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51. 发明授权

US08057851B2 Ceramic wall cladding composites with electromagnetic shielding properties 有权
标题翻译：陶瓷墙面复合材料具有电磁屏蔽性能
公开(公告)号：US08057851B2
公开(公告)日：2011-11-15
申请号：US12093025
申请日：2006-12-07
申请人： Edwin Nun , Heike Bergandt , Andreas Gutsch , Gerhard Geipel
发明人： Edwin Nun , Heike Bergandt , Andreas Gutsch , Gerhard Geipel
IPC分类号： B05B5/00
CPC分类号： H01Q17/00 , H05K9/0083 , Y10T156/1153 , Y10T428/24926 , Y10T428/256
摘要： The present invention relates to a method for coating substrates, comprising the steps of: a) preparing a substrate, b) applying a composition onto at least one side of the substrate, the composition containing an inorganic compound, the inorganic compound containing at least one metal and/or semimetal selected from the group Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, Tl, Si, Ge, Sn, Zn, Pb, Sb, Bi or mixtures thereof and at least one element selected from the group Te, Se, S, O, Sb, As, P, N, C, Ga or mixtures thereof, and an electrically conductive substance selected from metals, particulate metals, metal alloys, particulate metal alloys, conductive compounds containing carbon or mixtures thereof, c) drying the composition applied in step b), d) applying at least one coating onto the at least one side of the substrate onto which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, where Z1 is R, OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 18 carbon atoms and all R may be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or mixtures thereof, and an initiator, the coating preferably containing 3-aminopropyltrimethoxysilane and/or 3-aminopropyltriethoxysilane and/or N-2-aminoethyl-3-aminopropyltrimethoxysilane, and e) drying the coating applied in step d), as well as to the coated substrate.
摘要翻译：本发明涉及一种涂布基材的方法，包括以下步骤：a）制备基材，b）将组合物施加到基材的至少一侧上，所述组合物含有无机化合物，所述无机化合物含有至少一种金属和/或半金属选自Sc，Y，Ti，Zr，Nb，V，Cr，Mo，W，Mn，Fe，Co，B，Al，In，Tl，Si，Ge，Sn，Zn，Pb ，Sb，Bi或其混合物和选自Te，Se，S，O，Sb，As，P，N，C，Ga或其混合物中的至少一种元素，以及选自金属，颗粒金属，金属合金，颗粒状金属合金，含有碳或其混合物的导电化合物，c）干燥步骤b）中施加的组合物，d）将至少一层涂料施加到其上施用组合物的基材的至少一侧上步骤b），包含通式（Z1）Si（OR）3的硅烷的涂层，其中Z1是R，OR或Gly（Gly = 3-糖基烷氧基丙基），R是具有1至18个碳原子的烷基，所有R可以相同或不同，选自Ti，Si，Zr，Al，Y，Sn，Zn，Ce的氧化物或其混合物的氧化物颗粒，和引发剂，所述涂层优选含有3-氨基丙基三甲氧基硅烷和/或3-氨基丙基三乙氧基硅烷和/或N-2-氨基乙基-3-氨基丙基三甲氧基硅烷，和e）干燥步骤d）中施加的涂层以及涂覆的基材。

