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    • 49. 发明授权
    • Impact-resistant composition based on thermoplastic methacrylic (co)polymer
    • 基于热塑性甲基丙烯酸(共)聚合物的抗冲击组合物
    • US06939917B2
    • 2005-09-06
    • US10182671
    • 2001-01-26
    • Patrice GaillardPhilippe HeimGilles MeunierBruno Vuillemin
    • Patrice GaillardPhilippe HeimGilles MeunierBruno Vuillemin
    • C08J5/00B29B7/38B29K33/04C08F291/00C08L33/12C08F8/00C08L9/00C08L25/02C08L33/06C08L35/02
    • C08L33/12C08L2666/24
    • The impact-resistant thermoplastic compositions comprising (A) a rigid thermoplastic methacrylic polymer or copolymer matrix P containing mostly methyl methacrylate units, (B) at least one impact-modifying additive and (C) at least one elastomer copolymer which contains grafting sites, at least on pendant chains, and is obtained from at least one vinylaromatic monomer (C1) and from at one monomer chosen from the monomers (C2): C1-C15 linear or branched alkyl acrylates, C1-C4 alkoxyalkyl acrylates and aralkyl acrylates, dienes (C3) and ethylenically unsaturated monomers (C4) having one or more pendant initiating functional groups, the said copolymer (C) being grafted by thermoplastic polymer groups P and being dispersed in the matrix (A) in the form of nodules, which can be called “particles”, from 10 nm to 500 nm in size and able to have a droplet, capsule-type monoinclusion and/or salami-type multi-inclusion morphology.
    • 耐冲击热塑性组合物包含(A)主要含有甲基丙烯酸甲酯单元的刚性热塑性甲基丙烯酸聚合物或共聚物基体P,(B)至少一种冲击改性添加剂和(C)含有接枝位点的至少一种弹性体共聚物, 至少在侧链上,并且由至少一种乙烯基芳族单体(C 1 H 1)和从一种选自单体(C 2 H 2)的单体获得: 丙烯酸C 1 -C 4烷基烷基酯和丙烯酸芳烷基酯,二烯(C 1 -C 6烷基) (C 3)和具有一个或多个起始起始官能团的烯属不饱和单体(C 4 S),所述共聚物(C)由热塑性聚合物基团P接枝并分散在 可以称为“颗粒”的结节形式的矩阵(A),其尺寸为10nm至500nm,并且能够具有液滴,胶囊型单一包封和/或萨拉米字型多重 - 纳入形态。