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41. 发明授权

US5087755A Process for producing aromatic amines by reduction of aromatic nitro compounds 失效
标题翻译：通过减少芳族硝基化合物生产芳族氨基酸的方法
公开(公告)号：US5087755A
公开(公告)日：1992-02-11
申请号：US436690
申请日：1989-11-15
申请人： Kotohiro Nomura , Masaru Ishino
发明人： Kotohiro Nomura , Masaru Ishino
IPC分类号： B01J31/20 , C07B43/04 , C07B61/00 , C07C209/32 , C07C209/36 , C07C211/46 , C07C211/47 , C07C211/51 , C07C211/52 , C07C213/02 , C07C217/84 , C07C221/00 , C07C225/34 , C07C253/30 , C07C255/58
CPC分类号： C07C221/00 , C07C209/325 , C07C213/02 , C07C253/30 , C07C2103/24 , C07C2103/26
摘要： A process for producing an aromatic amine under moderate conditions is provided wherein a catalyst higher in activity than conventional catalysts is used. Reduction of an aromatic nitro compound under a CO/H.sub.2 O system is conducted using a rhodium compound catalyst in the presence of an aqueous alkali solution such as aqueous sodium hydroxide solution. Alternatively, an aromatic nitro compound is reduced under a CO/H.sub.2 O system using a rhodium compound or a ruthenium compound catalyst in the presence of the aqueous alkali solution and additionally at least one compound of amine compounds, diamine compounds, phosphine compounds, phosphite compounds, and diphosphine compounds.

42. 发明授权

US5082971A Trifluoromethylaminobenzenes containing fluorine and/or chlorine and their preparation 失效
标题翻译：含有氟和/或氯的三氟甲基苯并噻吩及其制备方法
公开(公告)号：US5082971A
公开(公告)日：1992-01-21
申请号：US487339
申请日：1990-03-01
申请人： Albrecht Marhold
发明人： Albrecht Marhold
IPC分类号： C07C211/52 , C07C67/00 , C07C209/00 , C07C209/10 , C07C209/36 , C07C211/46 , C07C211/47
CPC分类号： C07C209/365 , C07C211/52
摘要： Trifluoromethylaminobenzenes containing fluorine and/or chlorine, in which the trifluoromethyl groups are situated in the 1-position, the amino groupa) is situated in the 2-position and a fluorine atom is situated in the 6-position or two fluorine atoms are situated in the 5- and 6-position or a fluorine atom is situated in the 5-position and a chlorine atom is situated in the 6-position orb) is situated in the 3-position and a fluorine atom is situated in the 2-position or two fluorine atoms are situated in the 2- and 6-position or a chlorine atom is situated in the 2-position and a fluorine atom is situated in the 6-position orc) is situated in the 4-position and a fluorine atom is situated in the 2-position and additionally a further fluorine atom is situated in the 3- or 6-position or two further fluorine atoms are situated in the 5- and 6-position or a further fluorine atom is situated in the 6-position and two chlorine atoms are situated in the 3- and 5-position or a chlorine atom is situated in the 3-position to two chlorine atoms are situated in the 3- and 5-position ord) is situated in the 4-position and two fluorine atoms are situated in the 3- and 5-position or two chlorine atoms are situated in the 2- and 3-position or a fluorine atom is situated in the 3-position and a chlorine atom is situated in the 5-position ore) is situated in the 2-, 3- or 4-position and three fluorine atoms are situated on the aromatic ring and a process for their preparation.
摘要翻译：含有氟和/或氯的三氟甲基氨基苯，其中三氟甲基位于1-位，氨基a）位于2-位，氟原子位于6-位，或两个氟原子位于在5-和6-位或氟原子位于5-位且氯原子位于6-位或b）位于3-位，氟原子位于2-位，位置或两个氟原子位于2-和6-位，或氯原子位于2-位，氟原子位于6-位，或c）位于4-位，氟原子位于2-位，并且另外的氟原子位于3-或6-位，或另外两个氟原子位于5-和6-位，或另外的氟原子位于6-位，位置和两个氯原子位于3-和5-位或氯原子位于3-位，两个氯原子位于3-和5-位，或d）位于4-位，两个氟原子位于3-和5-位或两个氯原子位于2-和3-位，或氟原子位于3-位，氯原子位于5-位或e-位于2-，3-或4-位，三氟原子位于芳环上，其制备方法。

