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51. 发明授权

US5885763A Method for the preparation of an improved photographic tabular emulsion rich in chloride 失效
标题翻译：用于制备富含氯化物的改进的照相片状乳液的方法
公开(公告)号：US5885763A
公开(公告)日：1999-03-23
申请号：US956362
申请日：1997-10-23
申请人： Peter Verrept , Hieronymus Andriessen
发明人： Peter Verrept , Hieronymus Andriessen
IPC分类号： G03C1/00 , G03C1/005 , G03C1/015 , G03C1/035 , G03C1/047 , G03C5/16
CPC分类号： G03C1/0053 , G03C1/047 , G03C5/16 , Y10S430/167
摘要： A method is disclosed of preparing of a photographic silver halide emulsion comprising precipitating in one or more precipitation steps in a reaction vessel, followed by desalting by means of flocculation and washing or by means of ultrafiltration, said emulsion comprising gelatin as a binder and {100} tabular silver halide grains containing at least 50 mole % of chloride, wherein at least 40% by number of all grains is provided by said tabular grains, and wherein said tabular grains exhibit an average aspect ratio of at least 2, an average thickness of at most 0.5 .mu.m, and an average equivalent circular crystal diameter of 0.3 .mu.m or more, characterized in that during said precipitation step(s) said gelatin binder present in said reaction vessel is substantially free of calcium ions and is oxidized to a degree in order to have a methionine content of at most 4000 ppm.
摘要翻译：公开了一种制备照相卤化银乳剂的方法，其包括在反应容器中的一个或多个沉淀步骤中沉淀，然后通过絮凝和洗涤或通过超滤脱盐，所述乳液包含明胶作为粘合剂和{100 }含有至少50摩尔％氯化物的片状卤化银颗粒，其中由所述片状颗粒提供至少40％的全部颗粒，并且其中所述片状颗粒的平均纵横比至少为2，平均厚度为至多0.5μm，平均当量圆形结晶直径为0.3μm以上，其特征在于，在所述沉淀步骤中，存在于所述反应容器中的所述明胶粘合剂基本上不含钙离子并被氧化至一定程度以使甲硫氨酸含量在4000ppm以下。

