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1. 发明申请

US20140178278A1 CO2 CAPTURE VIA AMINE-CO2 PRODUCT PHASE SEPARATION 审中-公开
标题翻译： CO2捕获通过胺 - 二氧化碳产物相分离
公开(公告)号：US20140178278A1
公开(公告)日：2014-06-26
申请号：US14087377
申请日：2013-11-22
申请人： Michael Siskin , Patrick L. Hanks , Pavel Kortunov , Robert B. Fedich , Patrick P. McCall , Hans Thomann , Daniel Leta , Lisa S. Baugh , David C. Calabro , Harry W. Deckman
发明人： Michael Siskin , Patrick L. Hanks , Pavel Kortunov , Robert B. Fedich , Patrick P. McCall , Hans Thomann , Daniel Leta , Lisa S. Baugh , David C. Calabro , Harry W. Deckman
IPC分类号： B01D53/62
CPC分类号： B01D53/62 , B01D53/1425 , B01D53/1475 , B01D2252/20415 , B01D2252/20447 , B01D2252/20484 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： Systems and methods are provided for performing CO2 sorption and regeneration processes that can take advantage of phase changes between solutions of amine-CO2 reaction products and precipitate slurries, where the slurry particles can include solid precipitates formed based on the amine-CO2 reaction products. An amine solution can be used to capture CO2 from a gas phase stream. During this initial capture process, the amine-CO2 reaction product can remain in solution. The solution containing the amine-CO2 reaction product can then be exposed to a set of conditions which result in precipitation of a portion of the amine-CO2 reaction product to form a slurry. The precipitate slurry can be passed into one or more release stages where the conditions for the slurry are altered to allow for release of the CO2.
摘要翻译：提供了系统和方法，用于执行CO2吸附和再生过程，可以利用胺-CO 2反应产物和沉淀物浆料的溶液之间的相变，其中浆料颗粒可以包括基于胺-CO 2反应产物形成的固体沉淀物。胺溶液可用于从气相物流中捕获CO 2。在该初始捕获过程中，胺-CO 2反应产物可以保留在溶液中。然后可以将含有胺-CO 2反应产物的溶液暴露于导致部分胺-CO 2反应产物沉淀形成浆料的一组条件。沉淀浆料可以进入一个或多个释放阶段，其中改变浆料的条件以允许CO 2的释放。

2. 发明授权

US09272242B2 High cyclic capacity amines for high efficiency CO2 scrubbing processes 有权
标题翻译：高循环量胺用于高效CO2洗涤工艺
公开(公告)号：US09272242B2
公开(公告)日：2016-03-01
申请号：US13933614
申请日：2013-07-02
申请人： Pavel Kortunov , Michael Siskin , Hans Thomann
发明人： Pavel Kortunov , Michael Siskin , Hans Thomann
IPC分类号： B01D53/14 , B01D53/62 , C10L3/10
CPC分类号： B01D53/62 , B01D53/1475 , B01D53/1493 , B01D2252/20405 , B01D2252/20426 , B01D2252/20484 , B01D2258/0283 , C10L3/104 , Y02C10/06
摘要： A high cyclic capacity carbon dioxide scrubbing process contacts a gas stream containing carbon dioxide in a sorption zone with a liquid scrubbing solution of a low molecular weight sterically hindered amine, particularly a secondary alkanolamine or aminoether at a high concentration, typically at least 3.5M and at a temperature of at least 30° C. to sorb the carbon dioxide into the solution and form a rich stream of the sorbed carbon dioxide in the solution in the form of dissolved amine carbamate and/or alkanolamine bicarbonate. The rich stream is then passed from the sorption zone to at least one regeneration zone and the sorbed carbon dioxide is desorbed as gas from the solution to form a lean solution containing a reduced concentration of sorbed carbon dioxide relative to the rich stream; the lean stream is then returned to the sorption zone for a further sorption cycle.
摘要翻译：高循环容量的二氧化碳洗涤方法在吸附区中与含有低分子量空间位阻胺的液体洗涤溶液，特别是高浓度，典型地至少为3.5M的仲烷醇胺或氨基醚接触含有二氧化碳的气流，在至少30℃的温度下将二氧化碳吸附到溶液中，并以溶解的胺氨基甲酸酯和/或链烷醇胺碳酸氢盐的形式在溶液中形成富含二氧化碳的富流。然后将富流从吸附区传递到至少一个再生区，并且吸附的二氧化碳作为气体从溶液中解吸，形成相对于富流而含有降低浓度的吸附二氧化碳的贫溶液; 然后将贫流返回到吸附区以进一步吸附循环。

