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41. 发明授权

US09199909B2 Hydroconversion of renewable feedstocks 有权
标题翻译：可再生原料的加氢转化
公开(公告)号：US09199909B2
公开(公告)日：2015-12-01
申请号：US13315729
申请日：2011-12-09
申请人： Cong-Yan Chen
发明人： Cong-Yan Chen
IPC分类号： C07C1/00 , C07C67/00 , C10G3/00 , C07C29/17 , C07C27/04
CPC分类号： C07C67/00 , C07C27/04 , C07C29/177 , C10G3/46 , C10G3/50 , C10G2300/1014 , Y02P30/20 , C07C69/26 , C07C31/125
摘要： A hydrocarbon conversion process comprises contacting a renewable feedstock under hydroprocessing conditions with supported catalyst comprising at least one metal selected from the group consisting of Group VIII metals, Group VIB metals to form oleochemicals such as fatty alcohols, esters, and normal paraffins. Advantageously, the reaction conditions can be selected to directly convert the renewable feedstock to the desired product(s).
摘要翻译：烃转化方法包括在加氢处理条件下使可再生原料与包含至少一种选自第Ⅷ族金属，第ⅥB族金属的金属的载体催化剂接触，以形成油化学物质如脂肪醇，酯和正链烷烃。有利地，可以选择反应条件以将可再生原料直接转化为所需的产物。

42. 发明授权

US09163221B2 Fatty alcohol forming acyl reductases (FARs) and methods of use thereof 有权
标题翻译：形成脂肪醇的酰基还原酶（FARs）及其使用方法
公开(公告)号：US09163221B2
公开(公告)日：2015-10-20
申请号：US14040550
申请日：2013-09-27
申请人： Codexis, Inc.
发明人： Behnaz Behrouzian , Louis Clark , Yihui Zhu , Michael Clay , Kristian Karlshoej
IPC分类号： C12P7/04 , C12N1/20 , C12N1/00 , C11D3/00 , C07H21/02 , C07C51/00 , C07C35/04 , C07C1/00 , C07K1/00 , C12N9/02 , C07C1/22 , C10G3/00 , C11D3/20 , C12N9/04
CPC分类号： C12N9/0008 , C07C1/22 , C07K2319/00 , C07K2319/036 , C10G3/00 , C10G3/40 , C10G2300/1011 , C10G2400/04 , C11D3/2003 , C11D3/2013 , C11D3/2031 , C12N9/0006 , C12P7/04 , Y02P30/20
摘要： The present disclosure provides methods useful for producing fatty alcohol compositions from recombinant host cells. The disclosure further provides variant fatty acyl-CoA reductase (FAR) enzymes, polynucleotides encoding the variant FAR enzymes, and vectors and host cells comprising the same.
摘要翻译：本公开内容提供了用于从重组宿主细胞产生脂肪醇组合物的方法。本公开进一步提供变体脂肪酰基-CoA还原酶（FAR）酶，编码变体FAR酶的多核苷酸，以及载体和包含其的宿主细胞。

43. 发明授权

US09102879B2 Process to produce biofuels from biomass 有权
标题翻译：从生物质生产生物燃料的过程
公开(公告)号：US09102879B2
公开(公告)日：2015-08-11
申请号：US13331065
申请日：2011-12-20
申请人： Joseph Broun Powell , Juben Nemchand Chheda
发明人： Joseph Broun Powell , Juben Nemchand Chheda
IPC分类号： C07C1/00 , C10G3/00 , C10L1/04
CPC分类号： C10G3/00 , C10G3/42 , C10G2300/1014 , C10G2300/202 , C10G2300/4081 , C10G2300/44 , C10L1/04 , Y02P30/20
摘要： Biomass is contacted with an aqueous media to form an extracted biomass. An aqueous liquor separated from the extracted biomass is treated with a purification substrate to form a treated carbohydrate stream having less than 35% of the sulfur content and less than 35% of the nitrogen content, based on the untreated aqueous liquor stream, prior to contact with an aqueous phase reforming catalyst to form oxygenated intermediates that can be further processed to form a liquid fuel. An extracted biomass solids stream is also separated from the extracted biomass which is contacted with a first digestive solvent and then a second digestive solvent to form a solubilized pulp. This solublilized pulp may be combined with the aqueous liquor stream or combined to an aqueous reforming reaction system or recycled to the aqueous media to be processed further for an effective process to produce the liquid fuel.
摘要翻译：生物质与水性介质接触以形成提取的生物质。用提取的生物质分离的含水液体用净化底物处理，以在接触之前基于未处理的含水液体流形成具有少于35％的硫含量和小于氮含量的35％的经处理的碳水化合物流与水相重整催化剂形成氧化中间体，其可进一步加工以形成液体燃料。提取的生物质固体物流也与提取的生物质分离，其与第一消化溶剂接触，然后与第二消化溶剂接触以形成溶解的纸浆。这种溶解的纸浆可以与含水液体流合并或与水性重整反应体系结合或再循环到水性介质中以进一步进行处理以产生液体燃料。

