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    • 58. 发明授权
    • Process for preparing alkyl isocyanates
    • 烷基异氰酸酯的制备方法
    • US4514339A
    • 1985-04-30
    • US608984
    • 1984-05-10
    • Ugo RomanoFranco RivettiGiacomo Sasselli
    • Ugo RomanoFranco RivettiGiacomo Sasselli
    • C07C265/04C07C20060101C07C67/00C07C69/00C07C241/00C07C249/00C07C263/00C07C263/04
    • C07C263/04
    • Process for the production of alkyl isocyanates which can be defined by the general formula: R--N.dbd.C.dbd.O wherein R is an alkyl radical having from 1 to 4 carbon atoms by thermal decomposition of phenyl-N-alkyl urethans which can be defined by the general formula: ##STR1## wherein R has the above defined meaning. Said thermal decomposition is carried out without any substance having a catalytic activity being present in the decomposition reaction, by heating to a temperature of from 180.degree. C. to 210.degree. C. under the atmospherical pressure or a slightly reduced pressure, a mixture of phenol and phenyl-N-alkyl urethan, in a molar ratio of the former to the latter equal to or nearly equal to 1:1, removing by vaporization the phenol and the alkyl isocyanate from said vaporized products and maintaining in the reaction mixture, substantially throughout the thermal decomposition a molar ratio of phenol to phenyl-N-alkyl urethan not lower than about 1:1.
    • 制备烷基异氰酸酯的方法,其可以由通式RN = C = O定义,其中R是通过苯基-N-烷基氨基甲酸酯的热分解具有1至4个碳原子的烷基,其可以由 通式:其中R具有上述定义的含义。 所述热分解在没有任何具有催化活性的物质在分解反应中进行,通过在大气压或稍微减压下加热至180℃至210℃的温度,苯酚 和苯基-N-烷基氨基甲酸酯以前者与后者的摩尔比等于或几乎等于1:1,通过蒸发从所述汽化产物中蒸发苯酚和异氰酸烷基酯并基本上保持在反应混合物中 苯酚与N-烷基氨基甲酸酯的摩尔比热分解不低于约1:1。