52. 发明授权

US5693709A Polyoxymethylene with improved acid stability, process for production and use thereof 失效
标题翻译：具有改善的酸稳定性的聚甲醛，其制备方法和用途
公开(公告)号：US5693709A
公开(公告)日：1997-12-02
申请号：US701800
申请日：1996-08-26
申请人： Edwin Nun , Stephanie Schauhoff , Detlef Arnoldi
发明人： Edwin Nun , Stephanie Schauhoff , Detlef Arnoldi
IPC分类号： C08L59/00 , C08L71/00 , C08L75/04 , C08K5/05
CPC分类号： C08L59/00 , C08L71/00 , C08L75/04
摘要： Polyoxymethylene with improved acid stability, process for production and use thereof. By adding 0.01 to 5 parts of an alkali metal salt of a polybasic acid, for example oxalic acid, citric acid and/or 0.01 to 5 parts of a polyalkylene glycol, for example polyethylene glycol and/or 0.1 to 100 parts of a thermoplastic polyurethane, each related to 100 parts of a polyoxymethylene, this polymer is stabilized against attack by acids, wherein in particular the combination of an alkali metal salt, in particular an oxalate, with small proportions of a thermoplastic polyurethane is advantageous. The proportion of thermoplastic polyurethane may be reduced when the thermoplastic polyurethane has a Shore A hardness of 70 to 96. The weight loss of a stabilized POM under the action of acid may be less than 3% of that of an unstabilized POM. The products are useful when exposed to acidic agents such as irrigation systems, dishwashers, sanitary installations.
摘要翻译：具有改善的酸稳定性的聚甲醛，其制备方法和用途。通过加入0.01至5份多元酸的碱金属盐，例如草酸，柠檬酸和/或0.01至5份聚亚烷基二醇，例如聚乙二醇和/或0.1至100份热塑性聚氨酯各自与100份聚甲醛相关，该聚合物被抗酸侵蚀稳定，其中特别是碱金属盐，特别是草酸盐与小比例的热塑性聚氨酯的组合是有利的。当热塑性聚氨酯的肖氏A硬度为70至96时，热塑性聚氨酯的比例可能会降低。在酸作用下稳定的POM的重量损失可能小于不稳定的POM的重量损失的3％。当暴露于酸性剂如灌溉系统，洗碗机，卫生设备时，该产品是有用的。

53. 发明授权

US5641830A Polyoxymethylene with improved resistance to zinc and/or copper ions, process for the production thereof and use thereof 失效
标题翻译：具有改善的对锌和/或铜离子的耐受性的聚甲醛，其制备方法及其用途
公开(公告)号：US5641830A
公开(公告)日：1997-06-24
申请号：US531412
申请日：1995-09-21
申请人： Edwin Nun , Stephanie Schauhoff , Klaus Dorn
发明人： Edwin Nun , Stephanie Schauhoff , Klaus Dorn
IPC分类号： C08K3/04 , C08K5/13 , C08L59/00 , C08L75/04
CPC分类号： C08L59/00 , C08L75/04
摘要： A polyoxymethylene composition, polyoxymethylene parts, and a process for the production of polyoxymethylene. The polyoxymethylene composition contains one or more polyoxymethylene species, an aqueous anionic polyurethane dispersion, phenolic antioxidant(s), and optionally, colorant, filler, and conventional additives. The composition exhibits improved resistance to non-ferrous metal corrosion.
摘要翻译：聚甲醛组合物，聚甲醛部件，以及生产聚甲醛的方法。聚氧化亚甲基组合物含有一种或多种聚甲醛种类，阴离子聚氨酯水分散体，酚类抗氧化剂和任选的着色剂，填料和常规添加剂。该组合物显示出对有色金属腐蚀性的改善的抗性。

