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51. 发明申请

US20080188598A1 Salts of alkyl esters of carboxyethyl(Alkyl)phosphinic acid 失效
标题翻译：羧乙基（烷基）次膦酸的烷基酯的盐
公开(公告)号：US20080188598A1
公开(公告)日：2008-08-07
申请号：US11999986
申请日：2007-12-07
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause
IPC分类号： C08K5/51 , C07F9/30 , C07F9/32
CPC分类号： C09K21/12 , C07F9/301 , C08K5/5313
摘要： The invention relates to salts of alkyl esters of carboxyethyl(alkyl)phosphinic acid, where the salts have the formula (I) R1—P(═O)(OX)—CH2—CH2—CO2R2 in which R1 and R2 are identical or different and, independently of one another, are C1-C20-alkyl, C2-C20-alkenyl, C1-C20-alkynyl, and/or C6-C20-aralkyl, and X is an alkali metal, an element of the second main and transition group, an element of the third main and transition group, an element of the fourth main and transition group, an element of the fifth main and transition group, an element of the sixth main group, an element of the seventh transition group, or an element of the eighth transition group, and also to processes for their preparation, and to their use.
摘要翻译：本发明涉及羧乙基（烷基）次膦酸的烷基酯的盐，其中盐具有式（I）<？in-line-formula description =“In-line formula”end =“lead”？> R SUP > - > - （ - O）（OX）-CH 2 -CH 2 - - - - - 2 <？in-line-formula description =“在线公式”end =“tail”？>其中R 1和R 2是相同的，或不同且彼此独立地为C 1 -C 20 - 烷基，C 2 -C 20烷基，C 1 -C 20烷基，C 2 -C 20 - - 烯基，C 1 -C 20炔基和/或C 6 -C 20 - 芳烷基，C 1 -C 20 - X是碱金属，第二主转移体和过渡组的元素，第三主转移基团和过渡组的元素，第四主转移基团和过渡组的元素，第五主转移基团和过渡组的元素，第六大集团，第七过渡集团的要素或第八过渡集团的要素，以及其准备过程，以及他们的使用。

52. 发明授权

US07220791B2 Styrene-hypophosphite adduct, a process for preparation thereof, and its use 失效
标题翻译：苯乙烯 - 次磷酸盐加合物及其制备方法及其用途
公开(公告)号：US07220791B2
公开(公告)日：2007-05-22
申请号：US10854606
申请日：2004-05-26
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken , Peter Staniek
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken , Peter Staniek
IPC分类号： C08K5/51
CPC分类号： C07F9/4816 , C09K21/14
摘要： The invention relates to a styrene-hypophosphite adduct of the formula (I) {R9[C(Ph(R1, R2, R3, R4, R5))R6—CR7R8]n}mP(O)(O 1/x Mx+)(R10)2-m where R1, R2, R3, R4, R5, R6, R7 and R8 are identical or different and are hydrogen, alkyl, linear or branched, aryl, aralkyl, oxoalkyl, oxoaryl, aminoalkyl, and/or aminoaryl, R9 is H or a free-radical-initiator radical, R10 is H, Mx+ is Li, Na, K, Mg, Ca, Sr, Ba, Al, Ge, Sn, Bi, Sb, Pb, Ti, TiO, Zr, ZrO, Zn, Fe, Ce, Mn, and/or a protonated nitrogen base having the valency x, m=1 or 2, and n=from 1 to 100, and is the number of styrene units C(Ph(R1, R2, R3, R4, R5))R6—CR7R8 inserted into the P—H bond.
摘要翻译：本发明涉及式（I）的苯乙烯 - 次磷酸盐加合物<？in-line-formula description =“In-line Formulas”end =“lead”→> {R 9 Ph（R 1，R 2，R 2，R 3，R 4，R 5） >））R 6 -CR 7 R 8 N 3 N 2 N （O）（O 1 / x M×x +）（R 10）2-m < - in-line-formula description =“In 其中R 1，R 2，R 3，R 4，R 3，R 3，R 3，R 3， R 5，R 6，R 7和R 8是相同或不同的，是氢，烷基直链或支链的芳基，芳烷基，氧代烷基，氧代芳基，氨基烷基和/或氨基芳基，R 9是H或自由基引发剂基，R 10是 H，M x +是Li，Na，K，Mg，Ca，Sr，Ba，Al，Ge，Sn，Bi，Sb，Pb，Ti，TiO，Zr，ZrO，Zn，Fe， Ce，Mn和/或具有化合价x，m = 1或2，n = 1至100的质子化氮碱，并且是苯乙烯单元C（Ph（R 1） UB 2，R 2，R 3，R 4，R 5））R 6，插入到PH键中的一个或多个R 7 R 8。