43. 发明授权

US5081302A Selective C-alkylation of aniline in the presence of zeolite catalysts to para-aniline 失效
标题翻译：沸石催化剂存在下苯胺的选择性C碱性
公开(公告)号：US5081302A
公开(公告)日：1992-01-14
申请号：US343876
申请日：1989-04-27
申请人： Arthur C. Bayer , Charles U. Pittman, Jr. , Lichang Wang , Earl G. Alley , Anthony C. Maliyackel
发明人： Arthur C. Bayer , Charles U. Pittman, Jr. , Lichang Wang , Earl G. Alley , Anthony C. Maliyackel
IPC分类号： B01J29/08 , C07B61/00 , C07C209/18 , C07C209/60 , C07C209/68 , C07C211/47 , C07C211/48
CPC分类号： C07C209/68
摘要： The selective ring-alkylation of anilines comprising providing a mixture of a lower alkanol and an aniline, exposing said mixture to a temperature of from 300.degree. C. to 500.degree. C., preferably from 350.degree. C. to 450.degree. C., in the presence of an acidic Y-type zeolite is described. The Y-type zeolites are predominantly selective to the formation of para-alkylanilines.
摘要翻译：苯胺的选择性环烷基化，包括提供低级链烷醇和苯胺的混合物，将所述混合物暴露于300℃至500℃，优选350℃至450℃的温度，描述了酸性Y型沸石的存在。 Y型沸石主要对对烷基苯胺的形成有选择性。

44. 发明授权

US4535162A Process for catalytically reducing nitroaromatic compounds 失效
标题翻译：催化还原硝基芳族化合物的方法
公开(公告)号：US4535162A
公开(公告)日：1985-08-13
申请号：US504748
申请日：1983-06-16
申请人： Giovanni Mestroni , Grazia Zassinovich , Enzo Alessio
发明人： Giovanni Mestroni , Grazia Zassinovich , Enzo Alessio
IPC分类号： C07D213/18 , B01J31/00 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/36 , C07C211/46 , C07C211/47 , C07C211/51 , C07C211/52 , C07D213/22 , C07D471/04 , C07D215/38 , C07D211/72 , C07D239/02
CPC分类号： C07C209/36
摘要： A process is herein described for catalytically reducing nitroaromatic compounds by displacement of hydrogen from carbon monoxide and water or from synthesis gas to nitroaromatic compounds, the catalytic reduction being catalyzed by complexes of rhodium, iridium, ruthenium and osmium; said process is characterized in that the CO+H.sub.2 O system or the (CO+H.sub.2)+H.sub.2 O system is caused to react with a nitroaromatic compound of formula:Ar--(NO.sub.2).sub.x (I)wherein Ar is an aryl or hetero-aryl group, also substituted by inert groups; x is an integer from 1 to 3, in the presence of a complex catalyst of formula:[MChel(L).sub.2 ].sup.+ X.sup.- (II)or of a catalyst composed by carbonyl compounds and chelants of formula:Mz(CO).sub.y +nChel (III)wherein M=Rh, Ir, Ru, Os; "Chel" is a bidentate or tridentate aromatic nitrogen chelating compound; "L" is a molecule of carbon monoxide or of an olefin or half a molecule of a diolefin; X.sup.- is an anion selected from Cl.sup.-, Br.sup.-, I.sup.-, PF.sub.6.sup.-, BF.sub.4.sup.-, B(C.sub.6 H.sub.5).sub.4.sup.-, CO.sub.3.sup.-- and HCO.sub.3.sup.- ; z, y are integers with n being an integer or a fractional number, at temperatures ranging from about 25.degree. C. to 250.degree. C., at a carbon monoxide pressure between 1 and 150 atmospheres.The products obtained from the hydrogenation of the starting nitroaromatic compounds consist of arylamines in general and are utilized as intermediates for the organic syntheses in the field of fine chemicals.
摘要翻译：本文描述了通过将氢从一氧化碳和水或从合成气置换为硝基芳族化合物来催化还原硝基芳族化合物的方法，催化还原由铑，铱，钌和锇的络合物催化; 所述方法的特征在于使CO + H 2 O体系或（CO + H 2）+ H 2 O体系与式Ar-（NO 2）x（I）的硝基芳族化合物反应，其中Ar是芳基或杂芳基组，也被惰性基团取代; 在具有下式的复合催化剂存在下，x是1至3的整数：[MChel（L）2] + X-（II）或由羰基化合物和下式的螯合剂组成的催化剂：Mz（CO）y + nChel（III）其中M = Rh，Ir，Ru，Os; “Chel”是二齿或三齿芳族氮螯合化合物; “L”是一氧化碳或烯烃或半分子二烯烃的分子; X-是选自Cl-，Br-，I-，PF6-，BF4-，B（C6H5）4-，CO3-和HCO3-的阴离子; z，y是在约25℃至250℃的温度范围内，在1至150个大气压的一氧化碳压力下，n为整数或分数的整数。从起始硝基芳族化合物的氢化获得的产物通常由芳基胺组成，并用作精细化学品领域的有机合成的中间体。