54. 发明授权

US08105656B2 Method for coating substrates 有权
标题翻译：涂布基材的方法
公开(公告)号：US08105656B2
公开(公告)日：2012-01-31
申请号：US12092086
申请日：2006-10-05
申请人： Edwin Nun , Heike Bergandt , Hannelore Armoneit , Marie-Theres Wilkes , Sigrid Banken , Thomas Schrief
发明人： Edwin Nun , Heike Bergandt , Hannelore Armoneit , Marie-Theres Wilkes , Sigrid Banken , Thomas Schrief
IPC分类号： B05D3/02
CPC分类号： D06M11/77 , B05D7/546 , C09D183/04 , C09D183/06 , D06M11/45 , D06M11/46 , D06M11/49 , D06M11/71 , D06M11/78 , D06M11/79 , D06M11/81 , D06M11/83 , D06M13/507 , D06M13/513 , Y10T428/31663
摘要： The present invention relates to a method of coating a substrate, comprising the steps of a) providing a substrate, b) applying a composition to at least one side of the substrate, the composition containing an inorganic compound and the inorganic compound containing at least one metal and/or semimetal selected from the group Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, Tl, Si, Ge, Sn, Zn, Pb, Sb, Bi or a mixture thereof and at least one element selected from the group Te, Se, S, O, Sb, As, P, N, C, Ga or a mixture thereof, c) drying the composition applied in step b), d) applying at least one coating to the at least one side of the substrate to which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, Z1 being R, OR or Gly (Gly is 3-glycidyloxypropyl) and R being an alkyl radical having from 1 to 18 carbon atoms, it being possible for all radicals R to be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or a mixture thereof, a polymer, and an initiator, and e) drying the coating applied in step d), and also to a coated substrate obtainable by the above method.
摘要翻译：本发明涉及一种涂覆基材的方法，包括以下步骤：a）提供基材，b）将组合物施用至基材的至少一侧，所述组合物含有无机化合物和含有至少一种金属和/或半金属选自Sc，Y，Ti，Zr，Nb，V，Cr，Mo，W，Mn，Fe，Co，B，Al，In，Tl，Si，Ge，Sn，Zn，Pb ，Sb，Bi或其混合物和选自Te，Se，S，O，Sb，As，P，N，C，Ga或其混合物中的至少一种元素，c）干燥步骤b ），d）在步骤b）中将至少一个涂层施加到其上施加组合物的基材的至少一侧，所述涂层含有通式（Z1）Si（OR）3的硅烷，Z1为R ，OR或Gly（Gly是3-缩水甘油氧基丙基），R是具有1至18个碳原子的烷基，所有基团R可以相同或不同，选自氧化物的氧化物颗粒的Ti，Si，Zr，Al，Y，Sn，Zn，Ce或其混合物，聚合物和引发剂，以及e）干燥步骤d）中施加的涂层，以及可以由上述方法。

55. 发明申请

US20080292799A1 Production of Coated Substrates 有权
标题翻译：涂层基材的生产
公开(公告)号：US20080292799A1
公开(公告)日：2008-11-27
申请号：US12092084
申请日：2006-08-10
申请人： Edwin Nun , Heike Bergandt , Hannelore Armoneit , Marie-Theres Wilkes , Thomas Schrief
发明人： Edwin Nun , Heike Bergandt , Hannelore Armoneit , Marie-Theres Wilkes , Thomas Schrief
IPC分类号： B05D3/02
CPC分类号： C09D183/06 , C09D183/04 , C09D183/08 , C08L2666/72 , C08L2666/36 , C08L2666/34
摘要： The present invention relates to a process for coating substrates, which comprises the steps: a) provision of a substrate, b) application of a composition to at least one surface of the substrate, the composition comprising a silane of the general formula (Z1)Si(OR3), where Z1 is OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 6 carbon atoms and all radicals R can be identical or different, an inert solvent and an initiator and the inert solvent having a boiling point under the drying conditions of step c) which is in a range from 50° C. above to 50° C. below the drying temperature of step c) and the boiling point of the inert solvent under the drying conditions of step c) being at least 80° C., and c) drying of the composition applied in step b) at a drying temperature of from 100° C. to 250° C., and also to a coated substrate obtainable by means of the abovementioned process.
摘要翻译：本发明涉及一种用于涂覆基材的方法，其包括以下步骤：a）提供基材，b）将组合物施用于基材的至少一个表面，所述组合物包含通式（Z1）的硅烷， Si（OR 3），其中Z 1为OR或Gly（Gly = 3-缩水甘油氧基丙基），R为具有1至6个碳原子的烷基，所有基团R可以相同或不同，惰性溶剂和引发剂和惰性在步骤c）的干燥条件下具有沸点的溶剂在低于步骤c）的干燥温度的50℃以上至50℃的范围内，并且在干燥条件下的惰性溶剂的沸点步骤c）为至少80℃，和c）在100℃至250℃的干燥温度下干燥步骤b）中所用的组合物，并且还可以通过使用上述过程。