53. 发明申请

US20060287418A1 Nanoparticulate phosphorus-containing flame retardant system 审中-公开
标题翻译：纳米微粒含磷阻燃体系
公开(公告)号：US20060287418A1
公开(公告)日：2006-12-21
申请号：US11182459
申请日：2005-07-15
申请人： Harald Bauer , Werner Krause , Martin Sicken , Norbert Weferling
发明人： Harald Bauer , Werner Krause , Martin Sicken , Norbert Weferling
IPC分类号： C08K5/52
CPC分类号： C08K5/5313 , C07F9/30 , C07F9/305 , C08K5/0091
摘要： The invention relates to a nanoparticulate phosphorus-containing flame retardant system, which comprises a phosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II) and/or their polymers, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4; and to a process for the preparation of these flame retardant systems, and to their use.
摘要翻译：本发明涉及一种纳米颗粒含磷阻燃体系，其包含式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物，其中R 1， O 2和R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4; 以及制备这些阻燃体系的方法及其应用。

54. 发明授权

US07148276B2 Granular flame-retardant composition 有权
标题翻译：颗粒阻燃组合物
公开(公告)号：US07148276B2
公开(公告)日：2006-12-12
申请号：US10656398
申请日：2003-09-05
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C08K5/53
CPC分类号： C08K5/5313
摘要： The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1–C6-alkyl, linear or branched, and/or aryl; R3 is C1–C10-alkylene, linear or branched, C6–C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.
摘要翻译：本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些的聚合物，其中R 1和 R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含B1，B2和/或B3组分，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与三聚氰胺的复合盐，黑夜和/或混战。

55. 发明申请

US20050143503A1 Phosphorus-containing flame retardant agglomerates 有权
标题翻译：含磷阻燃剂
公开(公告)号：US20050143503A1
公开(公告)日：2005-06-30
申请号：US10959515
申请日：2004-10-06
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C09K21/12 , B01J2/28 , C08K5/00 , C08K5/5313 , C08K9/04 , C08L101/00 , C09K21/02 , C09K21/10 , C08K5/49
CPC分类号： C08K5/0066 , C08J3/223 , C08J2367/02 , C08J2377/02 , C08J2377/06 , C08K5/5313
摘要： The invention relates to phosphorus-containing flame retardant agglomerates comprising a) from 99.99 to 80% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or composed of a diphosphinic salt of the formula (II), and/or composed of polymers of these, where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and b) from 0.01 to 20% by weight of auxiliaries. The invention likewise relates to a process for the production of these phosphorus-containing flame retardant agglomerates, and also to polymeric compositions and moldings which comprise these phosphorus-containing flame retardant agglomerates.
摘要翻译：本发明涉及含磷阻燃附聚物，其包含a）99.99至80重量％的由式（I）的次膦酸盐组成的和/或由式（I）的次膦酸盐和/或由式（I）的二膦酸盐组成的聚集体和/ II）和/或由它们的聚合物组成，其中R 1，R 2，R 2相同或不同，为C 1 -C 3烷基，直链或支链的亚烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，b）为0.01至20重量％的助剂。本发明同样涉及一种生产这些含磷阻燃附聚物的方法，以及包含这些含磷阻燃剂附聚物的聚合物组合物和模制品。

56. 发明授权

US10421909B2 Mixed alkali-aluminum phosphites, method for producing same, and the use thereof 有权
公开(公告)号：US10421909B2
公开(公告)日：2019-09-24
申请号：US14362871
申请日：2012-11-28
申请人： Harald Bauer , Sebastian Hoerold , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Martin Sicken
IPC分类号： C09K21/04 , C01F7/00 , C01B25/163 , C08K3/32 , C08K7/14 , C08K5/56
摘要： The invention relates to mixed alkali-aluminum phosphites of the formula (I) Al2.00Mz(HPO3)y(OH)vx(H2O)w (I) in which M represents alkali metal ions, z is 0.01 to 1.5, y is 2.63 to 3.5, v is 0 to 2, w is 0 to 4; to a process for preparation thereof and to the use thereof.

