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    • 43. 发明授权
    • Highly water-absorptive polymers having enhanced gel strength
    • 具有增强凝胶强度的高吸水性聚合物
    • US5973042A
    • 1999-10-26
    • US664311
    • 1996-06-11
    • Kenji YoshinagaShozo KitagawaToshiko NakamuraMiho TanakaKiichi Ito
    • Kenji YoshinagaShozo KitagawaToshiko NakamuraMiho TanakaKiichi Ito
    • A61L15/60C08K3/22C08K3/30C08K5/092C08K5/098C08K5/20C08K5/057C08K5/11C08K5/25
    • C08K5/092A61L15/60C08K3/22C08K3/30C08K5/098
    • There is provided a highly water-absorptive polymer composition comprising:(A) 100 parts by weight of a highly water-absorptive polymer having a crosslinked structure, comprising as its constituent a carboxyl group and/or a carboxylate group; and(B) 0.05 to 10 parts by weight of an additive selected from the group consisting of an oxalic acid (salt) compound, a sulfate of a metal selected from titanium, zirconium and vanadium, and a crystalline or noncrystalline, high-purity particulate titania having a mean particle diameter of 1 .mu.m or less, a specific surface area of 10 m.sup.2 /g or more as determined by the Brunauer-Emmett-Teller method, and, when crystalline, a crystal structure of a mixed type of rutile and anatase.There is also provided a method for producing a highly water-absorptive polymer having enhanced gel strength, which comprises treating with an alkoxytitanium a highly water-absorptive polymer having a crosslinked structure, comprising as its constituent a carboxyl group and/or a carboxylate group.
    • 提供了一种高吸水性聚合物组合物,其包含:(A)100重量份具有交联结构的高吸水性聚合物,其包含作为其组分的羧基和/或羧酸酯基; 和(B)0.05至10重量份的选自草酸(盐)化合物,选自钛,锆和钒的金属硫酸盐和结晶或非结晶的高纯度颗粒的添加剂 平均粒径为1μm以下的二氧化钛,通过Brunauer-Emmett-Teller方法测定的比表面积为10m 2 / g以上,并且当结晶时,混合型金红石和 锐钛矿 还提供了一种制备具有增强的凝胶强度的高吸水性聚合物的方法,其包括用烷氧基钛处理具有交联结构的高吸水性聚合物,其包含羧基和/或羧酸酯基作为其组分。
    • 46. 发明授权
    • Aqueous dispersed resin composition
    • 水分散树脂组合物
    • US5472996A
    • 1995-12-05
    • US224521
    • 1994-04-07
    • Ryutaro HayashiMasahiro AokiToyoji TomitaYoshinori KatoTakeo TsukamotoTakeshi Awata
    • Ryutaro HayashiMasahiro AokiToyoji TomitaYoshinori KatoTakeo TsukamotoTakeshi Awata
    • C08L101/02C08F291/00C08K5/25C08L51/00C08L101/00C09D5/00C09D5/02C09D5/28C09D151/00C09D201/02C09J201/00C09J201/02C08F8/30
    • C09D151/00C08F291/00C08K5/25C08L51/003Y10S525/902
    • An aqueous dispersed resin composition comprising (A) an aqueous dispersion of carbonyl-containing resin particles having an inner layer and an outermost layer, which is obtained by emulsion polymerization of a monomer mixture comprising (a) not less than 0.5% by weight of a carbonyl-containing monomer containing at least one aldo group or keto group and one polymerizable unsaturated double bond in the molecule thereof, (b) not less than 0.5% by weight of an ethylenically unsaturated carboxylic acid, (c) not more than 99% by weight of a monomer having a water-solubility of not more than 8 g/100 ml at 20.degree. C., and (d) not more than 99% by weight of an unsaturated monomer other than the monomers (a) to (c) in the presence of dispersed resin particles serving as an inner layer and (B) a hydrophilic compound comprising a hydrazine derivative containing at least two hydrazino groups in the molecule thereof, in which the resin constituting the outermost layer of the carbonyl-containing resin particles has a degree of solubilization of at least 5% by weight, and the resin constituting the inner layer has a degree of solubilization lower than that of the resin constituting the outermost layer. The composition provides a film excellent in water resistance, adhesion to a substrate, smoothness, gloss, and resistance to whitening on contact with water.
