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51. 发明授权

US5675041A Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene 失效
标题翻译：含有一氧化碳，氢气，乙烯和乙炔的多组分合成气的直接加氢甲酰化
公开(公告)号：US5675041A
公开(公告)日：1997-10-07
申请号：US573052
申请日：1995-12-15
申请人： Gabor Kiss , Frank Hershkowitz , Harry W. Deckman , Michael Gerard Matturro , Istvan T. Horvath , Anthony M. Dean , Raymond A. Cook
发明人： Gabor Kiss , Frank Hershkowitz , Harry W. Deckman , Michael Gerard Matturro , Istvan T. Horvath , Anthony M. Dean , Raymond A. Cook
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , Y02P20/582
摘要： The invention is a process for production of C.sub.3 to C.sub.6 aldehydes by hydroformylating a mixture containing: (a) C.sub.2 to C.sub.5 olefins and mixtures thereof, and (b) (i) C.sub.2 to C.sub.5 alkynes and mixtures thereof or (ii) C.sub.3 to C.sub.5 cumulated dienes and mixtures thereof or (iii) mixtures of (i) and (ii), with CO, H.sub.2 and a solution of a rhodium complex catalyst produced by complexing Rh and an organophosphorus compound at a concentration of Rh in solution from 1 to 1000 ppm by weight. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio of at least 30. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio greater than the value R.sub.L defined by the formula: ##EQU1## in which R.sub.B is the P/Rh ratio sufficient for a catalytically active Rh complex, pKa.sub.TPP is the pKa value for triphenylphosphine, pKa.sub.L is the pKa value for the triorganophosphorus compound, R is the gas constant, and .DELTA.S.sub.B is 35(N-1) cal/mole/.degree.K., N is the number of P-Rh attachments per ligand molecule. The process has utility for the hydroformylation of streams that contain olefins and alkynes.
摘要翻译：本发明是通过加氢甲酰化含有：（a）C 2〜C 5烯烃及其混合物的混合物，和（b）（ⅰ）C2〜C5炔烃及其混合物或（ⅱ）C3〜C5 累积的二烯及其混合物，或（iii）（ⅰ）和（ⅱ）的混合物与CO，H 2和铑络合物催化剂的溶液形成，所述铑配合物催化剂是通过使Rh和溶液中Rh浓度为1〜1000的有机磷化合物重量ppm。或者，铑络合物催化剂的溶液的P / Rh原子比可以至少为30.另外，铑络合物催化剂的溶液可以具有大于由下式定义的值RL的P / Rh原子比：其中RB是催化活性Rh配合物的P / Rh比，pKaTPP是三苯基膦的pKa值，pKaL是三有机磷化合物的pKa值，R是气体常数，DELTA SB是35（N-1 ）cal / mole / DEGK，N是每个配体分子的P-Rh附着物的数目。该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。

52. 发明授权

US5186833A Composite metal-ceramic membranes and their fabrication 失效
标题翻译：复合金属陶瓷膜及其制造
公开(公告)号：US5186833A
公开(公告)日：1993-02-16
申请号：US775656
申请日：1991-10-10
申请人： James A. Mchenry , Harry W. Deckman , Wen-Yih F. Lai , Michael G. Matturro , Allan J. Jacobson , Jack W. Johnson
发明人： James A. Mchenry , Harry W. Deckman , Wen-Yih F. Lai , Michael G. Matturro , Allan J. Jacobson , Jack W. Johnson
IPC分类号： B01D71/02 , C23C26/00
CPC分类号： B01D67/0048 , B01D67/0083 , B01D71/02 , C23C26/00 , B01D2323/08 , B01D2325/04
摘要： The present invention provides a novel, porous, composite membrane comprising a metallic support having large pores and a microporous ceramic membrane deposited on the support and integral therewith. Preferably, the support is steel having pores in the range of from about 0.25 .mu.m to about 50 .mu.m and the ceramic membrane is alumina having pores ranging from about 5 .ANG.to about 2500 .ANG..

