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41. 发明授权

US08334394B2 Solid phase reaction system for oxidation 有权
标题翻译：用于氧化的固相反应体系
公开(公告)号：US08334394B2
公开(公告)日：2012-12-18
申请号：US12524667
申请日：2008-01-30
申请人： Jyunko Ichihara , Syunrou Yamaguchi
发明人： Jyunko Ichihara , Syunrou Yamaguchi
IPC分类号： C07D303/00 , C07D301/02
CPC分类号： C07C45/294 , B01J23/007 , B01J23/28 , B01J23/30 , B01J27/1806 , B01J27/188 , B01J37/04 , C07B33/00 , C07C291/04 , C07C315/02 , C07D213/89 , C07D301/12 , C07D303/02 , C07D303/04 , C07D303/14 , C07C47/54 , C07C49/78 , C07C317/14
摘要： A solid phase reaction system for oxidation of an organic compound,having high industrial value in which an organic solvent exerting a reverse influence on earth environments is not necessary, reuse of a catalyst is possible, and high yield can be attained,comprising a mixture of a powdery dispersion medium and a powder of a solid catalyst for the above-described oxidation reaction, and the above-described organic compound and aqueous hydrogen peroxide, wherein the above-described organic compound, the above-described solid catalyst and the above-described aqueous hydrogen peroxide are dispersed in the above-described mixture so that they get into contact mutually.
摘要翻译：用于氧化有机化合物的固相反应体系，具有高的工业价值，其中对地球环境产生反向影响的有机溶剂是不必要的，催化剂的再利用是可能的，并且可以获得高产率，包括粉末分散介质和用于上述氧化反应的固体催化剂粉末，以及上述有机化合物和过氧化氢水溶液，其中上述有机化合物，上述固体催化剂和上述过氧化氢水分散在上述混合物中，使它们相互接触。

42. 发明申请

US20080221343A1 Novel hydrazone-based and oxime-based fluorescent and chromophoric/pro-fluorescent and pro-chromophoric reagents and linkers 有权
标题翻译：新型腙基和肟基荧光和发色/前荧光和原发色体试剂和接头
公开(公告)号：US20080221343A1
公开(公告)日：2008-09-11
申请号：US11787932
申请日：2007-04-18
申请人： David A. Schwartz , Leopoldo Mendoza
发明人： David A. Schwartz , Leopoldo Mendoza
IPC分类号： C07D303/02 , C07C241/00
CPC分类号： G01N33/582 , C07D303/02
摘要： Conjugationally extended hydrazine compositions of the formula (RR2)N(H)n(NH2)n, fluorescent hydrazone compositions of the formula (RR2)NN═C(R1R2), methods of the formation of hydrazones from the reaction of conjugationally extended hydrazines with conjugationally extended carbonyls and methods of their use in assays systems are described. Use of these conjugationally extended hydrazine and oxime compositions for direct calorimetric and fluorometric assays wherein a chromophore or the fluorophore is incorporated into the linker that is positioned between a reactive linking moiety and a biotin molecule. More specifically the linker comprises one molecule of a high affinity binding pair such as for example biotin of the biotin/avidin high affinity binding pair, connected to a spacer molecule such as for example a length of polyethyleneglycol followed by a pro-chromophoric, chromophoric, pro-fluorescent or fluorescent moiety connected to an amino-, thiol- or carbohydrate-reactive moiety such as for example succinimidyl, maleimido or aminoxy group respectively, that may covalently link to a biomolecule.
摘要翻译：式（R 2 N）N（H）n（NH 2）n）的共轭延伸的肼组合物，式（RR 2 N）NN-C（R 1 R 2 R 2）的荧光腙组合物，由反应形成腙的方法描述了具有共轭延伸的羰基的共轭延伸的肼及其在测定系统中的用途。使用这些共轭延伸的肼和肟组合物用于直接量热和荧光测定，其中发色团或荧光团被引入位于反应性连接部分和生物素分子之间的连接体中。更具体地，接头包含一个高亲和力结合对分子，例如生物素/抗生物素蛋白高亲和力结合对的生物素，连接到间隔分子，例如长度的聚乙二醇，随后是发色团，发色团，分别连接到可以共价连接到生物分子的氨基，硫醇或碳水化合物反应性部分的前荧光或荧光部分，例如琥珀酰亚胺基，马来酰亚胺基或氨氧基。