44. 发明授权

US09035117B2 Continuous process for conversion of lignin to useful compounds 有权
公开(公告)号：US09035117B2
公开(公告)日：2015-05-19
申请号：US13775238
申请日：2013-02-24
申请人： Chemtex Italia S.p.A.
发明人： Steven Ryba , Aaron Murray , Guliz Arf Elliott , Dan Gastaldo
IPC分类号： C07C1/00 , C07C37/01 , C01B31/20 , C07C37/54 , C07C45/42 , C07C41/01 , C07C1/20 , C07C67/00 , C07C29/09 , C08L97/00 , B01D21/00 , C07B31/00 , C07C45/59 , C07C45/60 , C07C29/00 , C08H8/00
CPC分类号： C07C37/54 , B01D21/00 , C07B31/00 , C07C1/20 , C07C29/00 , C07C29/09 , C07C41/01 , C07C45/42 , C07C45/59 , C07C45/60 , C07C67/00 , C07C2101/08 , C07C2101/10 , C07C2101/14 , C07C2601/08 , C07C2601/10 , C07C2601/14 , C08H8/00 , C08L97/005 , F15D1/00 , Y02P30/42 , Y10T137/0318 , C07C43/23 , C07C39/06 , C07C39/04 , C07C49/84 , C07C49/395 , C07C49/597 , C07C49/403 , C07C49/825 , C07C69/06 , C07C35/08
摘要： This specification discloses an operational continuous process to convert lignin as found in ligno-cellulosic biomass before or after converting at least some of the carbohydrates. The continuous process has been demonstrated to create a slurry comprised of lignin, raise the slurry comprised of lignin to ultra-high pressure, deoxygenate the lignin in a lignin conversion reactor over a catalyst which is not a fixed bed without producing char. The conversion products of the carbohydrates or lignin can be further processed into polyester intermediates for use in polyester preforms and bottles.

45. 发明授权

US09035115B2 Hydroconversion of renewable feedstocks 有权
标题翻译：可再生原料的加氢转化
公开(公告)号：US09035115B2
公开(公告)日：2015-05-19
申请号：US13315650
申请日：2011-12-09
申请人： Cong-Yan Chen , Alexander E. Kuperman , William J. Cannella
发明人： Cong-Yan Chen , Alexander E. Kuperman , William J. Cannella
IPC分类号： C07C1/00 , C10G45/62 , C10G45/60 , C10G3/00 , B01J37/20 , B01J23/888
CPC分类号： C10G45/62 , B01J23/8885 , B01J37/20 , C10G3/42 , C10G3/46 , C10G3/50 , C10G45/60 , C10G2300/1014 , C10G2300/1055 , C10G2300/1088 , Y02E50/14 , Y02P30/20
摘要： A hydrocarbon conversion process comprises contacting a renewable feedstock under hydroprocessing conditions with a bulk catalyst to form oleochemicals such as fatty alcohols, esters, and normal paraffins. Advantageously, the reaction conditions can be selected to directly convert the renewable feedstock to the desired product(s).
摘要翻译：烃转化方法包括在加氢处理条件下将可再生原料与本体催化剂接触以形成油脂化学物质，例如脂肪醇，酯和正链烷烃。有利地，可以选择反应条件以将可再生原料直接转化为所需的产物。