53. 发明授权

US4891829A Method and apparatus for utilizing an electro-optic detector in a microtomography system 失效
标题翻译：在微影像系统中利用电光检测器的方法和装置
公开(公告)号：US4891829A
公开(公告)日：1990-01-02
申请号：US932273
申请日：1986-11-19
申请人： Harry W. Deckman , Brian P. Flannery
发明人： Harry W. Deckman , Brian P. Flannery
IPC分类号： A61B6/03 , G01N23/04 , G01T1/20 , G01T1/29 , G21K4/00
CPC分类号： G01T1/2928 , G01N23/046 , G01N2223/419 , Y10S378/901
摘要： The present invention is an apparatus and a method for producing tomographic images of an object irradiated by a beam of collimated radiation transmitted in a plurality of rays through a set of coplanar sections of an object as viewed from a plurality of angles about a rotation axis. The apparatus includes an imaging electro-optic detector to record the transmitted radiation, wherein the electro-optic detector alters the image format, the format alteration being focused; means to determine and align the projected position of the rotation axis on the electro-optic detector; means to align the object with respect to the rotation axis; means to determine and assure spatial uniformity of detector response; means to reduce signal dependent backgrounds; means to determine the projection coefficients from the transmitted radiation with respect to one or more reference calibration exposures; and means to compute a reconstructed image of the object's attenuation coefficients.
摘要翻译：本发明是一种用于生成由多个射线透过的准直辐射束照射的物体的断层图像的装置和方法，该多个光束通过从旋转轴的多个角度观察的物体的一组共面部分。该装置包括用于记录透射辐射的成像电光检测器，其中电光检测器改变图像格式，正在聚焦的格式变化; 用于确定和对准电光检测器上的旋转轴的投影位置的装置; 用于使物体相对于旋转轴线对齐的装置; 意味着确定并确保检测器响应的空间均匀性; 减少信号依赖背景的手段; 用于相对于一个或多个参考校准曝光来确定来自所发射的辐射的投影系数的装置; 以及用于计算对象的衰减系数的重建图像的装置。

54. 发明授权

US4690750A Micro-porous superlattice separations 失效
标题翻译：微孔超晶格分离
公开(公告)号：US4690750A
公开(公告)日：1987-09-01
申请号：US874027
申请日：1986-06-13
申请人： Charles B. Roxlo , Harry W. Deckman
发明人： Charles B. Roxlo , Harry W. Deckman
IPC分类号： B01D15/08 , B01D53/04 , B01J20/02 , B01J20/30 , C07C7/12 , G01N30/52
CPC分类号： B01J20/30 , B01D15/08 , B01D53/02 , B01D53/0407 , B01J20/02 , B01J20/103 , C07C7/12 , B01D2253/106 , B01D2253/116 , B01D2253/308 , B01D2257/7022 , B01D2257/7027 , B01D2259/4145 , G01N2030/525 , Y10S148/16
摘要： A high surface area substrate with controlled pore size and slot geometry is used in an adsorbing process. The material is made by depositing at least two materials in alternating layers. The film is then broken up and one of the materials is etched away to produce a slotted surface structure. These slots can add size and shape selectivity to separations and catalytic processes which because of the uniform and controllable dimensions (>5A) would be superior to that obtainable from zeolites and clays.
摘要翻译：在吸附过程中使用具有受控孔径和槽几何形状的高表面积基材。该材料通过以交替的层沉积至少两种材料制成。然后将薄膜破碎，并将其中一种材料蚀刻掉以产生开槽表面结构。这些槽可以增加分离和催化过程的尺寸和形状选择性，因为均匀和可控的尺寸（> 5A）将优于沸石和粘土可获得的尺寸和形状选择性。