43. 发明申请

US20040180933A1 Process for preparing 1,2-diamino compounds 有权
标题翻译： 1,2-二氨基化合物的制备方法
公开(公告)号：US20040180933A1
公开(公告)日：2004-09-16
申请号：US10388064
申请日：2003-03-13
发明人： Jack D. Brown , Peter J. Harrington , Robert C. Hughes
IPC分类号： A61K031/454 , C07D43/02
CPC分类号： C07D303/02 , C07C233/52 , C07C2601/16 , C07D203/26
摘要： The invention provides a multi-step process for preparing 1,2-diamino compounds of formula 1 wherein R1, R1null, R2, R2null, R3 and R4 have the meaning given in the specification and pharmaceutically acceptable addition salts thereof, from 1,2-epoxides of formula 2 wherein R1, R1null, R2 and R2null have the meaning given in the specification.
摘要翻译：本发明提供了制备下式的1,2-二氨基化合物的多步法：其中R 1，R 1，R 2，R 2，R 3和R 4，具有本说明书中给出的含义及其药学上可接受的加成盐，由下式的1,2-环氧化物其中R 1，R 1，R 2和R 2'具有在规范。

44. 发明授权

US5097047A Fungicidal and plant growth-regulating azolylmethyl-cyclopropyl derivatives 失效
标题翻译：杀菌剂和植物生长调节性氨基甲基环丙基衍生物
公开(公告)号：US5097047A
公开(公告)日：1992-03-17
申请号：US604559
申请日：1990-10-26
申请人： Klaus Stroech , Wilhelm Brandes , Stefan Dutzmann
发明人： Klaus Stroech , Wilhelm Brandes , Stefan Dutzmann
IPC分类号： C07C43/196 , A01N31/04 , A01N31/08 , A01N41/10 , A01N43/50 , A01N43/653 , C07C27/00 , C07C29/40 , C07C33/34 , C07C33/50 , C07C41/00 , C07C41/30 , C07C43/23 , C07C43/295 , C07C67/00 , C07C313/00 , C07C317/14 , C07C317/20 , C07C323/17 , C07C323/19 , C07C323/64 , C07C323/65 , C07D20060101 , C07D233/60 , C07D249/08 , C07D303/02 , C07D303/08 , C07D303/22 , C07D303/34 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07C33/50 , C07D233/56 , C07D249/08 , C07D303/02
摘要： Fungicidal and plant growth-regulating azolylmethylcyclopropyl derivatives of the formula ##STR1## in which R represents halogen, alkyl or optionally substituted phenyl, or represents the groupings --Y--R.sup.2,whereinY represents oxygen, sulphur, SO or SO.sub.2 andR.sup.2 represents optionally substituted phenyl,R.sup.1 represents hydrogen, alkyl or acyl,X represents nitrogen or a CH group,Z represents halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, halogenoalkyl with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio with 1 or 2 carbon atoms and 1 to 5 halogen atoms or phenyl which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen, or represents phenoxy which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen andm represents the number 0, 1, 2 or 3, and addition products thereof with acids and metal salts. Intermediates therefor of the formulas ##STR2## are also new.

45. 发明授权

US4990677A Fungicidal and plant growth-regulating azolylmethyl-cyclopropyl derivatives 失效
公开(公告)号：US4990677A
公开(公告)日：1991-02-05
申请号：US479143
申请日：1990-02-12
申请人： Klaus Stroech , Wilhelm Brandes , Stefan Dutzmann
发明人： Klaus Stroech , Wilhelm Brandes , Stefan Dutzmann
IPC分类号： C07C43/196 , A01N31/04 , A01N31/08 , A01N41/10 , A01N43/50 , A01N43/653 , C07C27/00 , C07C29/40 , C07C33/34 , C07C33/50 , C07C41/00 , C07C41/30 , C07C43/23 , C07C43/295 , C07C67/00 , C07C313/00 , C07C317/14 , C07C317/20 , C07C323/17 , C07C323/19 , C07C323/64 , C07C323/65 , C07D20060101 , C07D233/60 , C07D249/08 , C07D303/02 , C07D303/08 , C07D303/22 , C07D303/34 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07C33/50 , C07D233/56 , C07D249/08 , C07D303/02
摘要： Fungicidal and plant growth-regulating azolylmethylcyclopropyl derivatives of the formula ##STR1## in which R represents halogen, alkyl or optionally substituted phenyhl, or represents the groupings --Y--R.sup.2,whereinY represents oxygen, sulphur, SO or SO.sub.2 andR.sup.2 represents optionally substituted phenyl,R.sup.1 represents hydrogen, alkyl or acyl,X represents nitrogen or a CH group,Z represents halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, halogenoalkyl with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio with 1 or 2 carbon atoms and 1 to 5 halogen atoms or phenyl which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen, or represents phenoxy which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen andm represents the number 0, 1, 2 or 3, and addition products thereof with acids and metal salts. Intermediates therefor of the formulas ##STR2## are also new.

