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41. 发明申请

US20110290457A1 ENDOTHERMIC CRACKING AIRCRAFT FUEL SYSTEM 审中-公开
标题翻译：内燃机飞机燃料系统
公开(公告)号：US20110290457A1
公开(公告)日：2011-12-01
申请号：US13198741
申请日：2011-08-05
申请人： Thomas Henry Vanderspurt , Zissis A. Dardas
发明人： Thomas Henry Vanderspurt , Zissis A. Dardas
IPC分类号： F28F7/00
CPC分类号： B64D37/34 , B64C3/36 , C10G11/00 , C10G51/026
摘要： A method of controlling cooling in an aircraft system includes providing a fluid having a cooling capacity to cool a heat source, and selectively endothermically cracking the fluid to increase the cooling capacity.
摘要翻译：一种控制飞行器系统中的冷却的方法包括提供具有冷却能力的流体以冷却热源，以及选择性地使流体开裂以提高冷却能力。

42. 发明授权

US07795173B2 Long-lived high volumetric activity photocatalysts 有权
标题翻译：长寿命的高体积活性光催化剂
公开(公告)号：US07795173B2
公开(公告)日：2010-09-14
申请号：US12302639
申请日：2007-05-31
申请人： Thomas Henry Vanderspurt , Treese Hugener-Campbell , Stephen O. Hay , Timothy N. Obee
发明人： Thomas Henry Vanderspurt , Treese Hugener-Campbell , Stephen O. Hay , Timothy N. Obee
IPC分类号： B01J21/00
CPC分类号： B01J35/004 , A61L9/205 , B01J21/063 , B01J23/14 , B01J35/006 , B01J35/1014 , B01J35/108 , B01J37/0225 , B82Y30/00 , C01G23/047 , C01P2002/52 , C01P2002/72 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/14
摘要： The present disclosure relates to nanocrystalline titanium dioxide (TiO2) photocatalysts having nanocrystallites of less than 14 nanometers in diameter, which are substantially defect-free. The TiO2 photocatalysts form porous particles having a very large mass transfer surface area, large cylindrical pores, and low mass transfer resistance. The nanocrystalline TiO2 photocatalysts provide at least 75% of the photocatalytic activity of commercially-available TiO2 crystals having diameters greater than 20 nm. The nanocrystalline TiO2 photocatalysts may be doped with a metal, metal oxide, or non-metal dopant. A process for preparing the nanocrystalline TiO2 photocatalysts is disclosed. The present disclosure also provides methods for using nanocrystalline TiO2 photocatalysts to remove contaminants.
摘要翻译：本公开内容涉及纳米晶体二氧化钛（TiO 2）光催化剂，其具有直径小于14纳米的纳米晶体，其基本上是无缺陷的。 TiO 2光催化剂形成具有非常大的传质表面积，大圆柱形孔和低传质阻力的多孔颗粒。纳米晶体TiO 2光催化剂提供直径大于20nm的市售TiO 2晶体的至少75％的光催化活性。纳米晶体TiO2光催化剂可掺杂金属，金属氧化物或非金属掺杂剂。公开了一种制备纳米晶TiO2光催化剂的方法。本公开还提供了使用纳米晶体TiO 2光催化剂去除污染物的方法。

43. 发明授权

US07713319B2 Glycol recycle system 有权
标题翻译：乙二醇回收系统
公开(公告)号：US07713319B2
公开(公告)日：2010-05-11
申请号：US11505079
申请日：2006-08-16
申请人： Rakesh Radhakrishnan , Steven J. Moss , Per-Anders K. Lof , Michael K. Sahm , Joseph J. Sangiovanni , Thomas Henry Vanderspurt
发明人： Rakesh Radhakrishnan , Steven J. Moss , Per-Anders K. Lof , Michael K. Sahm , Joseph J. Sangiovanni , Thomas Henry Vanderspurt
IPC分类号： C01B3/32
CPC分类号： B01J19/2475 , B01D17/085 , B01J8/0278 , B01J14/005 , B01J19/127 , B01J2208/00407 , B01J2208/00415 , B01J2208/00504 , B01J2219/00135 , B01J2219/00157 , C01B3/323 , C01B3/501 , C01B2203/0233 , C01B2203/0405 , C01B2203/047 , C01B2203/0475 , C01B2203/0805 , C01B2203/0811 , C01B2203/0827 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1217 , Y02P20/129 , Y02P20/133 , Y02P20/134
摘要： A fluid recycling system includes a separator for physically separating glycol from at least a portion of other substances mixed with the glycol to produce a first effluent stream having separated glycol and a second effluent stream having the other substances and residual glycol. A catalytic reactor receives the second effluent stream and chemically reacts the other substances and residual glycol to produce a hydrogen stream and a remainder stream.
摘要翻译：流体循环系统包括用于将二醇与至少一部分与二醇混合的物质分离以产生具有分离的二醇的第一流出物流和具有其它物质和残余二醇的第二流出物流的分离器。催化反应器接收第二流出物流并使其它物质和残余二醇发生化学反应以产生氢气流和余气流。

