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    • 48. 发明授权
    • Process for spinning fibers of ionic thermoplastic polymers
    • 离子热塑性聚合物纺丝方法
    • US4259284A
    • 1981-03-31
    • US12114
    • 1979-02-14
    • Robert D. LundbergHenry S. Makowski
    • Robert D. LundbergHenry S. Makowski
    • C08K5/00C08L23/32C08L25/18D01F6/02D01F6/22D01F6/28D01F6/00
    • D01F6/28C08K5/0016C08L23/32C08L25/18D01F6/02D01F6/22
    • The present invention relates to an improved process for forming fibers for fabrics from neutralized sulfonated thermoplastic polymers, and novel ionic polymer fiber compositions derived therefrom, wherein the neutralized sulfonated thermoplastic polymer is dissolved in a solvent, preferably a mixed solvent, consisting of a backbone solvent and a polar cosolvent and spun into fibers. The neutralized sulfonated thermoplastic polymer has about 10 to about 100 meq. SO.sub.3 H per 100 grams of sulfonated thermoplastic polymer, of which at least 95% is neutralized with a cation being selected from the group consisting essentially of antimony, iron, lead, aluminum, or Groups I-A, II-A, I-B or II-B of the Periodic Table of Elements and mixture thereof. The solution of the neutralized sulfonated thermoplastic polymer having a Brookfield viscosity at room temperature at about 6 rpm of about 1,000 to about 200,000 cps is fabricated into fibers by wet or dry spinning through a spinner having a plurality of orifices therein. The resultant fibers exhibit improved dimensional stability and resistance to solvents and temperature when fabricated into a fabric.
    • 本发明涉及一种用于从中和磺化热塑性聚合物形成织物纤维的改进方法和由其衍生的新型离子聚合物纤维组合物,其中中和的磺化热塑性聚合物溶解在溶剂中,优选由主要溶剂组成的混合溶剂 和极性助溶剂并纺成纤维。 中和的磺化热塑性聚合物具有约10至约100meq。 SO 3 H / 100克磺化热塑性聚合物,其中至少95%被阳离子中和,阳离子主要由锑,铁,铅,铝或IA,II-A,IB或II-B族组成 元素周期表及其混合物。 通过湿法或干纺法通过其中具有多个孔的旋转器将具有Brookfield粘度的Brookfield粘度的中和磺化热塑性聚合物溶液在大约6rpm的约1000至约200,000cps下制成纤维。 当制成织物时,所得纤维表现出改进的尺寸稳定性和耐溶剂性和耐温度。
    • 49. 发明授权
    • Fibers of ionic thermoplastic polymers
    • 离子热塑性聚合物纤维
    • US4226751A
    • 1980-10-07
    • US12118
    • 1979-02-14
    • Robert D. LundbergHenry S. Makowski
    • Robert D. LundbergHenry S. Makowski
    • C08J3/09C08L23/32D01F6/04D01F6/22C08L91/06
    • C08J3/091C08J3/09C08L23/32D01F6/04D01F6/22C08J2325/18C08J2357/06
    • The present invention relates to an improved process for forming fibers for fabrics from neutralized sulfonated thermoplastic polymers, and novel ionic polymer fiber compositions derived therefrom, wherein the neutralized sulfonated thermoplastic polymer is dissolved in a solvent, preferably a mixed solvent, consisting of a backbone solvent and a polar cosolvent and spun into fibers. The neutralized sulfonated thermoplastic polymer has about 10 to about 100 meq. SO.sub.3 H per 100 grams of sulfonated thermoplastic polymer, of which at least 95% is neutralized with a cation being selected from the group consisting essentially of antimony, iron, lead, aluminum, or Groups I-A, II-A, I-B or II-B of the Periodic Table of Elements and mixture thereof. The solution of the neutralized sulfonated thermoplastic polymer having a Brookfield viscosity at room temperature at about 6 rpm of about 1,000 to about 200,000 cps is fabricated into fibers by wet or dry spinning through a spinner having a plurality of orifices therein. The resultant fibers exhibit improved dimensional stability and resistance to solvents and temperature when fabricated into a fabric.
    • 本发明涉及一种用于从中和磺化热塑性聚合物形成织物纤维的改进方法和由其衍生的新型离子聚合物纤维组合物,其中中和的磺化热塑性聚合物溶解在溶剂中,优选由主要溶剂组成的混合溶剂 和极性助溶剂并纺成纤维。 中和的磺化热塑性聚合物具有约10至约100meq。 SO 3 H / 100克磺化热塑性聚合物,其中至少95%被阳离子中和,阳离子主要由锑,铁,铅,铝或IA,II-A,IB或II-B族组成 元素周期表及其混合物。 通过湿法或干纺法通过其中具有多个孔的旋转器将具有Brookfield粘度的Brookfield粘度的中和磺化热塑性聚合物溶液在大约6rpm的约1000至约200,000cps下制成纤维。 当制成织物时,所得纤维表现出改进的尺寸稳定性和耐溶剂性和耐温度。
    • 50. 发明授权
    • Fibers of ionic thermoplastic polymers
    • 离子热塑性聚合物纤维
    • US4172820A
    • 1979-10-30
    • US855550
    • 1977-11-29
    • Robert D. LundbergHenry S. Makowski
    • Robert D. LundbergHenry S. Makowski
    • D01F6/22C08K5/00C08L23/32C08L25/18D01F6/28C08L91/00
    • C08L23/32C08K5/0016C08L25/18D01F6/28
    • The present invention relates to an improved process for forming fibers for fabrics from neutralized sulfonated thermoplastic polymers, and novel ionic polymer fiber compositions derived therefrom, wherein the neutralized sulfonated thermoplastic polymer is dissolved in a solvent, preferably a mixed solvent, consisting of a backbone solvent and a polar cosolvent and spun into fibers. The neutralized sulfonated thermoplastic polymer has about 10 to about 100 meq. SO.sub.3 H per 100 grams of sulfonated thermoplastic polymer, of which at least 95% is neutralized with a cation being selected from the group consisting essentially of antimony, iron, lead, aluminum, or Groups I-A, II-A, I-B or II-B of the Periodic Table of Elements and mixture thereof. The solution of the neutralized sulfonated thermoplastic polymer having a Brookfield viscosity at room temperature at about 6 rpm of about 1,000 to about 200,000 cps is fabricated into fibers by wet or dry spinning through a spinner having a plurality of orifices therein. The resultant fibers exhibit improved dimensional stability and resistance to solvents and temperature when fabricated into a fabric.
    • {PG,1]本发明涉及一种用于从中和磺化热塑性聚合物形成织物纤维的改进方法和由其衍生的新型离子聚合物纤维组合物,其中中和的磺化热塑性聚合物溶于溶剂,优选混合溶剂中, 的主链溶剂和极性助溶剂,并纺丝成纤维。 中和的磺化热塑性聚合物具有约10至约100meq。 SO {HD 3 {LH / 100克磺化热塑性聚合物,其中至少95%被阳离子中和的阳离子基本上由锑,铁,铅,铝或IA,II-A,IB组成的组中和 或元素周期表II-B及其混合物。 通过湿法或干纺法通过其中具有多个孔的旋转器将具有Brookfield粘度的Brookfield粘度的中和磺化热塑性聚合物溶液在大约6rpm的约1,000至约200,000cps下制成纤维。 当制成织物时,所得纤维表现出改进的尺寸稳定性和耐溶剂性和耐温度。