3. 发明申请

US20140030177A1 HIGH CYCLIC CAPACITY AMINES FOR HIGH EFFICIENCY CO2 SCRUBBING PROCESSES 有权
标题翻译：高效CO2二氧化碳清洗工艺的高循环性能
公开(公告)号：US20140030177A1
公开(公告)日：2014-01-30
申请号：US13933614
申请日：2013-07-02
申请人： Pavel Kortunov , Michael Siskin , Hans Thomann
发明人： Pavel Kortunov , Michael Siskin , Hans Thomann
IPC分类号： B01D53/62
CPC分类号： B01D53/62 , B01D53/1475 , B01D53/1493 , B01D2252/20405 , B01D2252/20426 , B01D2252/20484 , B01D2258/0283 , C10L3/104 , Y02C10/06
摘要： A high cyclic capacity carbon dioxide scrubbing process contacts a gas stream containing carbon dioxide in a sorption zone with a liquid scrubbing solution of a low molecular weight sterically hindered amine, particularly a secondary alkanolamine or aminoether at a high concentration, typically at least 3.5M and at a temperature of at least 30° C. to sorb the carbon dioxide into the solution and form a rich stream of the sorbed carbon dioxide in the solution in the form of dissolved amine carbamate and/or alkanolamine bicarbonate. The rich stream is then passed from the sorption zone to at least one regeneration zone and the sorbed carbon dioxide is desorbed as gas from the solution to form a lean solution containing a reduced concentration of sorbed carbon dioxide relative to the rich stream; the lean stream is then returned to the sorption zone for a further sorption cycle.
摘要翻译：高循环容量的二氧化碳洗涤方法在吸附区中与含有低分子量空间位阻胺的液体洗涤溶液，特别是高浓度，典型地至少为3.5M的仲烷醇胺或氨基醚接触含有二氧化碳的气流，在至少30℃的温度下将二氧化碳吸附到溶液中，并以溶解的胺氨基甲酸酯和/或链烷醇胺碳酸氢盐的形式在溶液中形成富含二氧化碳的富流。然后将富流从吸附区传递到至少一个再生区，并且吸附的二氧化碳作为气体从溶液中解吸，形成相对于富流而含有降低浓度的吸附二氧化碳的贫溶液; 然后将贫流返回到吸附区以进一步吸附循环。

4. 发明申请

US20150314235A1 CARBON DIOXIDE SCRUBBING PROCESS 审中-公开
标题翻译：二氧化碳清洗工艺
公开(公告)号：US20150314235A1
公开(公告)日：2015-11-05
申请号：US14268174
申请日：2014-05-02
申请人： Pavel Kortunov , Michael Siskin , Eugene R. Thomas , Hans Thomann
发明人： Pavel Kortunov , Michael Siskin , Eugene R. Thomas , Hans Thomann
IPC分类号： B01D53/62 , B01D53/14
CPC分类号： B01D53/1475 , B01D53/1425 , B01D53/1493 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , B01D2258/0283 , Y02C10/04 , Y02C10/06
摘要： A cyclic process for separating CO2 from a gas stream by contacting the gas stream at a first temperature and typically at a pressure of at least 30 barg with a CO2 sorbent comprising an ionic liquid containing a potentially nucleophilic carbon atom bearing a relatively acidic hydrogen atom bonded to a potentially nucleophilic carbon atom to sorb CO2 into the solution and regenerating the ionic liquid absorbent by treating the sorbent under conditions including a second, typically higher, temperature, to cause desorption of at least a portion of the CO2 and to regenerate the ionic liquid.
摘要翻译：通过在第一温度和通常在至少30barg的压力下将气流与包含含有相对酸性氢原子键合的潜在亲核性碳原子的离子液体的CO 2吸附剂接触，从气流中分离CO 2的循环方法到潜在的亲核碳原子以将CO 2吸收到溶液中并通过在包括第二，通常较高的温度的条件下处理吸附剂来再生离子液体吸收剂，以引起至少一部分CO 2的解吸并再生离子液体。