44. 发明申请

US20100075836A1 DEACTIVATION RESISTANT PHOTOCATALYST AND METHOD OF PREPARATION 审中-公开
标题翻译：抗激光光催化剂及其制备方法
公开(公告)号：US20100075836A1
公开(公告)日：2010-03-25
申请号：US12627981
申请日：2009-11-30
申请人： Treese Hugener-Campbell , Thomas Henry Vanderspurt , Wayde R. Schmidt , Steven M. Zhitnik
发明人： Treese Hugener-Campbell , Thomas Henry Vanderspurt , Wayde R. Schmidt , Steven M. Zhitnik
IPC分类号： B01J31/06 , B01J31/02 , B01J23/10 , B01J23/745 , B01J23/06 , B01J21/06 , B01J23/08
CPC分类号： B01J35/004 , A61L9/205 , B01D53/8687 , B01D2255/20707 , B01D2255/802 , B01D2257/708 , B01J21/063 , B01J23/06 , B01J23/10 , B01J23/14 , B01J35/1019 , B01J35/1061 , B01J35/1095 , B01J37/0018 , B01J37/0215 , B01J37/036
摘要： A photocatalyst formed using a sol-gel process provides high photoactivity, increased photocatalyst lifetime, and improved resistance to performance degradation caused by siloxane-based contaminants. The photocatalyst is formed by a method including the steps of photocatalyst template creation, template conditioning, template refinement, and coating application.
摘要翻译：使用溶胶 - 凝胶法形成的光催化剂提供高的光活性，增加的光催化剂寿命和改善的耐硅氧烷类污染物引起的性能降解。光催化剂通过包括光催化剂模板产生，模板调理，模板细化和涂布应用的步骤的方法形成。

45. 发明授权

US07655183B2 Durable pd-based alloy and hydrogen generation membrane thereof 有权
标题翻译：耐用pd基合金及其氢生成膜
公开(公告)号：US07655183B2
公开(公告)日：2010-02-02
申请号：US11712200
申请日：2007-02-28
申请人： Raymond C. Benn , Susanne M. Opalka , Thomas Henry Vanderspurt
发明人： Raymond C. Benn , Susanne M. Opalka , Thomas Henry Vanderspurt
IPC分类号： C22C5/04 , C22C5/00 , C22C30/00 , B01J20/28 , B01J35/00
CPC分类号： C01B3/505 , B01D71/022 , B01D2325/22 , C01B2203/041 , C01B2203/047 , C01B2203/0475 , H01M8/0687
摘要： A durable Pd-based alloy is used for a H2-selective membrane in a hydrogen generator, as in the fuel processor of a fuel cell plant. The Pd-based alloy includes Cu as a binary element, and further includes “X”, where “X” comprises at least one metal from group “M” that is BCC and acts to stabilize the β BCC phase for stability during operating temperatures. The metal from group “M” is selected from the group consisting of Fe, Cr, Nb, Ta, V, Mo, and W, with Nb and Ta being most preferred. “X” may further comprise at least one metal from a group “N” that is non-BCC, preferably FCC, that enhances other properties of the membrane, such as ductility. The metal from group “N” is selected from the group consisting of Ag, Au, Re, Ru, Rh, Y, Ce, Ni, Ir, Pt, Co, La and In. The at. % of Pd in the binary Pd—Cu alloy ranges from about 35 at. % to about 55 at. %, and the at. % of “X” in the higher order alloy, based on said binary alloy, is in the range of about 1 at. % to about 15 at. %. The metals are selected according to a novel process.
摘要翻译：耐用的Pd基合金用于氢发生器中的H 2选择性膜，如在燃料电池厂的燃料处理器中。 Pd基合金包括Cu作为二元元素，并且还包括“X”，其中“X”包括至少一种B族的“M”族金属，并且用于稳定βBCC相以保持工作温度。来自组“M”的金属选自Fe，Cr，Nb，Ta，V，Mo和W，Nb和Ta是最优选的。 “X”可以进一步包含至少一种金属，其来自非BCC（优选FCC）的组“N”，其提高膜的其它性质，例如延展性。来自组“N”的金属选自Ag，Au，Re，Ru，Rh，Y，Ce，Ni，Ir，Pt，Co，La和In。在。二元Pd-Cu合金中Pd的％为约35at。％至55华氏度。％，和at。基于所述二元合金的高阶合金中的“X”的％在约1at的范围内。％至约15英寸％。根据新颖的方法选择金属。

