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51. 发明申请

US20100279855A1 Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof 有权
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US20100279855A1
公开(公告)日：2010-11-04
申请号：US12432721
申请日：2009-04-29
申请人： Dennis Dykstra , Theodorus Maesen , Alexander E. Kuperman , Soy Uckung , Darren Fong
发明人： Dennis Dykstra , Theodorus Maesen , Alexander E. Kuperman , Soy Uckung , Darren Fong
IPC分类号： B01J31/04 , B01J27/051
CPC分类号： B01J23/8885 , B01J23/24 , B01J23/85 , B01J35/1076 , B01J37/0009 , B01J37/0018 , B01J37/031 , B01J37/20 , C10G45/00
摘要： A stable catalyst with low volumetric shrinkage and a process for making the stable catalyst with low volumetric shrinkage is disclosed. The catalyst is made by sulfiding a catalyst precursor containing at least a Group VIB metal compound; at least a promoter metal compound selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, having an oxidation state of either +2 or +4; optionally at least a ligating agent; optionally at least a diluent. In the process of making the catalyst, the catalyst precursor is first shaped then heat treated at a temperature of 50° C. to 200° C. for about 15 minutes to 12 hours, wherein the catalyst precursor still has a low (less than 12%) volumetric shrinkage after exposure to a temperature of at least 100° C.
摘要翻译：公开了具有低体积收缩率的稳定催化剂和制备具有低体积收缩率的稳定催化剂的方法。催化剂是通过硫化至少含有VIB族金属化合物的催化剂前体制成的; 至少一种选自具有+2或+4的氧化态的VIII族，IIB族，IIA族，IVA族及其组合的助催化剂金属化合物; 任选地至少一种结合剂; 任选地至少一种稀释剂。在制备催化剂的过程中，首先将催化剂前体成型，然后在50℃至200℃的温度下热处理约15分钟至12小时，其中催化剂前体仍然具有低（小于12 ％）暴露于至少100℃的温度后的体积收缩率

52. 发明申请

US20100279851A1 Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof 有权
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US20100279851A1
公开(公告)日：2010-11-04
申请号：US12432730
申请日：2009-04-29
申请人： Alexander E. Kuperman , Theodorus Maesen , Dennis Dykstra , Soy Uckung , Darren Fong
发明人： Alexander E. Kuperman , Theodorus Maesen , Dennis Dykstra , Soy Uckung , Darren Fong
IPC分类号： B01J31/04
CPC分类号： B01J37/031 , B01J23/002 , B01J23/24 , B01J23/652 , B01J23/85 , B01J23/8885 , B01J31/0239 , B01J31/0268 , B01J31/04 , B01J31/2226 , B01J35/0026 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1071 , B01J35/1085 , B01J37/0009 , B01J37/0018 , B01J37/20 , B01J2523/00 , B01J2531/64 , B01J2531/66 , B01J2531/847 , C10G45/04 , C10G45/08 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： A catalyst precursor for preparing a bulk multi-metallic catalyst upon sulfidation is provided. The precursor has an essentially monomodal pore volume distribution with at least 90% of the pores being macropores, and a total pore volume of at least 0.08 g/cc. The bulk multi-metallic prepared from the precursor is particularly suitable for hydrotreating heavy oil feeds having a boiling point in the range of 343° C. (650° F.)—to 454° C. (850° F.), an average molecular weight Mn ranging from 300 to 400, and an average molecular diameter ranging from 0.9 nm to 1.7 nm.
摘要翻译：提供了一种用于在硫化时制备本体多金属催化剂的催化剂前体。前体具有基本单峰孔体积分布，其中至少90％的孔是大孔，总孔体积至少为0.08g / cc。从前体制备的大量多金属特别适用于加氢处理沸点在343℃（650°F）至454℃（850°F）范围内的重油进料，平均分子量Mn为300〜400，平均分子量为0.9nm〜1.7nm。