55. 发明授权

US4407695A Natural lithographic fabrication of microstructures over large areas 失效
标题翻译：大面积微观结构的天然光刻制造
公开(公告)号：US4407695A
公开(公告)日：1983-10-04
申请号：US363019
申请日：1982-03-29
申请人： Harry W. Deckman , John H. Dunsmuir
发明人： Harry W. Deckman , John H. Dunsmuir
IPC分类号： B41M5/24 , G03F7/004 , G03F7/16 , H01L21/308 , B44C1/22 , C03C15/00 , C03C25/06 , H01L21/306
CPC分类号： G03F7/004 , B41M5/24 , G03F7/165 , H01L21/3081
摘要： Large area random and mosaic arrays of identical submicron microcolumnar structures can be produced on surfaces by directionally ion etching a monolayer film of spherical colloidal particles.
摘要翻译：可以通过定向离子蚀刻球形胶体颗粒的单层膜，在表面上产生相同亚微米微柱结构的大面积随机和镶嵌阵列。

56. 发明授权

US10662768B2 Methods of determining a spatial distribution of an injected tracer material within a subterranean formation 有权
公开(公告)号：US10662768B2
公开(公告)日：2020-05-26
申请号：US15666315
申请日：2017-08-01
申请人： Brent Wheelock , Mehmet Deniz Ertas , Lang Feng , Qiuzi Li , Harry W. Deckman
发明人： Brent Wheelock , Mehmet Deniz Ertas , Lang Feng , Qiuzi Li , Harry W. Deckman
IPC分类号： E21B49/00 , E21B47/00 , G01V3/30 , E21B47/10 , G01V15/00 , E21B33/12 , E21B43/04 , E21B43/26
摘要： Methods of determining a spatial distribution of an injected tracer material within a subterranean formation are disclosed, including flowing the tracer material, which includes a tracer electrical capacitance that differs from a formation electrical capacitance of a region of the subterranean formation, into the region of the subterranean formation via a wellbore. Subsequent to the flowing, the methods also include providing an input electromagnetic signal to the region of the subterranean formation. Responsive to the providing, the methods further include receiving an output electromagnetic signal from the subterranean formation. The methods further include determining the spatial distribution of the tracer material within the subterranean formation based, at least in part, on the output electromagnetic signal.

57. 发明授权

US09095809B2 Selectivation of adsorbents for gas separation 有权
标题翻译：选择气体分离吸附剂
公开(公告)号：US09095809B2
公开(公告)日：2015-08-04
申请号：US14074860
申请日：2013-11-08
申请人： Harry W. Deckman , Peter I. Ravikovitch , Preeti Kamakoti , Chris Yoon
发明人： Harry W. Deckman , Peter I. Ravikovitch , Preeti Kamakoti , Chris Yoon
IPC分类号： B01D53/04 , B01D53/047 , B01D69/14 , B01J20/30 , C01B39/48 , B01D53/02 , C01B37/02
CPC分类号： C01B39/04 , B01D53/02 , B01D53/04 , B01D53/0423 , B01D53/0462 , B01D53/047 , B01D53/0473 , B01D69/147 , B01D2253/108 , B01D2256/245 , B01D2257/102 , B01D2257/504 , B01J20/3078 , B01J35/023 , B01J35/026 , C01B37/02 , C01B39/48 , Y02C10/08 , Y02P20/152
摘要： Systems and methods are provided for improving separation of gas phase streams using an adsorbent, such as 8-member ring zeolite adsorbents or DDR type zeolite adsorbents. Suitable gas phase streams can include at least one hydrocarbon, such as methane or a hydrocarbon containing at least one saturated carbon-carbon bond, and at least one additional component, such as CO2 or N2. The selectivity of the adsorbent is improved by selectivating the adsorbent with one or more barrier compounds. The presence of the barrier compounds is believed to alter the relative ability of potential adsorbates to enter into and/or move within the pores of the adsorbent.
摘要翻译：提供的系统和方法用于改善使用吸附剂如8元环沸石吸附剂或DDR型沸石吸附剂的气相流分离。合适的气相物流可以包括至少一种烃，例如甲烷或含有至少一个饱和碳 - 碳键的烃，以及至少一种另外的组分如CO 2或N 2。通过用一种或多种阻挡化合物选择吸附剂来提高吸附剂的选择性。认为阻挡化合物的存在可以改变潜在的被吸附物进入和/或移动吸附剂的孔内的相对能力。