5. 发明授权

US07310580B2 Method for borehole measurement of formation properties 失效
标题翻译：钻孔测量方法
公开(公告)号：US07310580B2
公开(公告)日：2007-12-18
申请号：US10318786
申请日：2002-12-13
申请人： Minyao Zhou , Hans Thomann , Stuart Ronald Keller
发明人： Minyao Zhou , Hans Thomann , Stuart Ronald Keller
IPC分类号： G01V1/40 , G06G7/48
CPC分类号： G01V1/50
摘要： The present invention is a method of estimating formation properties by analyzing acoustic waves that are emitted from and received by a bottom hole assembly. A bottom hole assembly may be deployed in a borehole to estimate formation properties. From the bottom hole assembly, a source signal may be emitted and at least one signal may be received by one or more receivers in the bottom hole assembly. Analysis of the frequency dependent characteristics of the received signal allows the estimation of the formation properties of interest, including pore pressure. The formation properties of interest may be used to monitor a wellbore pressure safety margin and to optimize drilling and weight.
摘要翻译：本发明是通过分析从底孔组件发出并接收的声波来估计地层特性的方法。井底组件可以部署在钻孔中以估计地层特性。从井底组件可以发射源信号，并且至少一个信号可以由底孔组件中的一个或多个接收器接收。对接收信号的频率依赖特性的分析允许估计感兴趣的形成特性，包括孔隙压力。感兴趣的形成特性可用于监测井筒压力安全裕度，并优化钻井和重量。

6. 发明授权

US5281653A Fullerene-polymer compositions 失效
标题翻译：富勒烯聚合物组合物
公开(公告)号：US5281653A
公开(公告)日：1994-01-25
申请号：US797525
申请日：1991-11-25
申请人： Hans Thomann , Patrick Brant , John P. Dismukes , David J. Lohse , Jyi-Faa Hwang , Edward N. Kresge
发明人： Hans Thomann , Patrick Brant , John P. Dismukes , David J. Lohse , Jyi-Faa Hwang , Edward N. Kresge
IPC分类号： C08K3/02 , C08K3/04 , C08L101/00 , C08K5/01
CPC分类号： C08K3/04 , Y10S977/753
摘要： The present invention relates to novel compositions of matter comprising fullerenes and polymers, wherein the fullerenes are combined with the polymer in an amount sufficient to result in a change or modification in the viscoelastic properties of the resulting composition from that of the unmodified polymer typically within the range of from about 0.01 wt. % to about 85 wt. %. Also included in the present invention is the process for making the novel fullerene-polymer compositions and the products produced by the process disclosed therein. The novel compositions show changes in the viscoelastic properties in comparison to the unmodified polymer, and hence, have utility in any application in which the unmodified polymer may be used, but wherein the application would benefit from the resulting change in the viscoelastic properties.
摘要翻译：本发明涉及包含富勒烯和聚合物的新型物质组合物，其中富勒烯与聚合物结合的量足以导致所得组合物的粘弹性性质与未改性聚合物的粘弹性性质的改变或改性，范围为约0.01重量％％至约85重量％％。本发明还包括制备新型富勒烯聚合物组合物和通过其中公开的方法制备的产品的方法。与未改性的聚合物相比，该新型组合物显示出粘弹性性能的变化，因此在可以使用未改性聚合物的任何应用中具有实用性，但是其应用将受益于所得到的粘弹性质的变化。