52. 发明授权

US5712081A Method for reproducing an electronically stored medical image on a hardcopy material 失效
标题翻译：用于在硬拷贝材料上再现电子存储的医学图像的方法
公开(公告)号：US5712081A
公开(公告)日：1998-01-27
申请号：US812265
申请日：1997-03-06
申请人： Hieronymus Andriessen , Freddy Henderickx
发明人： Hieronymus Andriessen , Freddy Henderickx
IPC分类号： G03C5/08 , A61B5/00 , G03C1/00 , G03C1/035 , G03C1/047 , G03C1/09 , G03C1/12 , G03C1/30 , G03C1/74 , G03C5/16 , G03C5/26 , G03C5/29 , G03C5/30 , G03C5/305 , G03C5/31
CPC分类号： G03C5/26 , G03C1/035 , G03C1/09 , G03C5/164
摘要： A method of reproducing an electronically stored medical image on a hardcopy material is disclosed, said material comprising a support and on only one side thereof a silver halide emulsion layer and a hydrophilic colloid layer, wherein said emulsion layer comprises red sensitized homogeneous cubic silver chloride, silver chloroiodide, silver chlorobromide or silver chlorobromoiodide crystals having not less than 70 mole % of chloride ions and preferably not less than 90 mole %; not more than 1 mole % of iodide ions and an average crystal size of from 0.12 to 0.30 .mu.m and more preferred from 0.15 to 0.25 .mu.m; wherein said crystals are coated in an amount, expressed as an equivalent amount of silver nitrate of from 2 to 6 g per sq.m., and wherein said material has a hardening degree corresponding with a water absorption of up to 3 g per gram of gelatin at an emulsion side, the said water absorption being measured by the method disclosed herein; said method of image formation being characterized by the steps of image-wise exposure of said material with an electronically adressed red or infrared laser followed by development processing in a developer free from hardening agents in less than 20 seconds in a total processing time from 30 to 50 seconds from dry to dry, wherein said developer contains a compound corresponding to formula (I) given herein, a precursor thereof, a derivative thereof and/or a metal salt thereof, being more preferably (iso)ascorbic acid; replenishing said developer in an amount of not more than 100 ml per square meter of developed material; fixing said developer in a time from 2 to 10 seconds; rinsing and drying.
摘要翻译：公开了一种在硬拷贝材料上再现电子存储的医学图像的方法，所述材料包括支撑体，并且仅在其一侧上具有卤化银乳剂层和亲水胶体层，其中所述乳剂层包含红色敏化的均匀立方氯化银，氯氯化银，氯溴化银或氯代溴碘化银晶体，不少于70摩尔％的氯离子，优选不低于90摩尔％; 不大于1摩尔％的碘离子，平均晶体尺寸为0.12至0.30微米，更优选为0.15至0.25微米; 其中所述晶体的涂覆量以每平方米2至6g的硝酸银的当量表示，并且其中所述材料具有对应于每克高达3g的吸水率高达3g的硬化度所述吸水性通过本文公开的方法测量; 所述图像形成方法的特征在于以下步骤：通过电子加载的红色或红外激光以图像方式曝光所述材料，然后在不超过20秒的显影剂中在不含硬化剂的显影处理下，在总处理时间为30至 50秒，从干到干，其中所述显影剂含有对应于本文给出的式（I）的化合物，其前体，其衍生物和/或其金属盐，更优选（异）抗坏血酸; 以每平方米开发材料不超过100毫升的方式补充该开发商; 在2到10秒的时间内固定开发人员; 冲洗和干燥。

53. 发明授权

US5604082A Method for processing an exposed photographic silver halide material 失效
标题翻译：处理曝光的照相卤化银材料的方法
公开(公告)号：US5604082A
公开(公告)日：1997-02-18
申请号：US594722
申请日：1996-01-31
申请人： Freddy Henderickx , Hieronymus Andriessen , Ann Verbeeck
发明人： Freddy Henderickx , Hieronymus Andriessen , Ann Verbeeck
IPC分类号： G03C5/29 , G03C1/005 , G03C1/035 , G03C5/30 , G03C5/305
CPC分类号： G03C1/0053 , G03C5/305 , G03C2200/01 , G03C2200/03 , G03C5/30
摘要： A method has been disclosed of processing an exposed silver halide photographic material comprising at least one coated hydrophilic silver halide emulsion layer comprising tabular grains rich in chloride, bounded by [100] or [111] major faces, characterized by the steps of developing, followed by fixing, rinsing and drying the said material, wherein developing proceeds in a developer, comprising hydroquinone in an amount from 0 to 30 g per liter, an auxiliary developer, as silver halide complexing agents alkali metal sulphite salts in an amount from 1 to 50 g per liter, at least 1 g of a compound corresponding to the formula (I), a precursor thereof, a derivative thereof and/or a metal salt thereof ##STR1## wherein the substituents are defined in the main embodiment of the specification.
摘要翻译：已经公开了一种处理曝光的卤化银照相材料的方法，该材料包含至少一个涂覆的亲水性卤化银乳剂层，其包含由[100]或[111]主面限定的富含氯化物的片状颗粒，其特征在于以下步骤：通过固定，漂洗和干燥所述材料，其中显影在显影剂中进行，其包含量为0至30g /升的对苯二酚，辅助显影剂，卤化银配合剂碱金属亚硫酸盐，其量为1至50 g，至少1g对应于式（I）的化合物，其前体，其衍生物和/或其金属盐，其中取代基在主要实施方案中定义规范。

