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    • 41. 发明申请
    • PROCESS FOR THE PRODUCTION OF EXPANDED POLYESTER FOAM BEADS
    • 生产膨胀聚酯泡沫珠的方法
    • US20160244583A1
    • 2016-08-25
    • US15027803
    • 2014-09-29
    • BASF SE
    • Uwe KEPPELER
    • C08J9/18C08J9/12C08J9/00C08J9/14
    • C08J9/18B29C44/3453B29C44/3461C08J9/0061C08J9/0066C08J9/122C08J9/141C08J9/228C08J9/232C08J9/236C08J2201/034C08J2203/06C08J2203/14C08J2203/182C08J2205/052C08J2300/16C08J2367/02C08J2467/04
    • A process for the production of expanded foam beads that are prepared from pellets comprising polyester mixture comprising a) from 50 to 99% by weight, based on components a and b, of a biodegradable polyester based on aliphatic, or a mixture of aliphatic and aromatic,dicarboxylic acids and an aliphatic diol, and b) from 1 to 50% by weight, based on components a and b, of polylactic acid, the process comprising the following steps: (i) providing an aqueous suspension of the polyester pellets, (ii) impregnating the pellets in the suspension of step (i) with at least one physical or chemical blowing agent to provide blowing-agent-loaded pellets in suspension, wherein the impregnation of the at least one blowing agent includes heating the mixture to a depressurization temperature IMT with stirring, and (iii) depressurizing the suspension obtained in step (ii) to provide the expanded foam beads. The at least one blowing agent is added to the suspension in step (i), or in step (ii) during the heating phase, or immediately after the heating phase, and following the heating of step (ii), the suspension is maintained at a temperature in the range from IMT minus 5° C. to IMT plus 2° C. for a period of 3 to 100 minutes. The invention further relates to expanded foam beads obtained by the process, and to the production of moldings from the expanded foam beads.
    • 一种用于生产由包含聚酯混合物的颗粒制成的膨胀泡沫珠粒的方法,其包含a)基于脂肪族的可生物降解的聚酯的基于组分a和b的50至99重量%,或脂族和芳族的混合物 ,二羧酸和脂族二醇,和b)基于聚乳酸的组分a和b的1-50重量%,所述方法包括以下步骤:(i)提供聚酯颗粒的水悬浮液, ii)用至少一种物理或化学发泡剂将步骤(i)的悬浮液中的颗粒浸渍到悬浮液中以提供负载泡沫剂的颗粒,其中至少一种发泡剂的浸渍包括将混合物加热至减压 温度IMT,和(iii)将步骤(ii)中获得的悬浮液减压以提供发泡泡珠。 在加热阶段或加热阶段之后,将至少一种发泡剂加入到步骤(i)或步骤(ii)中的悬浮液中,或在加热步骤(ii)之后,将悬浮液保持在 在IMT减5℃至IMT加2℃范围内的温度,持续3至100分钟。 本发明还涉及通过该方法获得的膨胀泡沫珠粒和从膨胀的泡沫珠粒制备模制品。