53. 发明申请

US20100279849A1 Hydroconversion Multi-Metallic Catalyst and Method for Making Thereof 有权
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US20100279849A1
公开(公告)日：2010-11-04
申请号：US12770388
申请日：2010-04-29
申请人： Alexander E. Kuperman , Theodorus Maesen , Dennis Dykstra
发明人： Alexander E. Kuperman , Theodorus Maesen , Dennis Dykstra
IPC分类号： B01J31/34 , B01J31/12
CPC分类号： B01J31/04 , B01J23/002 , B01J23/24 , B01J23/652 , B01J23/85 , B01J23/8885 , B01J31/0201 , B01J31/2226 , B01J35/002 , B01J35/0026 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/031 , B01J37/20 , B01J2523/00 , B01J2531/64 , B01J2531/66 , B01J2531/847 , C10G45/04 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： The invention relates to a bulk multi-metallic catalyst for hydrotreating heavy oil feeds and to a method for preparing the catalyst. The bulk multi-metallic catalyst is prepared by sulfiding a catalyst precursor having a poorly crystalline structure with disordered stacking layers, with a type IV adsorption-desorption isotherms of nitrogen with a hysteresis starting point value of about 0.35, for a sulfided catalyst that will facilitate the reactant's and product's diffusion in catalytic applications. In another embodiment, the precursor is characterized as having a type H3 hysteresis loop. In a third embodiment, the hysteresis loop is characterized as having a well developed plateau above P/Po of about 0.55. The mesapores of the precursor can be adjustable or tunable.
摘要翻译：本发明涉及用于加氢处理重油进料的本体多金属催化剂及其制备方法。本体多金属催化剂是通过硫化具有无序堆叠层的结晶结构不良的催化剂前体，具有约0.35的磁滞起始点值的氮的IV型吸附 - 解吸等温线来制备的，所述硫化催化剂将促进反应物和产品在催化应用中的扩散。在另一个实施方案中，前体的特征在于具有H3型磁滞回线。在第三实施例中，磁滞回线的特征在于具有高于P / Po的良好发展的平台约为0.55。前体的介孔可以是可调节的或可调节的。

54. 发明授权

US07803735B2 Hydroconversion processes employing multi-metallic catalysts and method for making thereof 有权
标题翻译：采用多金属催化剂的加氢转化方法及其制备方法
公开(公告)号：US07803735B2
公开(公告)日：2010-09-28
申请号：US12259507
申请日：2008-10-28
申请人： Theodorus Ludovicus Michael Maesen , Alexander E. Kuperman , Darren Fong
发明人： Theodorus Ludovicus Michael Maesen , Alexander E. Kuperman , Darren Fong
IPC分类号： B01J27/045 , B01J27/047 , B01J27/14 , B01J27/24 , B01J31/00
CPC分类号： C10G45/08 , B01J23/002 , B01J23/8885 , B01J31/2239 , B01J37/0018 , B01J37/036 , B01J37/20 , B01J2523/00 , B01J2531/26 , B01J2531/66 , B01J2531/847 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/48 , C10G45/50 , C10G45/52 , C10G45/54 , C10G47/06 , C10G47/18 , C10G47/20 , C10G49/04 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/27 , B01J2523/22 , B01J2523/31 , B01J2523/41 , B01J2523/43 , B01J2523/845
摘要： A catalyst precursor composition and methods for making such catalyst precursor are disclosed. The catalyst precursor comprises at least a metal compound selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, at least one Group VIB metal, at least one organic, oxygen-containing ligand, and a cellulose-containing material. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds. In one embodiment, the sulfidation is carried out by contacting the catalyst precursor with hydrogen and a sulfur containing compound in a “slow” process with the sulfidation taking place over a few days up to two weeks, e.g., for at least over 96 hours. In another embodiment, the sulfidation is in a “quick” process with the sulfidation taking place in less than 72 hours. The catalyst prepared from the slow sulfidation process gives a 700° F.+ conversion rate of at least 25% higher than the 700° F.+ conversion rate of a catalyst prepared from a quick sulfidation process.
摘要翻译：公开了催化剂前体组合物和制备这种催化剂前体的方法。催化剂前体至少包含选自VIII族，IIB族，IIA族，IVA族及其组合的金属化合物，至少一种VIB族金属，至少一种有机，含氧配位体和含纤维素材料。由这些催化剂前体的硫化制备的催化剂用于烃进料的加氢处理。在一个实施方案中，硫化是通过使催化剂前体与“慢”方法中的含硫化合物接触进行的，其中硫化在几天至多两周内进行，例如至少超过96小时。在另一个实施方案中，硫化是在“快速”过程中，硫化在少于72小时内发生。从缓慢硫化过程制备的催化剂的转化率比从快速硫化工艺制备的催化剂的700°F +转化率高至少高出25％。

