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    • 42. 发明授权
    • Cross-linked polymers based on bis-silane, bis-thioether, bis-sulphoxide, bis-sulphone and butane-di-yl derivatives of polysaccharides and oligosaccharides, and their shaping as support materials
    • 基于双硅烷,双硫醚,双亚砜,双糖和双糖的双砜和丁烷二基衍生物的交联聚合物及其成型作为载体材料
    • US07825240B2
    • 2010-11-02
    • US10694844
    • 2003-10-29
    • Raphaël Duval
    • Raphaël Duval
    • C08B37/00C07H5/04
    • C08B15/10C07B57/00C08B15/005
    • There are described novel cross-linked polymers based on bis-silane, bis-thioether, bis-sulphoxide, bis-sulphone and butane-di-yl derivatives of polysaccharides and oligosaccharides, their shaping as support materials useful for the separation or preparation of enantiomers; a process for preparing the said cross-linked polymer compounds, a process for preparing balls of support materials containing the said cross-linked polymer compounds; a method of obtaining balls of support materials useful in chromatography or in organic synthesis; and the use of the said support materials containing the cross-linked polymer compounds in separation or in preparation of enantiomers, through employment in chromatography or organic synthesis processes in a heterogeneous medium; and the use of the said cross-linked polymer compounds in the form of membranes in processes using percolation through membranes for the separation or the preparation of enantiomers.
    • 描述了基于双硅烷,双硫醚,双亚砜,双糖和双糖的双砜和丁烷二基衍生物的多糖和寡糖的新型交联聚合物,它们的成型作为用于分离或制备对映异构体的载体材料 ; 制备所述交联聚合物化合物的方法,制备包含所述交联聚合物化合物的载体材料球的方法; 获得可用于色谱法或有机合成的载体材料球的方法; 以及通过在异质介质中的色谱法或有机合成过程中使用分离或制备对映异构体的含有交联聚合物化合物的所述载体材料; 以及在使用膜渗透以分离或制备对映异构体的方法中使用所述膜形式的交联聚合物化合物。
    • 46. 发明授权
    • Chemically cross-linked cellulose fiber and method of making same
    • 化学交联的纤维素纤维及其制备方法
    • US07074301B2
    • 2006-07-11
    • US10166254
    • 2002-06-11
    • Othman A. HamedHarry J. ChmielewskiDana B. McBee
    • Othman A. HamedHarry J. ChmielewskiDana B. McBee
    • D21H11/20D21H17/47D21H21/22D06M15/39
    • D21C9/002A61F13/15203A61F13/53C08B15/10C08H8/00D06M13/12D06M13/207D06M2101/06
    • The present invention relates to cross-linked cellulosic fiber having improved absorbency characteristics when compared to conventional cross-linked fibers. The cross-linked cellulosic fiber is obtainable by reacting pulp in the sheet or fluff form with one or more reagents selected from organic molecule having acid and aldehyde functional groups “acid aldehydes.” The invention also relates to a method of producing the cross-linked fiber. The method includes heating the treated cellulosic fibers to promote intrafiber cross-linking. The cross-linked fibers are characterized by having an improved centrifuge retention capacity, fluid acquisition rate, resiliency, absorbent capacity, absorbency under load, and other absorbent properties. The inventive cross-linked fibers are useful in forming absorbent composites, and in particular absorbent cores for use in absorbent articles.
    • 本发明涉及与常规交联纤维相比具有改善的吸收性能的交联纤维素纤维。 交联的纤维素纤维可通过将纸浆或绒毛形式的纸浆与一种或多种选自具有酸和醛官能团“酸醛”的有机分子的试剂反应而获得。 本发明还涉及交联纤维的制造方法。 该方法包括加热经处理的纤维素纤维以促进纤维内交联。 交联纤维的特征在于具有改进的离心机保留能力,流体获取速率,弹性,吸收能力,负载下的吸收性能和其它吸收性能。 本发明的交联纤维可用于形成吸收性复合材料,特别是用于吸收制品的吸收芯。
    • 50. 发明授权
    • Polyanhydride crosslinked fibrous cellulosic products and process for
their preparation
    • 聚酐交联纤维素纤维制品及其制备方法
    • US5981739A
    • 1999-11-09
    • US926911
    • 1997-09-10
    • Ronald L. AndersonWendell W. CattronVincent F. Smith, Jr.David J. Fenoglio
    • Ronald L. AndersonWendell W. CattronVincent F. Smith, Jr.David J. Fenoglio
    • C08B15/10C08H8/00D06M13/17D06M13/184D06M13/224D06M15/53D21C9/00C07C63/307C08B3/00
    • C08H8/00C08B15/10D06M13/17D06M13/1845D06M13/224D06M15/53D21C9/005D06M2101/06
    • A process for preparation of crosslinked cellulosic products containing at least 30 wt. % cellulosic fibers and the polyanhydride crosslinked cellulosic products resulting therefrom wherein a cellulosic material is treated with an aqueous solution of a polycarboxylic acid formed by hydrolysis of a polyanhydride of the structure ##STR1## which comprises the reaction product of trimellitic anhydride and a diol in the mole ratio of from about 2.0:0.9 to about 2.0:1.1, wherein R is selected from the group consisting of alkyl, alkylene and cycloalkylene moieties of up to 12 carbon atoms and ethylene oxide and propylene oxide moieties of molecular weight up to about 6000, wherein said cellulosic material is impregnated with an aqueous solution of said polyanhydride, dried, and heated to a temperature of from about 120.degree. C. to about 200.degree. C. at ambient pressure to obtain crosslinking of the cellulose fibers with the said polyanhydride by an ester bond between the hydroxyl groups of the cellulosic fibers and the anhydride groups of the anhydride. Fibrous cellulosic products are readily repulped paper with improved wet strength, pulp fluff with improved wet resilience, wood oriented strand board with improved moisture resistance, and textile products with improved durable press and reduced shrink characteristics.
    • 一种制备交联纤维素产品的方法,其包含至少30wt。 %的纤维素纤维和由此产生的聚酐交联的纤维素产品,其中纤维素材料用多元羧酸的水溶液处理,所述多元羧酸的水溶液是通过水解结构的聚酐形成的,该聚酐包含偏苯三酸酐和二醇的反应产物的摩尔比 约2.0:0.9至约2.0:1.1,其中R选自具有至多12个碳原子的烷基,亚烷基和亚环烷基部分以及分子量高达约6000的环氧乙烷和环氧丙烷部分,其中所述纤维素 材料用所述聚酐的水溶液浸渍,干燥并在环境压力下加热至约120℃至约200℃的温度,以使纤维素纤维与所述聚酐通过酯键之间的酯键进行交联 纤维素纤维的羟基和酸酐的酸酐基团。 纤维素纤维素产品易于重新制备具有改进的湿强度的纸浆,具有改善的湿回弹性的纸浆绒毛,具有改善的耐湿性的木材定向刨花板以及具有改进的耐久压制和降低的收缩特性的纺织产品。