57. 发明授权

US10202549B2 Mixtures of aluminum phosphite with sparingly soluble aluminum salts and foreign ions, process for the production thereof and the use thereof 有权
公开(公告)号：US10202549B2
公开(公告)日：2019-02-12
申请号：US14362881
申请日：2012-11-28
申请人： Harald Bauer , Sebastian Hoerold , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Martin Sicken
IPC分类号： C08K3/32 , C09K21/04 , C01B25/163
摘要： The invention relates to mixtures of aluminum phosphite with sparingly soluble aluminum salts and nitrogen-free extraneous ions, comprising 80 to 99.898% by weight of aluminum phosphite of the formula (I) Al2(HPO3)3xH2O (I) in which x is 0 to 4, 0.1 to 10% by weight of sparingly soluble aluminum salts and 0.002 to 10% by weight of nitrogen-free extraneous ions; to a process for preparation thereof and use thereof.

58. 发明申请

US20150005427A1 Mixtures of Aluminum Phosphite with Sparingly Soluble Aluminum Salts and Foreign Ions, Process for the Production Thereof and The Use Thereof 审中-公开
标题翻译：亚磷酸铝与可溶性铝盐和外来离子的混合物，其生产工艺及其用途
公开(公告)号：US20150005427A1
公开(公告)日：2015-01-01
申请号：US14362881
申请日：2012-11-28
申请人： Harald Bauer , Sebastian Hoerold , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Martin Sicken
IPC分类号： C09K21/04 , C08K3/32
CPC分类号： C09K21/04 , C01B25/163 , C01P2004/61 , C01P2006/11 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/80 , C01P2006/82 , C08K3/32
摘要： Mixtures of aluminum phosphite with sparingly soluble aluminum salts and extraneous ions, process for preparation thereof and use thereofThe invention relates to mixtures of aluminum phosphite with sparingly soluble aluminum salts and nitrogen-free extraneous ions, comprising 80 to 99.898% by weight of aluminum phosphite of the formula (I) Al2(HPO3)3×H2O (I) in which x is 0 to 4, 0.1 to 10% by weight of sparingly soluble aluminum salts and 0.002 to 10% by weight of nitrogen-free extraneous ions; to a process for preparation thereof and use thereof.
摘要翻译：亚磷酸铝与微溶性铝盐和外来离子的混合物，其制备方法及其用途本发明涉及亚磷酸铝与微溶铝盐和无氮外来离子的混合物，其包含80至99.898重量％的亚磷酸铝式（I）其中x为0至4的式（I）Al 2（HPO 3）3×H 2 O（I），0.1至10重量％的微溶铝盐和0.002至10重量％的无氮外来离子; 涉及其制备方法及其应用。