46. 发明授权

US4988819A Fungicidal and plant growth-regulating azolylmethyl-cyclopropyl derivatives 失效
公开(公告)号：US4988819A
公开(公告)日：1991-01-29
申请号：US479144
申请日：1990-02-12
申请人： Klaus Stroech , Wilhelm Brandes , Stefan Dutzmann
发明人： Klaus Stroech , Wilhelm Brandes , Stefan Dutzmann
IPC分类号： C07C43/196 , A01N31/04 , A01N31/08 , A01N41/10 , A01N43/50 , A01N43/653 , C07C27/00 , C07C29/40 , C07C33/34 , C07C33/50 , C07C41/00 , C07C41/30 , C07C43/23 , C07C43/295 , C07C67/00 , C07C313/00 , C07C317/14 , C07C317/20 , C07C323/17 , C07C323/19 , C07C323/64 , C07C323/65 , C07D20060101 , C07D233/60 , C07D249/08 , C07D303/02 , C07D303/08 , C07D303/22 , C07D303/34 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07C33/50 , C07D233/56 , C07D249/08 , C07D303/02
摘要： Fungicidal and plant growth-regulating azolylmethylcyclopropyl derivatives of the formula ##STR1## in which R represents halogen, alkyl or optionally substituted phenyl, or represents the groupings --Y--R.sup.2, whereinY represents oxygen, sulphur, SO or SO.sub.2 andR.sup.2 represents optionally substituted phenyl,R.sup.1 represents hydrogen, alkyl or acyl,X represents nitrogen or a CH group,Z represents halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, halogenalkyl with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenalkoxy with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio with 1 or 2 carbon atoms and 1 to 5 halogen atoms or phenyl which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen, or represents phenoxy which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen andm represents the number 0, 1, 2 or 3,and addition products thereof with acids and metal salts. Intermediates therefor of the formulas ##STR2## are also new.

47. 发明授权

US4980488A Fungicidal and plant growth-regulating azolymethyl-cyclopropyl derivatives 失效
标题翻译：杀真菌剂和植物生长调节性多甲基 - 环丙基衍生物
公开(公告)号：US4980488A
公开(公告)日：1990-12-25
申请号：US449668
申请日：1989-12-12
申请人： Klaus Stroech , Wilhelm Brandes , Stefan Dutzmann
发明人： Klaus Stroech , Wilhelm Brandes , Stefan Dutzmann
IPC分类号： C07C43/196 , A01N31/04 , A01N31/08 , A01N41/10 , A01N43/50 , A01N43/653 , C07C27/00 , C07C29/40 , C07C33/34 , C07C33/50 , C07C41/00 , C07C41/30 , C07C43/23 , C07C43/295 , C07C67/00 , C07C313/00 , C07C317/14 , C07C317/20 , C07C323/17 , C07C323/19 , C07C323/64 , C07C323/65 , C07D20060101 , C07D233/60 , C07D249/08 , C07D303/02 , C07D303/08 , C07D303/22 , C07D303/34 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07C33/50 , C07D233/56 , C07D249/08 , C07D303/02
摘要： Fungicidal and plant growth-regulating azolylmethylcyclopropyl derivatives of the formula ##STR1## in which R represents halogen, alkyl or optionally substituted phenyl, or represents the groupings --Y--R.sup.2,whereinY represents oxygen, sulfur, SO or SO.sub.2 andR.sup.2 represents optionally substituted phenyl,R.sup.1 represents hydrogen, alkyl or acyl,X represents nitrogen or a CH group,Z represents halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, halogenoalkyl with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio with 1 or 2 carbon atoms and 1 to 5 halogen atoms or phenyl which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen, or represents phenoxy which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen andm represents the number 0, 1, 2 or 3, and addition products thereof with acids and metal salts. Intermediates therefor of the formulas ##STR2## are also new.