7. 发明授权

US09476356B2 Integration of pressure swing adsorption with a power plant for CO2 capture/utilization and N2 production 有权
标题翻译：将变压吸附与发电厂整合，用于CO2捕集/利用和N2生产
公开(公告)号：US09476356B2
公开(公告)日：2016-10-25
申请号：US13917101
申请日：2013-06-13
申请人： Narasimhan Sundaram , Ramesh Gupta , Hans Thomann , Hugo S. Caram , Loren K. Starcher , Franklin F. Mittricker , Simon C. Weston , Scott J. Weigel
发明人： Narasimhan Sundaram , Ramesh Gupta , Hans Thomann , Hugo S. Caram , Loren K. Starcher , Franklin F. Mittricker , Simon C. Weston , Scott J. Weigel
IPC分类号： F02C6/04 , F02C3/34 , B01D53/047
CPC分类号： F02C3/34 , B01D53/047 , B01D2253/1124 , B01D2256/10 , B01D2257/504 , B01D2258/0283 , B01D2259/40056 , F01K17/04 , F02C6/04 , F02C9/16 , F05D2220/31 , F05D2220/32 , F05D2260/61 , F23J2215/50 , Y02C10/04 , Y02C10/08 , Y02E20/14 , Y02E20/16
摘要： Systems and methods are provided for combined cycle power generation while reducing or mitigating emissions during power generation. Recycled exhaust gas from a power generation combustion reaction can be separated using a swing adsorption process so as to generate a high purity CO2 stream while reducing/minimizing the energy required for the separation and without having to reduce the temperature of the exhaust gas. This can allow for improved energy recovery while also generating high purity streams of carbon dioxide and nitrogen.
摘要翻译：提供系统和方法用于联合循环发电，同时减少或减少发电过程中的排放。来自发电燃烧反应的回收废气可以使用回转吸附法分离，以产生高纯度CO 2流，同时减少/最小化分离所需的能量，而不必降低废气的温度。这可以改善能量回收同时产生高纯度的二氧化碳和氮气流。

8. 发明授权

US07289909B2 Method for borehole measurement of formation properties 失效
标题翻译：钻孔测量方法
公开(公告)号：US07289909B2
公开(公告)日：2007-10-30
申请号：US10779885
申请日：2004-02-17
申请人： Hans Thomann , Charles F. Pepper , Stuart R. Keller
发明人： Hans Thomann , Charles F. Pepper , Stuart R. Keller
IPC分类号： G01V1/40 , G06G7/48
CPC分类号： G01V1/50
摘要： The present invention is a method of estimating formation properties by analyzing acoustic waves that are emitted from and received by a bottom hole assembly. A bottom hole assembly may be deployed in a borehole to estimate formation properties. From the bottom hole assembly, a source signal may be emitted and at least one signal may be received by one or more receivers in the bottom hole assembly. Analysis of the frequency dependent characteristics of the received signal allows the estimation of the formation properties of interest, including pore pressure. The formation properties of interest may be used to monitor a wellbore pressure safety margin and to optimize drilling mud weight.
摘要翻译：本发明是通过分析从底孔组件发出并接收的声波来估计地层特性的方法。井底组件可以部署在钻孔中以估计地层特性。从井底组件可以发射源信号，并且至少一个信号可以由底孔组件中的一个或多个接收器接收。对接收信号的频率依赖特性的分析允许估计感兴趣的形成特性，包括孔隙压力。感兴趣的形成特性可用于监测井眼压力安全裕度，并优化钻井泥浆重量。