46. 发明授权

US09006501B2 Low pour point renewable fuel blend 有权
标题翻译：低倾点可再生燃料混合物
公开(公告)号：US09006501B2
公开(公告)日：2015-04-14
申请号：US13100832
申请日：2011-05-04
申请人： Rebecca Brafman , Stephen Roby , Guangci Zhou
发明人： Rebecca Brafman , Stephen Roby , Guangci Zhou
IPC分类号： C10L1/04 , C07C1/00 , C10G45/00 , C10G3/00
CPC分类号： C10L1/04 , C10G3/50 , C10G45/00 , C10G2300/1011 , C10G2300/1048 , C10G2300/301 , C10G2300/304 , Y02P30/20
摘要： A renewable fuel blend and a process for producing a renewable fuel blend are described. The blend includes biologically derived C13 to C18 normal paraffins, which are provided to the blend in quantities such that blend does not require a pour point reducing treatment to achieve a low pour point. In embodiments, the normal paraffins are produced in an upgrading process, such as a hydrotreating process.
摘要翻译：描述了可再生燃料混合物和用于生产可再生燃料共混物的方法。共混物包括生物衍生的C13至C18正链烷烃，其以量的量提供给共混物，使得共混物不需要倾点降低处理以实现低倾点。在实施方案中，正常链烷烃在升级过程中产生，例如加氢处理方法。

47. 发明授权

US08946494B2 Method for processing biomass 有权
标题翻译：生物质处理方法
公开(公告)号：US08946494B2
公开(公告)日：2015-02-03
申请号：US13224533
申请日：2011-09-02
申请人： Thomas Henry Vanderspurt , Timothy D. Davis , Sean C. Emerson , Ying She , Rhonda R. Willigan , Salvatore Saitta , Tianli Zhu
发明人： Thomas Henry Vanderspurt , Timothy D. Davis , Sean C. Emerson , Ying She , Rhonda R. Willigan , Salvatore Saitta , Tianli Zhu
IPC分类号： C07C1/00 , C10L1/02
CPC分类号： C10L1/026 , C07C2601/14 , C10G2300/1014 , C10G2300/42 , Y02E50/13 , Y02P30/20
摘要： A method for processing biomass to produce biofuel includes decomposing lignocellulosic material into byproduct polymers that include lignin, decomposing the lignin into targeted chemical fragments, and chemically converting the targeted chemical fragments into a biofuel.
摘要翻译：用于处理生物质以生产生物燃料的方法包括将木质纤维素材料分解成副产物聚合物，其包括木质素，将木质素分解成目标化学碎片，并将目标化学碎片化学转化成生物燃料。

48. 发明授权

US08927793B2 Processes for converting lignocellulosics to reduced acid pyrolysis oil 有权
标题翻译：将木质纤维素转化为酸性热解油的方法
公开(公告)号：US08927793B2
公开(公告)日：2015-01-06
申请号：US13194718
申请日：2011-07-29
申请人： Joseph Anthony Kocal , Timothy A. Brandvold
发明人： Joseph Anthony Kocal , Timothy A. Brandvold
IPC分类号： C07C1/00 , C10K1/00 , C10K1/34 , C10K3/02 , C10B49/22 , C10B53/02 , C10B57/06 , C10B57/18 , C10C5/00 , B01J23/00 , B01J23/02 , B01J29/08
CPC分类号： C10K1/00 , B01J23/007 , B01J23/02 , B01J29/082 , C10B49/22 , C10B53/02 , C10B57/06 , C10B57/18 , C10C5/00 , C10G2300/1014 , C10K1/34 , C10K3/026 , Y02E50/14 , Y02P30/20
摘要： Processes for producing reduced acid lignocellulosic-derived pyrolysis oil are provided. In a process, lignocellulosic material is fed to a heating zone. A basic solid catalyst is delivered to the heating zone. The lignocellulosic material is pyrolyzed in the presence of the basic solid catalyst in the heating zone to create pyrolysis gases. The oxygen in the pyrolysis gases is catalytically converted to separable species in the heating zone. The pyrolysis gases are removed from the heating zone and are liquefied to form the reduced acid lignocellulosic-derived pyrolysis oil.
摘要翻译：提供了生产降低的酸性木素纤维素衍生的裂解油的方法。在一个过程中，将木质纤维素材料送入加热区。碱性固体催化剂被输送到加热区。木质纤维素材料在碱性固体催化剂存在下在加热区中热解，以产生热解气体。热解气体中的氧气在加热区域被催化转化为可分离的物质。热解气体从加热区被去除，并被液化以形成还原酸木质纤维素衍生的裂解油。