54. 发明授权

US08313885B2 Lithographic printing plate precursor comprising bi-functional compounds 有权
标题翻译：含有双功能化合物的平版印刷版前体
公开(公告)号：US08313885B2
公开(公告)日：2012-11-20
申请号：US11546830
申请日：2006-10-12
申请人： Johan Loccufier , Hieronymus Andriessen
发明人： Johan Loccufier , Hieronymus Andriessen
IPC分类号： G03F7/00 , G03F7/26
CPC分类号： B41C1/1041
摘要： A heat-sensitive lithographic printing plate precursor comprising on a grained and anodized aluminum support a compound which is capable of converting form a hydrophobic state to a hydrophilic state or vice versa upon exposure to heat, and is represented by the following formula: A-(L)n-B wherein L represents a linking group, n represents 0 or 1 and B represents a thermo-labile group; characterized in that the compound further comprises the group A which is a functional group capable of interacting with the surface of a grained and anodized aluminum support and is selected from the list consisting of a halosilanyl group, an alkoxysilanyl group, a phosphonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a salicylic acid group or a salt thereof, a boronic acid group or an ester or a salt thereof, an optionally substituted di or tri-hydroxyaryl group, an optionally substituted salicaldoxime group, an optionally substituted salicaldimine group, an optionally substituted hydroxyheteroaryl group, an amidine group, a 1,3-dicarbonyl group or a group represented by the formula (i) wherein Q and Z independently represent the necessary atoms to form an optionally substituted five or six membered aromatic or heteroaromatic ring.
摘要翻译：包含在颗粒和阳极氧化铝上的热敏平版印刷版原版支持能够在暴露于热后将其形成疏水状态或反之亦然的化合物，并由下式表示：A-（ L）nB其中L表示连接基团，n表示0或1，B表示热不稳定基团; 其特征在于，所述化合物还包含基团A，其是能够与粒状和阳极氧化的铝载体的表面相互作用的官能团，并且选自卤代西兰基，烷氧基硅烷基，膦酸基或其盐，磷酸基或其盐，水杨酸基或其盐，硼酸基或其酯或其盐，任选取代的二或三羟基芳基，任选取代的salicaldoxime基团，任选取代的水杨基，任选取代的羟基杂芳基，脒基，1,3-二羰基或由式（ⅰ）表示的基团，其中Q和Z独立地表示必要的原子以形成任选被取代的五或六元芳族或杂芳族环。

55. 发明授权

US07118836B2 Process for preparing a substantially transparent conductive layer configuration 有权
标题翻译：制备基本上透明的导电层构型的方法
公开(公告)号：US07118836B2
公开(公告)日：2006-10-10
申请号：US10644043
申请日：2003-08-19
申请人： Hieronymus Andriessen
发明人： Hieronymus Andriessen
IPC分类号： G03C1/04 , G03C8/28 , G03C8/32 , G03C5/26 , H01C13/00
CPC分类号： G03C1/89 , C08G61/126 , G03C1/035 , G03C1/047 , G03C2007/3025 , G03C2200/27 , H01B1/127 , H01G11/48 , H01L51/0021 , H01L51/0037 , H01L51/445 , Y02E10/549 , Y02E60/13
摘要： A substantially transparent conductive layer on a support, the layer comprising an intrinsically conductive polymer e.g. containing an intrinsically conductive polymer optionally containing structural units represented by formula (I): wherein n is larger than 1 and each of R1 and R2 independently represents hydrogen or an optionally substituted C1-4 alkyl group or together represent an optionally substituted C1-4 alkylene group or an optionally substituted cycloalkylene group, preferably an ethylene group, an optionally alkyl-substituted methylene group, an optionally C1-12 alkyl- or phenyl-substituted ethylene group, a 1,3-propylene group or a 1,2-cyclohexylene group; and a conductive metal non-uniformly distributed therein and forming of itself a conductive entity; a process for preparing the transparently conductive layer; and light emitting diodes, photovoltaic devices, transistors and electroluminescent devices comprising the above-described conductive layer.
摘要翻译：支撑体上的基本上透明的导电层，该层包含固有导电聚合物含有任选含有由式（I）表示的结构单元的固有导电性聚合物：其中n大于1且R 1和R 2各自独立地表示氢或任选地取代的C 1-4烷基或一起代表任选取代的C 1-4 - 亚烷基或任选取代的亚环烷基，优选亚乙基，任选烷基取代的亚甲基，任选的C 1-12烷基或苯基取代的亚乙基，1,3-亚丙基或1,2-亚环己基; 以及不均匀分布在其中的导电金属，并且自身形成导电实体; 制备透明导电层的方法; 以及包括上述导电层的发光二极管，光电器件，晶体管和电致发光器件。