48. 发明授权

US4924013A Process for the reduction of free epichlorohydrin in epoxy compounds 失效
标题翻译：在环氧化合物中还原游离表氯醇的方法
公开(公告)号：US4924013A
公开(公告)日：1990-05-08
申请号：US222794
申请日：1988-07-22
申请人： Joe M. Hunter
发明人： Joe M. Hunter
IPC分类号： C07D301/27 , C07D301/32 , C07D303/02 , C08G59/00
CPC分类号： C07D303/02 , C07D301/32 , C08G59/00
摘要： A process for the reduction of free epichlorohydrin in epoxy compounds which involves the treatment of an epoxy compound with an alkali metal sulfite, preferably sodium sulfite.
摘要翻译：在环氧化合物中还原游离表氯醇的方法，其涉及用碱金属亚硫酸盐，优选亚硫酸钠处理环氧化合物。

49. 发明授权

US4723984A 1-hydroxyethyl-azole compounds and agricultural compositions 失效
标题翻译： 1-羟乙基 - 唑类化合物和农业组合物
公开(公告)号：US4723984A
公开(公告)日：1988-02-09
申请号：US621968
申请日：1984-06-18
申请人： Graham Holmwood , Karl H. Buchel , Klaus Lurssen , Paul-Ernst Frohberger , Wilhelm Brandes
发明人： Graham Holmwood , Karl H. Buchel , Klaus Lurssen , Paul-Ernst Frohberger , Wilhelm Brandes
IPC分类号： A01N20060101 , A01N43/20 , A01N43/50 , A01N43/64 , A01N43/653 , C07D20060101 , C07D233/60 , C07D249/08 , C07D301/00 , C07D301/02 , C07D303/02 , C07D303/04 , C07D303/08 , C07D303/20 , C07D303/22 , C07D521/00 , A61K31/41
CPC分类号： A01N43/50 , A01N43/653 , C07D231/12 , C07D233/56 , C07D249/08 , C07D303/02 , C07D303/04 , C07D303/08 , C07D303/22
摘要： New 1-hydroxyethyl-azole derivatives of the general formula ##STR1## in which R represents an alkyl radical, an optionally substituted cycloalkyl radical or an optionally substituted phenyl radical,X represents a nitrogen atom or a CH group,Y represents a grouping --OCH.sub.2 --, -- CH.sub.2 CH.sub.2 -- or --CH.dbd.CH--,Z represents a halogen atom, an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy or halogenoalkylthio radical, an optionally substituted phenyl radical, an optionally substituted phenoxy radical, an optionally substituted phenylalkyl radical or an optionally substituted phenylalkoxy radical andm is 0, 1, 2 or 3,a process for their preparation and their use as plant growth regulators and fungicides.
摘要翻译：其中R表示烷基，任选取代的环烷基或任选取代的苯基的新的1-羟乙基 - 唑衍生物，其中R表示氮原子或CH基团，Y表示分组-OCH 2 - ， - CH 2 CH 2 - 或-CH = CH-，Z表示卤素原子，烷基，环烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基或卤代烷硫基，任选取代的苯基，任选取代的苯氧基，任选取代的苯基烷基或任选取代的苯基烷氧基，m为0,1,2或3，其制备方法及其用作植物生长调节剂和杀真菌剂。

50. 发明授权

US4367342A Olefin epoxidation 失效
标题翻译：烯烃环氧化
公开(公告)号：US4367342A
公开(公告)日：1983-01-04
申请号：US909887
申请日：1978-05-26
申请人： Harald P. Wulff , Freddy Wattimena
发明人： Harald P. Wulff , Freddy Wattimena
IPC分类号： B01J21/06 , B01J23/02 , C07D301/19 , C07D303/02
CPC分类号： C07D301/19 , B01J21/06 , B01J21/063 , B01J23/02 , C07D303/02
摘要： Alkene oxides are produced by the reaction of an organic hydroperoxide and an alkene in the presence of a catalyst of an inorganic oxygen compound of silicon in chemical combination with an oxide or hydroxide of titanium.
摘要翻译：通过与钛的氧化物或氢氧化物的化学组合的无机氧化合物的催化剂的存在下，通过有机氢过氧化物和烯烃的反应来生产烯烃氧化物。

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