58. 发明申请

US20150159947A1 METHOD AND DEVICE FOR SEPARATING HYDROCARBONS AND CONTAMINANTS WITH A HEATING MECHANISM TO DESTABILIZE AND/OR PREVENT ADHESION OF SOLIDS 审中-公开
标题翻译：用加热机构分离碳氢化合物和污染物来降解和/或防止固体粘附的方法和装置
公开(公告)号：US20150159947A1
公开(公告)日：2015-06-11
申请号：US14516726
申请日：2014-10-17
申请人： Jaime A. Valencia , Harry W. Deckman , Charles J. Mart , James T. Wilkins , Paul Scott Northrop
发明人： Jaime A. Valencia , Harry W. Deckman , Charles J. Mart , James T. Wilkins , Paul Scott Northrop
IPC分类号： F25J3/08 , C07C7/05 , F25J3/06
CPC分类号： F25J3/067 , B01D3/42 , C07C7/05 , C10L3/102 , C10L3/104 , C10L3/107 , C10L2290/543 , C10L2290/545 , C10L2290/58 , C10L2290/60 , F25J1/0022 , F25J3/0209 , F25J3/0233 , F25J3/0266 , F25J3/061 , F25J3/0635 , F25J3/08 , F25J2200/02 , F25J2200/30 , F25J2200/50 , F25J2200/74 , F25J2205/04 , F25J2205/20 , F25J2220/66 , F25J2235/60 , F25J2280/02 , F25J2280/40 , F25J2290/12 , F25J2290/40 , Y02C10/12
摘要： The present disclosure provides a method for separating a feed stream in a distillation tower which includes separating a feed stream in a stripper section into an enriched contaminant bottom liquid stream and a freezing zone vapor stream; contacting the freezing zone vapor stream in the controlled freeze zone section with a freezing zone liquid stream at a temperature and pressure at which a solid and a hydrocarbon-enriched vapor stream form; directly applying heat to a controlled freeze zone wall of the controlled freeze zone section with a heating mechanism coupled to at least one of a controlled freeze zone internal surface of the controlled freeze zone wall and a controlled freeze zone external surface of the controlled freeze zone wall; and at least one of destabilizing and preventing adhesion of the solid to the controlled freeze zone wall with the heating mechanism.
摘要翻译：本公开提供了一种用于分离蒸馏塔中的进料流的方法，其包括将汽提部分中的进料流分离成富集的污染物底部液体流和冷冻区蒸气流; 在控制的冷冻区段中的冷冻区蒸汽流与形成固体和富含烃的蒸气流的温度和压力下与冷冻区液体流接触; 将受控冻结区段的受控冻结区域的热量直接加热到受控冻结区域壁的受控冷冻区内表面和受控冷冻区域外部表面中的至少一个的加热机构 ; 以及使用加热机构去除稳定和防止固体与受控冷冻区域壁粘合中的至少一种。