59. 发明申请

US20130210975A1 Flameproof Agent Stabiliser Combination for Thermoplastic and Duroplastic Polymers 有权
标题翻译：防火剂稳定剂组合用于热塑性塑料和杜尔塑料聚合物
公开(公告)号：US20130210975A1
公开(公告)日：2013-08-15
申请号：US13643784
申请日：2011-04-20
申请人： Sebastian Hoerold , Harald Bauer , Michael Hill
发明人： Sebastian Hoerold , Harald Bauer , Michael Hill
IPC分类号： C08K13/02
CPC分类号： C08K13/02 , C08K3/016 , C08K5/5313 , C08K2201/014 , C09K21/12
摘要： The invention relates to a novel flameproof agent stabiliser combination for thermoplastic and duroplastic polymers, containing, as component A 25 - 97.7 wt % of a dialkylphosphinic acid salt of formula (I) and/or a diphosphinic acid salt of formula (II) and/or polymers thereof, wherein R1, R2 are the same or different and represent C1-C6-alkyl, linear or branched and/or aryl; R3 represents C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m represents 1-4; n represents 1-4; x represents 1-4, as component B 2-45 wt. % of a monoalkylphosphinic acid salt of general formula (Ill), wherein R4 represents C1-C6-alkyl, linear or branched; M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; representing, as component C 0.3 - 30 wt. % of a synergist containing nitrogen or a phosphorous/nitrogen flameproof agent and as component D 0-10 wt. % of a zinc salt or a basic or amphoteric oxide, hydroxide, carbonate, silicate, borate, stannate, mixed oxide-hydroxides, oxide-hydroxide-carbonate, hydroxide-silicates or hydroxide-borates or mixtures of said substances, as components E 0-3 wt. % phosphonite or a phosphonite/phosphite mixture and as component F 0-3 wt.% of an ester or salt of long-chained carboxylic acids, the total of the components always amounting to 100 wt. %.
摘要翻译：本发明涉及用于热塑性和硬质聚合物的新型防火剂稳定剂组合物，其包含作为组分A 25-97.7重量％的式（I）的二烷基次膦酸盐和/或式（II）的二次膦酸盐和/ 或其聚合物，其中R 1，R 2相同或不同，表示C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3表示C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基，C 7 -C 20 - 烷基亚芳基或C 7 -C 20 - 芳基亚烷基; M表示Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m表示1-4; n表示1-4; x表示1-4，作为组分B 2-45wt。％的通式（III）的单烷基次膦酸盐，其中R 4表示直链或支链的C 1 -C 6 - 烷基; M表示Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; 作为组分C 0.3〜30wt。％的含氮或磷/氮防火剂的增效剂和作为组分D 0-10wt。％的锌盐或碱性或两性氧化物，氢氧化物，碳酸盐，硅酸盐，硼酸盐，锡酸盐，混合氧化物 - 氢氧化物，氧化物 - 氢氧化物 - 碳酸盐，氢氧化物 - 硅酸盐或氢氧化物 - 硼酸盐或所述物质的混合物， -3重量％％亚膦酸盐或亚磷酸盐/亚磷酸盐混合物，并且作为组分F 0-3重量％的长链羧酸的酯或盐，总量总计为100重量％％。

60. 发明申请

US20120175260A1 Device And Method For Simultaneous Coating Or De-Coating Of A Plurality Of Workpieces And Workpiece 有权
标题翻译：同时涂层或多层工件脱模的装置和方法
公开(公告)号：US20120175260A1
公开(公告)日：2012-07-12
申请号：US13259671
申请日：2010-05-11
申请人： Rolf Keller , Harald Bauer , Michael Lingner
发明人： Rolf Keller , Harald Bauer , Michael Lingner
IPC分类号： C25D21/10 , C25F5/00 , B23H3/00 , C25D17/10 , C25D17/02
CPC分类号： C25D5/022 , C25D5/08 , C25D17/06 , C25D17/12 , C25D17/18 , C25F5/00 , C25F7/00
摘要： A device for simultaneous coating of a plurality of workpieces is described, the plurality of workpieces being situated in a shared flow shaft through which an electrolyte flows, and each workpiece being connected electrically conducting to at least one component electrode and being electrically insulated in relation to at least one bath electrode, and a plurality of flow channels and a flow distributor for distributing the electrolyte stream to the plurality of flow channels further being situated in the flow shaft, the at least one bath electrode being situated in one of the flow channels.
摘要翻译：描述了用于同时涂覆多个工件的装置，所述多个工件位于共享流动轴中，电解液通过所述共用流动轴流动，并且每个工件被连接导电至至少一个部件电极并相对于至少一个浴电极，以及多个流动通道和用于将所述电解质流分配到所述多个流动通道的流量分配器，所述多个流动通道进一步位于所述流动轴中，所述至少一个浴电极位于所述流动通道中的一个中。

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