56. 发明申请

US20080280148A1 Method for Coating Substrates 有权
标题翻译：涂层基材的方法
公开(公告)号：US20080280148A1
公开(公告)日：2008-11-13
申请号：US12092086
申请日：2006-10-05
申请人： Edwin Nun , Heike Bergandt , Hannelore Armoneit , Marie-Theres Wilkes , Sigrid Banken , Thomas Schrief
发明人： Edwin Nun , Heike Bergandt , Hannelore Armoneit , Marie-Theres Wilkes , Sigrid Banken , Thomas Schrief
IPC分类号： B05D7/00 , B32B27/14
CPC分类号： D06M11/77 , B05D7/546 , C09D183/04 , C09D183/06 , D06M11/45 , D06M11/46 , D06M11/49 , D06M11/71 , D06M11/78 , D06M11/79 , D06M11/81 , D06M11/83 , D06M13/507 , D06M13/513 , Y10T428/31663
摘要： The present invention relates to a method of coating a substrate, comprising the steps of a) providing a substrate, b) applying a composition to at least one side of the substrate, the composition containing an inorganic compound and the inorganic compound containing at least one metal and/or semimetal selected from the group Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, TI, Si, Ge, Sn, Zn, Pb, Sb, Bi or a mixture thereof and at least one element selected from the group Te, Se, S, O, Sb, As, P, N, C, Ga or a mixture thereof, c) drying the composition applied in step b), d) applying at least one coating to the at least one side of the substrate to which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, Z1 being R, OR or Gly (Gly is 3-glycidyloxypropyl) and R being an alkyl radical having from 1 to 18 carbon atoms, it being possible for all radicals R to be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or a mixture thereof, a polymer, and an initiator, and e) drying the coating applied in step d), and also to a coated substrate obtainable by the above method.
摘要翻译：本发明涉及一种涂覆基材的方法，包括以下步骤：a）提供基材，b）将组合物施用至基材的至少一侧，所述组合物含有无机化合物和含有至少一种金属和/或半金属选自Sc，Y，Ti，Zr，Nb，V，Cr，Mo，W，Mn，Fe，Co，B，Al，In，TI，Si，Ge，Sn，Zn，Pb ，Sb，Bi或其混合物和选自Te，Se，S，O，Sb，As，P，N，C，Ga或其混合物中的至少一种元素，c）干燥步骤b ），d）在步骤b）中向组合物施加至少一个涂层至所述基材的至少一侧，所述涂层含有通式（Z 1）Si的硅烷（OR）3，Z 1是R，OR或Gly（Gly是3-缩水甘油氧基丙基），R是具有1至18个碳原子的烷基，它是所有基团R可能相同或不同，氧化物p 选自Ti，Si，Zr，Al，Y，Sn，Zn，Ce或其混合物的氧化物的物质，聚合物和引发剂，以及e）干燥步骤d）中施加的涂层，以及涂覆底物可通过上述方法获得。

57. 发明申请

US20060235143A1 Process for producing detachable dirt- and water-repellent surface coatings 有权
公开(公告)号：US20060235143A1
公开(公告)日：2006-10-19
申请号：US11451868
申请日：2006-06-13
申请人： Felix Muller , Edwin Nun , Patrick Winter
发明人： Felix Muller , Edwin Nun , Patrick Winter
IPC分类号： C08L83/04 , C04B41/49 , C03C25/24 , C23C16/40 , C04B28/26
CPC分类号： B08B17/06 , B08B17/065 , C03C17/007 , C03C2217/475 , C03C2217/76 , C04B20/10 , C04B26/32 , C04B2111/00482 , C04B2111/203 , C04B2111/27 , C08K3/013 , C09D183/04 , C09K3/18 , C14C9/00 , Y02W30/94 , C04B14/30 , C04B14/305 , C04B18/146 , C04B20/008 , C08L83/00 , C08L2666/54
摘要： Process for producing detachable dirt- and water-repellent surface coatings on articles, wherein during the coating process, hydrophobic particles are applied to the surface of the articles, thus generating a surface structure with elevations on that surface of the articles that has dirt- and water-repellent properties, which comprises suspending the hydrophobic particles in a solution of a silicone wax in a highly volatile siloxane, and applying this suspension to at least one surface of an article, and then removing the highly volatile siloxane.