    • 一种含水分散树脂组合物,其包含(A)具有内层和最外层的含羰基树脂颗粒的水分散体,其通过单体混合物的乳液聚合获得,所述单体混合物包含(a)不小于0.5重量% 在分子中含有至少一个醛基或酮基和一个可聚合不饱和双键的含羰基单体,(b)不小于0.5重量%的烯属不饱和羧酸,(c)不大于99重量% 在20℃下水溶性不超过8g / 100ml的单体的重量,和(d)不大于99重量%的单体(a)至(c)以外的不饱和单体, 在作为内层的分散树脂粒子的存在下,和(B)包含其分子中含有至少两个肼基的肼衍生物的亲水性化合物,其中构成含羰基的res的最外层的树脂 颗粒的增溶度为至少5重量%,构成内层的树脂的溶解度低于构成最外层的树脂的增溶度。 该组合物提供了耐水性,对基材的粘合性,平滑性,光泽度和与水接触时的美白抗性优异的膜。
    • 48. 发明授权
    • Aqueous polymer dispersions having a long shelf life
    • 具有长保质期的聚合物水分散体
    • US4931494A
    • 1990-06-05
    • US210321
    • 1988-06-23
    • Gerhard AuchterThomas SchwerzelRolf OsterlohGerhard NeubertPeter PfoehlerWolfgang DruschkeHelmut Jaeger
    • Gerhard AuchterThomas SchwerzelRolf OsterlohGerhard NeubertPeter PfoehlerWolfgang DruschkeHelmut Jaeger
    • C08F2/16C08K5/25C08L33/04C08L33/06C09J133/04C09J133/06
    • C08L33/064C08K5/25C09J133/06C08L33/06
    • Aqueous polymer dispersions which have a long shelf life are obtainable by dispersing a mixture of from 15 to 70% by weight of a copolymer (A) of(I) from 1.5 to 15% by weight of copolymerizable compounds of 3 to 10 carbon atoms which contain a carboxyl or carboxylic anhydride group,(II) from 65 to 98.5% by weight of C.sub.1 -C.sub.20 -alkyl acrylates or methacrylates,(III) from 0 to 20% by weight of vinylaromatics,(IV) from 0 to 20% by weight of copolymerizable carbonyl compounds and(V) from 0 to 10% by weight of further copolymerizable organic compounds not stated under (I) to (IV), and from 30to 85% by weight of a copolymer (B) of from 60 to 100% by weight of the monomers (II) and from 0 to 40% by weight of the monomers (III) to (V), with the proviso that the copolymers (A) and (B) together contain, as components, more than 65% by weight of alkyl (meth)acrylates (II) whose homopolymers have glass transition temperatures of less than 0.degree. C., and that one or more of the copolymers (A) and (B) contain the monomers (IV) as components, in water with the addition of ammonia and a polyhydrazide (C), and the said dispersions are used as pressure sensitive adhesives and as adhesives for laminated films.
    • 通过将15〜70重量%的(I)共聚物(A)与1.5〜15重量%的3〜10个碳原子的可共聚的化合物分散而得到的具有长保存期限的聚合物水分散体可以得到, 含有羧基或羧酸酐基团,(II)65至98.5重量%的丙烯酸或甲基丙烯酸C 1 -C 20烷基酯,(III)0至20重量%的乙烯基芳烃,(Ⅳ)0至20重量% 可共聚羰基化合物的重量和(V)0至10重量%的(I)至(IV)中未提及的另外可共聚的有机化合物,以及30至85重量%的共聚物(B)为60至100 单体(II)的重量%和单体(III)至(V)的0至40重量%,条件是共聚物(A)和(B)共同作为组分含有超过65 重量%的其均聚物具有小于0℃的玻璃化转变温度的(甲基)丙烯酸烷基酯(II),以及一种或多种共聚物(A)和( B)在水中加入氨和聚酰肼(C)作为组分含有单体(Ⅳ),所述分散体用作压敏粘合剂和层压薄膜的粘合剂。