56. 发明授权

US07056600B2 Layer configuration comprising an electron-blocking element 失效
标题翻译：层结构包括电子阻挡元件
公开(公告)号：US07056600B2
公开(公告)日：2006-06-06
申请号：US10638918
申请日：2003-08-11
申请人： Hieronymus Andriessen
发明人： Hieronymus Andriessen
IPC分类号： C07D211/02
CPC分类号： H01B1/127 , C09K11/06 , C09K2211/1441 , H01G11/48 , H01G11/56 , H01L51/0037 , Y02E10/549 , Y02E60/13 , Y10S428/917
摘要： A layer configuration on a support, the layer configuration comprising a non-photoactive element exclusive of poly(3,4-alkylenedioxythiophene)s and poly(3,4-dialkoxythiophene)s, the element containing a first polymer containing structural units according to formula (I): in which X and Y are independently O, S, N—R1, Z is —(CH2)m—CR2R3—(CH2)n—; R1 is aryl, C1-18-alkyl or hydrogen; R2 is hydrogen or —(CH2)s—O—(CH2)p—SO3−M+; R3 is —(CH2)s—O—(CH2)p—SO3−M+; M+ is a cation; m and n are independently a whole number from 0 to 3; s is a whole number from 0 to 10; and p is a whole number from 1 to 18, and a second polymer different from the first polymer and selected from the group consisting of optionally quaternized polyamine-polymers, polysulpho-polymers, polyphosphoric acids and polyphosphoric acid salts, the surface of one side of the element being contiguous with a positive electrode and the surface on the opposite side of the element being contiguous with a material capable of transporting holes.
摘要翻译：在载体上的层构型，该层构型包括不含聚（3,4-亚烷基二氧噻吩）的非光活性元素和聚（3,4-二烷氧基噻吩），该元素含有含有根据式（I）：其中X和Y独立地为O，S，NR 1，Z为 - （CH 2 CH 2）m - （CH 2）n - （CH 2）n - R 1是芳基，C 1-18 - 烷基或氢; R 2是氢或 - （CH 2 CH 2）n -O-（CH 2）2 3 3 + R 3是 - （CH 2）2 - （CH 2）2 - （CH 2） 3→3 + M + +是阳离子; m和n分别为0〜3的整数; s是从0到10的整数; 和p为1至18的整数，和不同于第一聚合物并选自任选季铵化聚胺聚合物，多聚磷酸聚合物，多磷酸和多磷酸盐的第二聚合物，其一面的表面所述元件与正电极连接，并且所述元件的相对侧上的表面与能够传输孔的材料邻接。

