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    • 46. 发明授权
    • Isometric isoindoline yellow pigment
    • 等量异吲哚啉黄色素
    • US08075683B2
    • 2011-12-13
    • US12744742
    • 2008-12-08
    • Rüdiger HainzJean AllazDidier Schroeder
    • Rüdiger HainzJean AllazDidier Schroeder
    • C09B67/14C09B67/20C09B57/04C08K5/00
    • C09B67/0025C08K5/0041C09B67/0017
    • Pigment of formula wherein R1 is CONR4R5 or C(═NR6)NR7R8, R2, R3, R4 and R5 are each independently of the others H, C1-C5alkyl, or phenyl which is unsubstituted or substituted from 1 to 5 times by C1-C5alkyl or by halogen, R6 is phenyl which is unsubstituted or substituted from 1 to 4 times by C1-C5alkyl or by halogen, R7 is H or C1-C5alkyl, and R8 is a direct bond or a carbonyl bridge to R6, which pigment consists of primary particles the average aspect ratio of which is from 4 to 1, preferably from 3.5 to 1, especially from 3 to 1, and for the ellipses equivalent to the contours of the primary particles on a two-dimensional electron microscopic image have an average numerical eccentricity ε of from 0 to 0.80, the numerical eccentricity ε being defined as (formula), wherein a is the semimajor axis and b is the semiminor axis of the equivalent ellipse. That pigment preferably has a narrow particle size distribution and is, as are analogous pigments, prepared by a novel process. The invention relates also to a process for the preparation of that pigment, wherein R1CH2CN or (formula) is dispersed in an acidic aqueous medium containing from 70 to 99% by weight water, preferably in the presence of a dispersant, and is reacted with solid (formula). preferably ɛ = a 2 - b 2 a
    • 下式的颜料其中R 1是CONR 4 R 5或C(= NR 6)NR 7 R 8,R 2,R 3,R 4和R 5各自独立地是H,C 1 -C 5烷基或被未取代的或被C 1 -C 5烷基取代1至5倍的苯基 或者被卤素取代,R6是未被取代或被C1-C5烷基或卤素取代1〜4次的苯基,R7是H或C1-C5烷基,R8是与R6直接键合或羰基桥连接,该颜料由 一次粒子的平均纵横比为4比1,优选3.5比1,特别是3比1,对于二维电子显微镜图像上与一次粒子轮廓等价的椭圆平均数值 偏心率 从0到0.80,数值偏心率 被定义为(公式),其中a是半长轴,b是等效椭圆的半正轴。 该颜料优选具有窄的粒度分布,并且与通过新方法制备的类似颜料一样。 本发明还涉及一种制备该颜料的方法,其中R1CH2CN或(式)分散在含有70-99%(重量)水的酸性含水介质中,优选在分散剂存在下,并与固体 (式)。 优选ε= a 2 - b 2 a