49. 发明授权

US08894939B2 Three phase reactor 有权
标题翻译：三相反应器
公开(公告)号：US08894939B2
公开(公告)日：2014-11-25
申请号：US13211078
申请日：2011-08-16
申请人： Rafael Espinoza , Kenneth L. Agee
发明人： Rafael Espinoza , Kenneth L. Agee
IPC分类号： B01J8/18 , B01J8/22 , B01J8/00 , B01J19/00 , B01J19/24 , C10L3/00 , C10L3/06 , C10L3/08 , C10L3/10 , C10G2/00 , C07C1/00 , C07C1/02 , C07C1/04
CPC分类号： B01J8/1827 , B01J8/006 , B01J8/1836 , B01J8/226 , B01J2208/00141 , B01J2208/003 , B01J2208/0084 , B01J2208/00902 , B01J2219/182 , C10G2/342
摘要： A reactor for carrying out a chemical reaction in a three phase slurry system providing a horizontal reaction vessel with a cross sectional area which is dependent on the vessel length, vessel diameter, and axial position. The vessel has a gas inlet at or near the bottom of the reaction vessel and a gas distributor. The gas product exits the vessel by conduit means at or near the top of the reaction vessel. The vessel includes a plurality of horizontal cooling coils to provide a cooling medium to the slurry. In the reaction vessel, the synthesis gas has an average linear velocity which is a function of the vessel cross sectional area.
摘要翻译：一种用于在三相浆料系统中进行化学反应的反应器，其提供具有取决于容器长度，容器直径和轴向位置的横截面积的水平反应容器。容器在反应容器底部或附近具有气体入口和气体分配器。气体产物通过在反应容器顶部或附近的导管装置离开容器。容器包括多个水平冷却盘管，以向浆料提供冷却介质。在反应容器中，合成气具有作为血管横截面积的函数的平均线速度。

50. 发明授权

US08884090B2 Process for the preparation of an olefin 有权
标题翻译：制备烯烃的方法
公开(公告)号：US08884090B2
公开(公告)日：2014-11-11
申请号：US12743276
申请日：2008-11-19
申请人： Jeroen Van Westrenen , Leslie Andrew Chewter , Ferry Winter
发明人： Jeroen Van Westrenen , Leslie Andrew Chewter , Ferry Winter
IPC分类号： C07C1/20 , C07C1/24 , C07C1/00 , B01J8/04 , B01J8/26 , C07C11/02
CPC分类号： B01J8/0457 , B01J8/26 , C07C1/20 , C07C11/02 , C07C2529/40 , C07C2529/85 , C07C2529/89 , Y02P30/42
摘要： An olefin is prepared from an alkyl alcohol in a process which comprises the steps: a) converting the alkyl alcohol into a dialkylether over a first catalyst, to yield a hot dialkylether product stream containing alkyl alcohol, dialkylether and water; b) cooling the hot dialkylether product stream at least partly by indirect heat exchange with a cold dialkylether product stream to below the dew point of water at the prevailing conditions to obtain a gas-liquid mixture; c) separating the obtained mixture into a liquid water-containing stream and a vaporous dialkylether-rich stream; d) subjecting at least part of the vaporous dialkylether-rich stream, as the cold dialkylether product stream in step b), to heat exchange with the hot dialkylether product stream, to yield a heated dialkylether-rich feed; and e) converting the heated dialkylether-rich feed to an olefin over a second catalyst.
摘要翻译：烯烃由烷基醇制备，该方法包括以下步骤：a）通过第一催化剂将烷基醇转化为二烷基醚，得到含有烷基醇，二烷基醚和水的热二烷基醚产物流; b）至少部分地通过与冷二烷基醚产物流的间接热交换在主要条件下将热二烷基醚产物流冷却至低于水的露点以获得气液混合物; c）将得到的混合物分离成含液体的水和富含二烷基醚的富含气体的物流; d）使至少部分富含二烷基醚的蒸汽气流作为步骤b）中的冷二烷基醚产物流与热二烷基醚产物流进行热交换，得到加热的富含二烷基醚的进料; 和e）通过第二催化剂将加热的富含二烷基醚的进料转化成烯烃。

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