57. 发明授权

US07026079B2 Process for preparing a substantially transparent conductive layer configuration 失效
标题翻译：制备基本上透明的导电层构型的方法
公开(公告)号：US07026079B2
公开(公告)日：2006-04-11
申请号：US10645160
申请日：2003-08-21
申请人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
发明人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
IPC分类号： G03C1/89 , G03C5/29 , G03C8/28 , G03C8/52 , G03C8/32
CPC分类号： H05K3/106 , H01B1/127 , H01B1/22 , H01L51/0021 , H01L51/0037 , H01L51/445 , H01L51/5203 , H05K2201/0329 , Y02E10/549
摘要： A process for preparing a substantially transparent conductive layer configuration on a support, the layer configuration comprising in any order at least a first layer containing an intrinsically conductive polymer optionally containing structural units represented by formula (I): wherein n is larger than 1 and each of R1 and R2 independently represents hydrogen or an optionally substituted C1-4 alkyl group or together represent an optionally substituted C1-4 alkylene group or an optionally substituted cycloalkylene group, preferably an ethylene group, an optionally alkyl-substituted methylene group, an optionally C1-12 alkyl- or phenyl-substituted ethylene group, a 1,3-propylene group or a 1,2-cyclohexylene group; and a second layer consisting of a non-continuous layer of conductive silver, the process comprising the step of: preparing the second layer by a photographic process; and light emitting diodes, photovoltaic devices, transistors and electroluminescent devices comprising a layer configuration prepared according to this process.
摘要翻译：一种用于在载体上制备基本上透明的导电层构型的方法，所述层构型至少包含含有本发明的导电聚合物的第一层，所述第一层含有任选含有由式（I）表示的结构单元的固有导电聚合物：其中n大于1， R 1和R 2独立地表示氢或任选取代的C 1-4烷基，或者一起表示任选取代的C 1 -C 4烷基， 1-4个亚烷基或任选取代的亚环烷基，优选亚乙基，任选烷基取代的亚甲基，任选的C 1-12烷基或苯基取代的亚乙基，1,3-亚丙基或1,2-亚环己基; 以及由不连续的导电银层组成的第二层，该方法包括以下步骤：通过摄影法制备第二层; 以及发光二极管，光电器件，晶体管和电致发光器件，其包括根据该工艺制备的层构型。

58. 发明授权

US06977390B2 Layer configuration comprising an electron-blocking element 失效
标题翻译：层结构包括电子阻挡元件
公开(公告)号：US06977390B2
公开(公告)日：2005-12-20
申请号：US10641381
申请日：2003-08-14
申请人： Hieronymus Andriessen
发明人： Hieronymus Andriessen
IPC分类号： C08G61/12 , C08G73/02 , C08G73/06 , C09K11/06 , C09K11/54 , C09K11/56 , C09K11/77 , H01B1/12 , H01L51/00 , H01L51/05 , H01L51/30 , H01L51/42 , H01L51/50 , H05B33/14 , H05B33/22 , H01L35/24
CPC分类号： H05B33/22 , C08G61/126 , C08G73/0266 , C08G73/0611 , C09K11/06 , C09K11/54 , C09K11/565 , C09K11/7716 , H01B1/127 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0042 , H01L51/0059 , H01L51/0504 , H01L51/42 , H01L51/5096 , H05B33/14 , Y02E10/549
摘要： A layer configuration on a support, the layer configuration comprising a non-photoactive element exclusive of poly(3,4-alkylenedioxythiophene)s, poly(3,4-dialkoxythiophene)s, polyanilines and polypyrroles, said element containing at least one polymer selected from the group consisting of polysulphato-polymers and polysulpho-polymers, the surface of one side of the element being contiguous with a positive electrode and the surface on the opposite side of the element being contiguous with a material capable of transporting holes.
摘要翻译：在支撑体上的层结构，该层结构包括不含聚（3,4-亚烷基二氧噻吩）的非光活性元素，聚（3,4-二烷氧基噻吩），聚苯胺和聚吡咯，所述元素含有至少一种选自由聚硫聚合物和多聚聚合物构成的组中，元件的一侧的表面与正极相邻，并且元件的相反侧的表面与能够传输孔的材料邻接。