59. 发明申请

US20140178278A1 CO2 CAPTURE VIA AMINE-CO2 PRODUCT PHASE SEPARATION 审中-公开
标题翻译： CO2捕获通过胺 - 二氧化碳产物相分离
公开(公告)号：US20140178278A1
公开(公告)日：2014-06-26
申请号：US14087377
申请日：2013-11-22
申请人： Michael Siskin , Patrick L. Hanks , Pavel Kortunov , Robert B. Fedich , Patrick P. McCall , Hans Thomann , Daniel Leta , Lisa S. Baugh , David C. Calabro , Harry W. Deckman
发明人： Michael Siskin , Patrick L. Hanks , Pavel Kortunov , Robert B. Fedich , Patrick P. McCall , Hans Thomann , Daniel Leta , Lisa S. Baugh , David C. Calabro , Harry W. Deckman
IPC分类号： B01D53/62
CPC分类号： B01D53/62 , B01D53/1425 , B01D53/1475 , B01D2252/20415 , B01D2252/20447 , B01D2252/20484 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： Systems and methods are provided for performing CO2 sorption and regeneration processes that can take advantage of phase changes between solutions of amine-CO2 reaction products and precipitate slurries, where the slurry particles can include solid precipitates formed based on the amine-CO2 reaction products. An amine solution can be used to capture CO2 from a gas phase stream. During this initial capture process, the amine-CO2 reaction product can remain in solution. The solution containing the amine-CO2 reaction product can then be exposed to a set of conditions which result in precipitation of a portion of the amine-CO2 reaction product to form a slurry. The precipitate slurry can be passed into one or more release stages where the conditions for the slurry are altered to allow for release of the CO2.
摘要翻译：提供了系统和方法，用于执行CO2吸附和再生过程，可以利用胺-CO 2反应产物和沉淀物浆料的溶液之间的相变，其中浆料颗粒可以包括基于胺-CO 2反应产物形成的固体沉淀物。胺溶液可用于从气相物流中捕获CO 2。在该初始捕获过程中，胺-CO 2反应产物可以保留在溶液中。然后可以将含有胺-CO 2反应产物的溶液暴露于导致部分胺-CO 2反应产物沉淀形成浆料的一组条件。沉淀浆料可以进入一个或多个释放阶段，其中改变浆料的条件以允许CO 2的释放。

60. 发明申请

US20140157984A1 SELECTIVATION OF ADSORBENTS FOR GAS SEPARATION 有权
标题翻译：气体分离吸附剂的选择
公开(公告)号：US20140157984A1
公开(公告)日：2014-06-12
申请号：US14074860
申请日：2013-11-08
申请人： Harry W. Deckman , Peter I. Ravikovitch , Preeti Kamakoti , Chris Yoon
发明人： Harry W. Deckman , Peter I. Ravikovitch , Preeti Kamakoti , Chris Yoon
IPC分类号： B01D53/047 , B01D69/14 , B01D53/04
CPC分类号： C01B39/04 , B01D53/02 , B01D53/04 , B01D53/0423 , B01D53/0462 , B01D53/047 , B01D53/0473 , B01D69/147 , B01D2253/108 , B01D2256/245 , B01D2257/102 , B01D2257/504 , B01J20/3078 , B01J35/023 , B01J35/026 , C01B37/02 , C01B39/48 , Y02C10/08 , Y02P20/152
摘要： Systems and methods are provided for improving separation of gas phase streams using an adsorbent, such as 8-member ring zeolite adsorbents or DDR type zeolite adsorbents. Suitable gas phase streams can include at least one hydrocarbon, such as methane or a hydrocarbon containing at least one saturated carbon-carbon bond, and at least one additional component, such as CO2 or N2. The selectivity of the adsorbent is improved by selectivating the adsorbent with one or more barrier compounds. The presence of the barrier compounds is believed to alter the relative ability of potential adsorbates to enter into and/or move within the pores of the adsorbent.
摘要翻译：提供的系统和方法用于改善使用吸附剂如8元环沸石吸附剂或DDR型沸石吸附剂的气相流分离。合适的气相物流可以包括至少一种烃，例如甲烷或含有至少一个饱和碳 - 碳键的烃，以及至少一种另外的组分如CO 2或N 2。通过用一种或多种阻挡化合物选择吸附剂来提高吸附剂的选择性。认为阻挡化合物的存在可以改变潜在的被吸附物进入和/或移动吸附剂的孔内的相对能力。

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