55. 发明申请

US20100084311A1 HYDRODEMETALLIZATION CATALYST AND PROCESS 有权
标题翻译：氢化催化剂和工艺
公开(公告)号：US20100084311A1
公开(公告)日：2010-04-08
申请号：US12245531
申请日：2008-10-03
申请人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
发明人： Christopher J. Dillon , Theodorus Maesen , Alexander E. Kuperman
IPC分类号： C10G65/00 , C01B33/26 , B01J21/02 , B01J21/16 , B01J21/10 , B01J21/06
CPC分类号： C10G45/04 , B01J21/16 , B01J23/24 , B01J23/28 , B01J23/40 , B01J23/74 , B01J23/85 , B01J23/883 , B01J35/1061 , B01J37/0009 , B01J37/0201 , B01J37/20 , B01J37/28 , C01B33/40 , C10G2300/1022 , C10G2300/1074 , C10G2300/1077 , C10G2300/206 , C10G2300/4018
摘要： This invention is directed to hydrodemetallization catalysts and hydrodemetallization processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic 29Si NMR spectrum. The magnesium aluminosilicate clay is the product of a series of specific reaction steps. Briefly, the magnesium aluminosilicate clay employed in the catalyst and process of the invention is made by combining a silicon component, an aluminum component, and a magnesium component, under aqueous conditions and at an acidic pH, to form a first reaction mixture and subsequently the pH of the first reaction mixture is adjusted to greater than about 7.5 to form a second reaction mixture. The second reaction mixture is allowed to react under conditions sufficient to form the magnesium aluminosilicate clay. The resulting magnesium aluminosilicate clay combines high surface area and activity for use in hydrodemetallization catalysts and processes.
摘要翻译：本发明涉及使用硅铝酸镁粘土的加氢脱金属催化剂和加氢脱金属化方法。硅铝酸镁粘土具有特征29 Si NMR光谱。铝硅酸镁粘土是一系列具体反应步骤的产物。简而言之，本发明的催化剂和方法中所用的硅铝酸镁粘土是通过在含水条件下和酸性pH下混合硅组分，铝组分和镁组分来形成第一反应混合物，随后将将第一反应混合物的pH调节至大于约7.5以形成第二反应混合物。允许第二反应混合物在足以形成硅铝酸镁粘土的条件下反应。所得到的硅铝酸镁粘土具有高表面积和活性，用于加氢脱金属催化剂和工艺。

56. 发明申请

US20090218061A1 PROCESS FOR GENERATING A HYDROCARBON FEEDSTOCK FROM LIGNIN 有权
标题翻译：从LIGNIN生产油料进料的方法
公开(公告)号：US20090218061A1
公开(公告)日：2009-09-03
申请号：US12039349
申请日：2008-02-28
申请人： William Lawrence Schinski , Alexander E. Kuperman , Jinyi Han , Douglas Gene Naae
发明人： William Lawrence Schinski , Alexander E. Kuperman , Jinyi Han , Douglas Gene Naae
IPC分类号： D21F1/66
CPC分类号： D21C11/0007 , C10G1/06 , C10G3/44 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1074 , C10L1/02 , Y02P30/20
摘要： The present invention discloses processes for generating a hydrocarbon feedstock for biofuels synthesis from lignin via hydroprocessing. Embodiments of the present invention can occur in a refinery setting or in a paper mill setting. Embodiments of the present invention can utilize the separated lignin or the entire black liquor solution.
摘要翻译：本发明公开了通过加氢处理从木质素生成用于生物燃料合成的烃原料的方法。本发明的实施例可以在炼油厂设置或造纸厂设置中发生。本发明的实施方案可以利用分离的木质素或整个黑液溶液。

57. 发明授权

US09199224B2 Hydroconversion multi-metallic catalysts and method for making thereof 有权
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US09199224B2
公开(公告)日：2015-12-01
申请号：US14019397
申请日：2013-09-05
申请人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
发明人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
IPC分类号： B01J27/051 , B01J27/049 , B01J27/043 , B01J27/047 , B01J35/00 , B01J35/10
CPC分类号： B01J27/0515 , B01J27/043 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/002 , B01J35/1014 , B01J35/1038 , C10G45/08
摘要： The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst has molar ratios of metal components Ni:Mo:W in a region defined by five points ABCDE of a ternary phase diagram, and wherein the five points ABCDE are defined as: A (Ni=0.72, Mo=0.00, W=0.25), B (Ni=0.25, Mo=0.00, W=0.75), C (Ni=0.25, Mo=0.25, W=0.50), D (Ni=0.60, Mo=0.25, W=0.15), E (Ni=0.72, Mo=0.13, W=0.15).
摘要翻译：本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。 MMS催化剂在由三元相图的五点ABCDE定义的区域中具有金属成分Ni:Mo:W的摩尔比，其中五点ABCDE定义为：A（Ni = 0.72，Mo = 0.00，W = 0.25），B（Ni = 0.25，Mo = 0.00，W = 0.75），C（Ni = 0.25，Mo = 0.25，W = 0.50），D（Ni = 0.60，Mo = 0.25，W = 0.15） Ni = 0.72，Mo = 0.13，W = 0.15）。