59. 发明授权

US06927298B2 3,4-alkylenedioxythiophenedioxide compounds and polymers comprising monomeric units thereof 失效
标题翻译： 3,4-亚烷基二氧基噻吩二氧化物化合物和包含其单体单元的聚合物
公开(公告)号：US06927298B2
公开(公告)日：2005-08-09
申请号：US10649761
申请日：2003-08-27
申请人： Bert Groenendaal , Frank Louwet , Hieronymus Andriessen
发明人： Bert Groenendaal , Frank Louwet , Hieronymus Andriessen
IPC分类号： C07D333/36 , C07D333/64 , C07D495/02 , C07D495/04 , C08G61/12 , C08G65/34 , C08G75/00 , C08G75/32
CPC分类号： C07D495/04 , C08G61/126 , H01G11/48 , Y02E60/13
摘要： A 3,4-alkylenedioxythiophenedioxide compound represented by formula (I): in which: A represents a C1-5-alkylene bridge; R represents an optionally substituted C1-24-alkyl, C3-18-cycloalkyl, C1-18-alkoxy or polyethylene oxide group (optionally with at least one substituent selected from the group consisting of an alcohol, amide, ether, ester or sulphonate group) or an optionally substituted aryl group; a polymer comprising monomeric units represented by formula (I); an aqueous dispersion of a polymer comprising monomeric units corresponding to at least one compound according to formula (I) and a polyanion; a chemical polymerization process for preparing the aqueous dispersion comprising the steps of: (i) providing a solution of a polyanion; (ii) adding a compound according to formula (I) and a thiophene or pyrrole compound to the solution provided in step (i); and (iii) adding an oxidizing or reducing system to the mixture provided in step (ii); a printable paste containing the aqueous dispersion; an electroconductive layer containing the polymer; the use of the electroconductive layer in a light emitting diode; an antistatic layer containing the polymer; and an electroconductive pattern and a process for preparing the electroconductive pattern.
摘要翻译：由式（I）表示的3,4-亚烷基二氧基噻吩二氧化物化合物：其中：A表示C 1-5烷基亚烷基桥; R代表任选取代的C 1-14 - 烷基，C 3-18 - 环烷基，C 1-18 - 烷氧基或聚环氧乙烷基（任选地具有至少一个选自醇，酰胺，醚，酯或磺酸酯基的取代基）或任选取代的芳基; 包含由式（I）表示的单体单元的聚合物; 包含对应于至少一种根据式（I）的化合物和聚阴离子的单体单元的聚合物的水分散体; 用于制备水分散体的化学聚合方法，包括以下步骤：（i）提供聚阴离子的溶液; （ii）将式（I）化合物和噻吩或吡咯化合物加入到步骤（i）中提供的溶液中; 和（iii）向步骤（ii）中提供的混合物中加入氧化或还原体系; 含有水分散体的可印刷浆料; 含有聚合物的导电层; 在发光二极管中使用导电层; 含有聚合物的抗静电层; 导电图案和制备导电图案的方法。

60. 发明授权

US06911081B2 Preparation of metal chalcogenide dispersions 失效
标题翻译：金属硫族化物分散体的制备
公开(公告)号：US06911081B2
公开(公告)日：2005-06-28
申请号：US10053104
申请日：2002-01-24
申请人： Hieronymus Andriessen
发明人： Hieronymus Andriessen
IPC分类号： C09K11/57 , C09K11/58 , C09K11/88 , C30B7/04
CPC分类号： C09K11/574 , C09K11/584 , C09K11/883 , Y10S977/773
摘要： Optionally doped nanoparticle dispersions of metal chalcogenides are prepared by a precipitation step in aqueous medium, followed by a diafiltration or ultrafiltration step in the presence of a compound capable of preventing agglomeration of said metal chalcogenide nanoparticles.
摘要翻译：金属硫族化物的任选掺杂的纳米颗粒分散体通过在水性介质中的沉淀步骤制备，然后在能够防止所述金属硫族化物纳米颗粒的附聚的化合物存在下进行渗滤或超滤步骤。

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