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    • 50. 发明授权
    • Acylated mono and/or bis-succinimides lubricating oil additives
    • 酰化单和/或双琥珀酰亚胺润滑油添加剂
    • US5460740A
    • 1995-10-24
    • US265669
    • 1994-06-22
    • Cyril A. MigdalWilly P. BroeckxJohn F. Lucas
    • Cyril A. MigdalWilly P. BroeckxJohn F. Lucas
    • C10M133/56C10M133/16C10M149/00
    • C10M133/56C10M2215/04C10M2215/26C10M2217/046C10M2217/06C10M2227/061C10N2240/10C10N2240/101C10N2240/104C10N2240/106
    • A lubricating oil composition comprising a major portion of a lubricating oil and a minor amount of an additive. The additive is prepared by reacting a polyamine with an alkenyl succinic acid anhydride having a number average molecular weight of about 500 to about 10,000 at a temperature of 60.degree. C.-120.degree. C. to form mono-alkenyl succinimide, bis-alkenyl succinimide or a mixture of mono- and bis-alkenyl succinimide. 2-pyrrolidone-5-carboxylic acid is then added to form an acylated mono-alkenyl succinimide, bis-alkenyl succinimide or mixture of mono- and bis-alkenyl succinimide. The acylated mono-alkenyl succinimide, bis-alkenyl succinimide or mixture of mono- and bis-alkenyl succinimide is acylated with an acylating compound selected from the group consisting of glycolic acid, oxalic acid, lactic acid, 2-hydroxymethyl-propionic acid and 2,2-bis(hydroxymethyl) propionic acid at a temperature of about 150.degree. C. to about 185.degree. C., to form a mixed acylated mono-alkenyl succinimide, bis-alkenyl succinimide or mixture of mono- and bis-alkenyl succinimide and the mixed acylated mono-alkenyl succinimide, bis-alkenyl succinimide or mixture of mono- and bis-alkenyl succinimide is recovered.
    • 一种润滑油组合物,其包含主要部分的润滑油和少量的添加剂。 该添加剂通过使多胺与数均分子量为约500至约10,000的烯基琥珀酸酐在60℃-120℃的温度下反应制备,以形成单链烯基琥珀酰亚胺,双链烯基琥珀酰亚胺 或单 - 和二链烯基琥珀酰亚胺的混合物。 然后加入2-吡咯烷酮-5-羧酸以形成酰化单链烯基琥珀酰亚胺,双链烯基琥珀酰亚胺或单链烯基和双链烯基琥珀酰亚胺的混合物。 酰化单链烯基琥珀酰亚胺,双链烯基琥珀酰亚胺或单链烯基和双链烯基琥珀酰亚胺的混合物用选自乙醇酸,草酸,乳酸,2-羟甲基 - 丙酸和2 ,2-双(羟甲基)丙酸在约150℃至约185℃的温度下反应,形成混合的酰化单烯基琥珀酰亚胺,双烯基琥珀酰亚胺或单 - 和二 - 链烯基琥珀酰亚胺的混合物和 回收混合的酰化单链烯基琥珀酰亚胺,双链烯基琥珀酰亚胺或单链和双链烯基琥珀酰亚胺的混合物。