58. 发明授权

US5541284A Method for processing crude polyoxymethylene 失效
标题翻译：粗聚甲醛加工方法
公开(公告)号：US5541284A
公开(公告)日：1996-07-30
申请号：US406141
申请日：1995-03-20
申请人： Detlef Arnoldi , Udo Gropp , Edwin Nun
发明人： Detlef Arnoldi , Udo Gropp , Edwin Nun
IPC分类号： C08G2/28 , C08G2/10
CPC分类号： C08G2/28
摘要： The subject invention relates to method for processing crude polyoxymethylene in which the isolation of unstable components from crude polyoxymethylene, such as residual monomers which are at least partly in the form of cyclic formaldehyde derivatives, is effected by treatment of the crude polyoxymethylene with an inert gaseous medium. The method of the invention is characterized in that the gaseous medium contains at least 10 volume % of water vapor, and less than 0.1 volume % of a volatile base, and/or less than 1 volume % of a volatile solvent. In an alternative variant method, the gaseous medium contains at least 10 volume % of water vapor and the treatment occurs at a temperature between 114.degree. C and the softening temperature of the crude polyoxymethylene and at a pressure of less 1.2 .multidot.10.sup.5 Pa.
摘要翻译：本发明涉及用于处理粗聚甲醛的方法，其中从粗聚甲醛分离不稳定组分，例如至少部分为环状甲醛衍生物形式的残留单体，其通过用惰性气体处理粗聚甲醛来实现中。本发明的方法的特征在于，气态介质含有至少10体积％的水蒸气和少于0.1体积％的挥发性碱，和/或少于1体积％的挥发性溶剂。在另一变体方法中，气体介质含有至少10体积％的水蒸气，并且处理在114℃和粗聚甲醛的软化温度之间并且在1.2×10 5 Pa以下的压力下进行。

59. 发明授权

US5393813A Polyoxymethylene having improved acid stability 失效
标题翻译：具有改善的酸稳定性的聚甲醛
公开(公告)号：US5393813A
公开(公告)日：1995-02-28
申请号：US140357
申请日：1993-10-22
申请人： Stephanie Schauhoff , Edwin Nun , Detlef Arnoldi
发明人： Stephanie Schauhoff , Edwin Nun , Detlef Arnoldi
IPC分类号： C08K5/09 , C08K5/3477 , C08K5/3492 , C08L59/00 , C08L61/28 , C08L71/02 , C08L75/04 , C08J5/10 , C08K5/34 , C08L59/02
CPC分类号： C08K5/34924 , C08L59/00 , C08L61/28 , C08L71/02 , C08L75/04
摘要： By adding melamine cyanurate, polyoxymethylene is stabilized against acid attack, wherein in particular as little as under 3 parts of MCA per 100 parts of POM are effective. The weight loss of a stabilized POM under the action of acid may be less than 3% of that of an unstabilized POM. The product is useful in products which are exposed to acidic agents such as irrigation systems, dishwashers, sanitary installations.
摘要翻译：通过加入三聚氰胺氰尿酸酯，聚甲醛稳定，防止酸侵蚀，其中特别是每100份POM少于3份MCA的有效性。在酸作用下稳定的POM的重量损失可能小于不稳定的POM的失重量的3％。该产品适用于暴露于酸性剂（如灌溉系统，洗碗机，卫生设备）的产品中。

60. 发明授权

US09096041B2 Method for coating substrates and carrier substrates 有权
标题翻译：涂布基材和载体基材的方法
公开(公告)号：US09096041B2
公开(公告)日：2015-08-04
申请号：US13402639
申请日：2012-02-22
申请人： Edwin Nun , Michael Vetter , Martin Wille
发明人： Edwin Nun , Michael Vetter , Martin Wille
IPC分类号： B32B33/00 , B32B37/12 , B32B37/24
CPC分类号： B32B33/00 , B32B37/12 , B32B2037/243 , B32B2607/00 , Y10T156/10 , Y10T428/31663
摘要： The present invention relates to a method for coating substrates, including applying a composition to a first side of the substrate, the composition containing an inorganic compound, drying the applied composition, applying at least one coating to the first side of the substrate to which the composition is applied, the coating containing a silane, drying the applied coating, and applying at least one barrier layer to a second side of the substrate.
摘要翻译：本发明涉及一种涂布基材的方法，包括将组合物施用到基材的第一面，含有无机化合物的组合物，干燥所施加的组合物，将至少一层涂布施加到基材的第一侧，涂覆组合物，所述涂层含有硅烷，干燥所涂覆的涂层，以及将至少一个阻挡层施加到所述基材的第二侧。

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