58. 发明申请

US20150119308A1 PROCESS FOR PREPARING A PARA-LINEAR ALKYL-SUBSTITUTED HYDROXYAROMATIC COMPOUND 有权
标题翻译：用于制备直链烷基取代羟基化合物的方法
公开(公告)号：US20150119308A1
公开(公告)日：2015-04-30
申请号：US14069271
申请日：2013-10-31
申请人： Cedrick Mahieux , Curtis B. Campbell , Alexander E. Kuperman
发明人： Cedrick Mahieux , Curtis B. Campbell , Alexander E. Kuperman
IPC分类号： C07C37/08 , C10M129/10
CPC分类号： C07C37/08 , C07C2/66 , C07C407/00 , C07C2529/18 , C10M129/10 , C10M177/00 , C10M2207/023 , C10N2270/00 , C07C39/06 , C07C15/107 , C07C409/08
摘要： Disclosed herein is a process for preparing an isomeric mixture comprising a major amount of a para-linear mono-alkyl-substituted hydroxyaromatic compound. The process involves the steps of: (a) providing an isomeric mixture comprising a major amount of a para-di(alkyl-substituted)aromatic compound; wherein a first alkyl substituent is a C3 to C8 alkyl moiety and a second alkyl substituent is a C4+n to C8+n linear alkyl moiety, wherein n is 0 to 42 and further wherein the second alkyl substituent is at least one carbon atom greater than the first alkyl substituent; (b) subjecting the isomeric mixture comprising a major amount of a para-di(alkyl-substituted)aromatic compound to oxidation conditions in the presence of an oxygen-containing source, thereby converting the first alkyl substituent which is a C3 to C8 alkyl moiety to a hydroperoxide-containing substituted moiety to produce an isomeric mixture comprising a major amount of a para-linear alkyl-substituted, hydroperoxide-containing substituted aromatic compound; and (c) converting the hydroperoxide-containing substituted moiety to a hydroxyl moiety thereby providing an isomeric mixture comprising a major amount of a para-linear mono-alkyl-substituted hydroxyaromatic compound.
摘要翻译：本文公开了一种制备包含主要量的对位线性单烷基取代的羟基芳族化合物的异构体混合物的方法。该方法包括以下步骤：（a）提供包含主要量的对二（烷基取代的）芳族化合物的异构体混合物; 其中第一烷基取代基是C3至C8烷基部分，第二烷基取代基是C 4 + n至C 8 + n直链烷基部分，其中n为0至42，并且其中第二烷基取代基为至少一个碳原子较大比第一烷基取代基; （b）在含氧源的存在下使含有主要量的对二（烷基取代）芳族化合物的异构体混合物经受氧化条件，由此转化为C3至C8烷基部分的第一烷基取代基涉及含氢过氧化物的取代部分以产生包含主要量的对位线性烷基取代的含氢过氧化物的取代的芳族化合物的异构体混合物; 和（c）将含氢过氧化物的取代的部分转化为羟基部分，从而提供包含主要量的对位线性单烷基取代的羟基芳族化合物的异构体混合物。

59. 发明授权

US08884077B2 Hydroconversion of renewable feedstocks 有权
标题翻译：可再生原料的加氢转化
公开(公告)号：US08884077B2
公开(公告)日：2014-11-11
申请号：US13315575
申请日：2011-12-09
申请人： Cong-Yan Chen , Alexander E. Kuperman , William J. Cannella
发明人： Cong-Yan Chen , Alexander E. Kuperman , William J. Cannella
IPC分类号： C07C29/149
CPC分类号： C11B3/02
摘要： A hydrocarbon conversion process comprises contacting a renewable feedstock under hydroprocessing conditions with a bulk catalyst to form oleochemicals such as fatty alcohols, esters, and normal paraffins. Advantageously, the reaction conditions can be selected to directly convert the renewable feedstock to the desired product(s).
摘要翻译：烃转化方法包括在加氢处理条件下将可再生原料与本体催化剂接触以形成油脂化学物质，例如脂肪醇，酯和正链烷烃。有利地，可以选择反应条件以将可再生原料直接转化为所需的产物。

60. 发明申请

US20140135207A1 Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof 有权
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US20140135207A1
公开(公告)日：2014-05-15
申请号：US14019444
申请日：2013-09-05
申请人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
发明人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
IPC分类号： B01J27/051
CPC分类号： B01J27/0515 , B01J27/043 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/002 , B01J35/1014 , B01J35/1038 , C10G45/08
摘要： The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst is characterized as having a BET surface area of at least 20 m2/g and a pore volume of at least 0.05 cm3/g. In one embodiment, the MMS catalyst is also characterized as having a multi-phased structure comprising five phases: a molybdenum sulfide phase, a tungsten sulfide phase, a molybdenum tungsten sulfide phase, an active nickel phase, and a nickel sulfide phase.
摘要翻译：本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。 MMS催化剂的特征在于具有至少20m 2 / g的BET表面积和至少0.05cm 3 / g的孔体积。在一个实施方案中，MMS催化剂的特征还在于具有包含五相的多相结构：硫化钼相，硫化钨相，硫化钨相，活性镍相和硫化镍相。

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