45. 发明授权

US4480128A Process for the manufacture of o-toluidine and/or m-toluidine and/or p-toluidine 失效
标题翻译：邻甲苯胺和/或间甲苯胺和/或对甲苯胺的制备方法
公开(公告)号：US4480128A
公开(公告)日：1984-10-30
申请号：US484179
申请日：1983-04-12
申请人： Hans-J/u/ rgen Arpe , Heinz Litterer
发明人： Hans-J/u/ rgen Arpe , Heinz Litterer
IPC分类号： C07B61/00 , B01J21/00 , B01J29/40 , C07C67/00 , C07C209/00 , C07C209/64 , C07C209/68 , C07C209/86 , C07C211/47 , C07C85/26
CPC分类号： C07C209/68
摘要： The invention provides a process for the manufacture of o-toluidine and/or m-toluidine and/or p-toluidine, which comprises the two following steps (a) and (b):(a) treatment of a toluidine isomer mixture or of the not intended toluidine isomer or of one of the not intended toluidine isomers with an isomerization catalyst selected from the group of synthetic zeolites of the pentasil type,(b) isolation of the intended isomer or one of the intended isomers from the isomer mixture formed in step (a) by selective adsorption to a medium-pore or large-pore zeolite and subsequent desorption, furthermore discharge of the isolated isomer and recycling of the remaining isomer mixture to step (a).
摘要翻译：本发明提供了制备邻甲苯胺和/或间甲苯胺和/或对甲苯胺的方法，其包括以下两个步骤（a）和（b）：（a）处理甲苯胺异构体混合物或不需要的甲苯胺异构体或一种不需要的甲苯胺异构体，其中异构化催化剂选自pentasil类型的合成沸石，（b）从所形成的异构体混合物中分离出所需异构体或其中一种异构体步骤（a）通过选择性吸附到中孔或大孔沸石并随后解吸，此外排出分离的异构体并将剩余的异构体混合物再循环到步骤（a）。

46. 发明授权

US4429155A Preparation of aromatic amines 失效
标题翻译：芳香胺的制备
公开(公告)号：US4429155A
公开(公告)日：1984-01-31
申请号：US326419
申请日：1981-12-01
申请人： Norbert Goetz , Peter Jacobs , Leopold Hupfer , Herbert Toussaint , Wolfgang Reiss
发明人： Norbert Goetz , Peter Jacobs , Leopold Hupfer , Herbert Toussaint , Wolfgang Reiss
IPC分类号： C07B61/00 , B01J21/00 , B01J23/00 , B01J23/44 , B01J23/56 , B01J23/58 , B01J23/63 , B01J23/89 , B01J27/00 , B01J29/00 , C07C67/00 , C07C209/00 , C07C209/16 , C07C209/18 , C07C209/26 , C07C209/68 , C07C209/72 , C07C211/16 , C07C211/46 , C07C211/47 , C07C213/02 , C07C85/00 , C07C85/06 , C07C85/24
CPC分类号： C07C209/18 , C07C209/72 , B01J21/005 , B01J23/005 , B01J23/44 , B01J23/58 , B01J23/63 , B01J23/89
摘要： Aromatic amines (anilines) are obtained directly or via the corresponding cycloaliphatic amines by an aminating/hydrogenating reaction of phenols with ammonia and hydrogen over a supported palladium catalyst which also contains elements from group 1b, 2b or 7b of the periodic table as well as iron, cobalt or nickel, as such or in the form of their compounds, and, preferably, an inorganic base, said catalysts also having dehydrogenating properties.
摘要翻译：芳族胺（苯胺）直接或通过相应的脂环族胺通过苯酚与氨和氢的氨化/氢化反应在负载的钯催化剂上得到，其还含有元素周期表第1b，2b或7b族元素以及铁，钴或镍，或其化合物的形式，优选无机碱，所述催化剂也具有脱氢性能。

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