agrawal
IPC分类号： E21B43/26
CPC分类号： C09K8/68 , C09K8/06 , C09K8/40 , C09K8/506 , C09K8/52 , C09K8/602 , C09K2208/30
摘要： In hydrocarbon recovery applications, viscoelastic surfactant (VES) gelled fluids may be preheated to a temperature that will increase viscosity of the VES gelled fluid. The preheated VES gelled fluid retains at least a portion of its preheated viscosity when cooled such as by introduction into a low temperature condition. In an embodiment, the VES gelled fluid may be a drilling fluid, completion fluid, or fracturing fluid, and the low temperature condition may be an offshore operation, an operation in a locality having a cold climate, and/or a shallow oil, gas, or both land-based operation where the formation temperature is 120° F. or less. The surfactant in the VES gelled fluid may be one or more of an amine, amine salt, quaternary ammonium salt, betaine, amidoamine oxide, amine oxide, and combinations thereof.
摘要翻译：在烃回收应用中，粘弹性表面活性剂（VES）胶凝液体可以预热到将增加VES凝胶流体粘度的温度。预热的VES凝胶流体在冷却时保持其预热粘度的至少一部分，例如通过引入低温条件。在一个实施方案中，VES凝胶化流体可以是钻井液，完井流体或压裂流体，并且低温条件可以是海上操作，具有寒冷气候的区域中的操作和/或浅油，气体或地层温度为120°F以下的陆基作业。 VES凝胶化流体中的表面活性剂可以是胺，胺盐，季铵盐，甜菜碱，酰氨基氧化胺，氧化胺及其组合中的一种或多种。

59. 发明申请

US20130090270A1 Method to Complex Metals in Aqueous Treating Fluids for Ves-Gelled Fluids 有权
标题翻译：用于Ves凝胶液的水处理液中的复合金属的方法
公开(公告)号：US20130090270A1
公开(公告)日：2013-04-11
申请号：US13270025
申请日：2011-10-10
申请人： James B. Crews , Tianping Huang
发明人： James B. Crews , Tianping Huang
IPC分类号： C09K8/68 , C09K8/86 , C09K8/58 , B82Y30/00
CPC分类号： C09K8/665 , B82Y30/00 , C09K8/68 , C09K8/70 , C09K2208/10 , C09K2208/30
摘要： Aqueous treating fluids may include a viscoelastic surfactant (VES) and an aqueous base fluid, e.g. a drilling fluid, whereby the VES may increase and/or maintain the viscosity of the aqueous treating fluid. Metal ions may be present within the aqueous treating fluid that break, reduce, and/or digest the VES within the aqueous treating fluid. An effective amount of complexation particles may be added to the aqueous treating fluid for complexing at least a portion of these metal ions and thereby disallowing the metal ions from breaking, reducing, and/or altering the VES within the aqueous treating fluid.
摘要翻译：水性处理流体可以包括粘弹性表面活性剂（VES）和碱性水溶液，例如水。钻井液，其中VES可以增加和/或维持水性处理流体的粘度。金属离子可能存在于含水处理流体中，破坏，减少和/或消除水处理流体内的VES。可以向水性处理流体中加入有效量的络合颗粒，以使至少一部分这些金属离子络合，从而不允许金属离子破坏，还原和/或改变水处理流体中的VES。

60. 发明申请

US20120247772A1 Method for Isolating and Completing Multi-Zone Gravel Packs 有权
标题翻译：多区砾石包装分离和完井方法
公开(公告)号：US20120247772A1
公开(公告)日：2012-10-04
申请号：US13077422
申请日：2011-03-31
申请人： Tianping Huang , Richard Xu
发明人： Tianping Huang , Richard Xu
IPC分类号： E21B43/14
CPC分类号： E21B27/02 , C04B28/26 , C09K8/46 , C09K8/50 , E21B33/13 , E21B43/04 , C04B24/045 , C04B40/065 , C04B24/04
摘要： A gel barrier may be created within an annulus in a one-step operation by combining two or more solutions within the annulus. The two solutions may include a first solution, such as a silicate solution, and a second solution that may be an aqueous hardener solution. Once the two solutions are combined and subsequently reacted together, the forming of a gel barrier may occur between a plurality of zones along the annulus. The gel barrier may then prevent a fluid from traveling between adjacent zones of the wellbore annulus.
摘要翻译：通过组合环内的两个或更多个溶液，可以在一步操作的环形空间内形成凝胶屏障。两种溶液可以包括第一溶液，例如硅酸盐溶液，和可以是水性固化剂溶液的第二溶液。一旦两种溶液结合并随后一起反应，则形成凝胶屏障可能发生在沿着环的多个区域之间。然后，凝胶屏障可以防止流体在井筒环的相邻区域之间行进。

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