9. 发明授权

US08436609B2 Method and apparatus for detection of a liquid under a surface 有权
标题翻译：用于检测表面下的液体的方法和装置
公开(公告)号：US08436609B2
公开(公告)日：2013-05-07
申请号：US12672969
申请日：2008-08-29
申请人： Leonard J. Srnka , Timothy J. Nedwed , Hans Thomann , Robert E. Sandstrom
发明人： Leonard J. Srnka , Timothy J. Nedwed , Hans Thomann , Robert E. Sandstrom
IPC分类号： G01V3/00
CPC分类号： G01V3/175 , G01N24/08 , G01N24/081 , G01R33/50 , Y02A90/344
摘要： Methods for detecting a liquid under a surface and characterizing Ice are provided The liquid may be a liquid hydrocarbon such as crude oil or fuel oil or mineral oil The surface may be ice, snow, or water, and the method may be practiced in an arctic region to detect oil spills, leaks, or seepages The methods may be used with a range finder to characterize marine ice The methods may include a nuclear magnetic resonance (NMR) tool with antenna to send a radio-frequency (RF) excitation pulse or signal into volume of substances being detected, detect an NMR response signal to determine the presence of the liquid of interest The NMR response may include a relaxation time element and an intensity level and may include a free induction signal (T2*), a spin echo signal (T2), a train of spin echo signals (T2), or a thermal equilibrium signal (T 1).
摘要翻译：提供用于检测表面下的液体并表征冰的方法液体可以是诸如原油或燃料油或矿物油的液体烃。表面可以是冰，雪或水，并且该方法可以在北极检测漏油，泄漏或泄漏的方法可以与测距仪一起使用以表征海洋冰。该方法可以包括具有天线的核磁共振（NMR）工具以发送射频（RF）激发脉冲或信号检测到的物质的体积，检测NMR响应信号以确定感兴趣的液体的存在。NMR响应可以包括弛豫时间元素和强度水平，并且可以包括自由感应信号（T2 *），自旋回波信号（T2），一系列自旋回波信号（T2）或热平衡信号（T 1）。

10. 发明授权

US08384379B2 Non-destructive determination of the pore size distribution and the distribution of fluid flow velocities 有权
标题翻译：非破坏性测定孔径分布和流体流速分布
公开(公告)号：US08384379B2
公开(公告)日：2013-02-26
申请号：US12675087
申请日：2008-10-01
申请人： Robert D. Nielsen , Hans Thomann
发明人： Robert D. Nielsen , Hans Thomann
IPC分类号： G01V3/00 , G01V33/20
CPC分类号： G01V3/32 , G01N24/081 , G01R33/5617 , G01R33/56308 , G01R33/56358
摘要： A method is disclosed for the non-destructive determination of the pore size distribution and the distribution of fluid flow velocities using NMR spin echo signal measurements. In one embodiment, the invention involves simultaneously injecting acoustic energy (208), generating a magnetic field having a gradient, and injecting radio-frequency electromagnetic energy (206) into a subsurface region, using for example an NMR tool and a well logging tool having an acoustic transmitter placed in a wellbore (202). The spin echo signal generated in the subsurface region is measured (210) by the NMR tool for at least two values (212) of the magnetic field gradient. A relationship is provided by which the pore fluid velocity distribution may be calculated (214) from the inverse Fourier transform of the spin echo data. The pore size distribution may then be calculated from the pore fluid velocity distribution.
摘要翻译：公开了一种使用NMR自旋回波信号测量法非破坏性地确定孔径分布和流体流速分布的方法。在一个实施例中，本发明涉及同时注入声能（208），产生具有梯度的磁场，并且使用例如NMR工具和测井工具将射频电磁能（206）注入到地下区域放置在井筒（202）中的声发射器。通过NMR工具对磁场梯度的至少两个值（212）测量（210）在地下区域中产生的自旋回波信号。提供了一种关系，通过该关系可以从自旋回波数据的逆傅里叶变换计算孔隙流体速度分布（214）。然后可以从孔隙流体速度分布计算孔径分布。

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