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    • 51. 发明申请
    • Plasma oxidation of a memory layer to form a blocking layer in non-volatile charge trap memory devices
    • 存储层的等离子体氧化在非挥发性电荷陷阱存储器件中形成阻挡层
    • US20090242962A1
    • 2009-10-01
    • US12080175
    • 2008-03-31
    • Krishnaswamy RamkumarSagy LevyJeong Byun
    • Krishnaswamy RamkumarSagy LevyJeong Byun
    • H01L21/28H01L29/423
    • H01L21/28282H01L29/4234H01L29/792
    • A blocking layer of a non-volatile charge trap memory device is formed by oxidizing a portion of a charge trapping layer of the memory device. In one embodiment, the blocking layer is grown by a radical oxidation process at temperature below 500° C. In accordance with one implementation, the radical oxidation process involves flowing hydrogen (H2) and oxygen (O2) gas mixture into a process chamber and exposing the substrate to a plasma. In a preferred embodiment, a high density plasma (HDP) chamber is employed to oxidize a portion of the charge trapping layer. In further embodiments, a portion of a silicon-rich silicon oxynitride charge trapping layer is consumptively oxidized to form the blocking layer and provide an increased memory window relative to oxidation of a nitrogen-rich silicon oxynitride layer.
    • 通过氧化存储器件的电荷俘获层的一部分来形成非易失性电荷陷阱存储器件的阻挡层。 在一个实施方案中,通过自由基氧化法在低于500℃的温度下生长阻挡层。根据一个实施方案,自由基氧化过程包括将氢(H 2)和氧(O 2)气体混合物流入处理室并暴露 衬底到等离子体。 在优选实施例中,使用高密度等离子体(HDP)室来氧化电荷俘获层的一部分。 在另外的实施例中,一部分富硅氧氮化硅电荷捕获层被消耗氧化以形成阻挡层,并且相对于富氮氧氮化硅层的氧化提供增加的存储窗口。