46. 发明授权

US5939352A Isobutanol synthesis catalyst--(LAW092) 失效
标题翻译：异丁醇合成催化剂 - （LAW092）
公开(公告)号：US5939352A
公开(公告)日：1999-08-17
申请号：US47204
申请日：1998-03-24
申请人： Thomas Henry Vanderspurt , Mark Alan Greaney , Daniel Paul Leta , Russell John Koveal , Mark Michael Disko , Angela V. Klaus , Sutinder K. Behal , Robert B. Harris
发明人： Thomas Henry Vanderspurt , Mark Alan Greaney , Daniel Paul Leta , Russell John Koveal , Mark Michael Disko , Angela V. Klaus , Sutinder K. Behal , Robert B. Harris
IPC分类号： B01J23/00 , B01J23/06 , B01J23/34 , B01J23/38 , B01J23/60 , B01J23/656 , B01J35/00 , C07C29/34 , B01J23/32 , B01J23/40 , B01J23/58
CPC分类号： C07C29/32 , B01J23/002 , B01J23/06 , B01J23/34 , B01J23/38 , B01J23/60 , B01J23/6562 , B01J35/0006 , B01J2523/00
摘要： The invention relates to a catalyst for conversion of methanol, ethanol alone or in combination with n-propanol to isobutanol and the process for making and using the catalyst. The catalyst is a noble metal supported on at least a first phase of mixed oxide crystallites containing from about 60 to about 74 atomic % (on a metals basis only) zirconium, from about 21 to about 31 atomic % manganese and from about 5 to about 9 atomic % zinc, and less than about 1 atomic % alkali, a second phase of zirconium-doped hetaerolite particles containing from about 65 to about 69 atomic % manganese, from about 31 to about 35 atomic % zinc, from about 0.5 to about 5 atomic % zirconium, and optionally a trace atomic % of alkali, and a third phase containing from about 29 to about 55 atomic % manganese, from about 13 to about 55 atomic % zinc and from about 13 to about 35 atomic % zirconium. The first phase mixed oxide crystallites have a zirconium oxide-like structure have a particle size of at least about 40 .ANG. to about 100 .ANG., wherein the second phase particles have a particle size of about 200 .ANG. to greater than about 2000 .ANG., and the third phase has a particle size of about 1000 .ANG. to greater than 4000 .ANG..
摘要翻译：本发明涉及用于将甲醇，乙醇单独或与正丙醇组合转化为异丁醇的催化剂以及制备和使用催化剂的方法。催化剂是负载在至少第一阶段的混合氧化物微晶的贵金属，其含有约60至约74原子％（仅金属基）锆，约21至约31原子％的锰和约5至约含有约65至约69原子％的锰，约31至约35原子％的锌，约0.5至约5原子％的锌，以及小于约1原子％的碱，第二相的锆掺杂的白粉石颗粒原子％锆和任选的痕量原子％的碱，以及含有约29至约55原子％的锰，约13至约55原子％的锌和约13至约35原子％的锆的第三相。第一相混合氧化物微晶具有氧化锆样结构，其粒径为至少约40至约100，其中第二相颗粒的粒径为约200至大于约2000，第三阶段的粒度约为1000 ANGSTROM，大于4000 ANGSTROM。

47. 发明授权

US5703133A Isoalcohol synthesis 失效
标题翻译：异构醇合成
公开(公告)号：US5703133A
公开(公告)日：1997-12-30
申请号：US569532
申请日：1995-12-08
申请人： Thomas Henry Vanderspurt , Russell John Koveal
发明人： Thomas Henry Vanderspurt , Russell John Koveal
IPC分类号： C07C29/154 , C07C27/20
CPC分类号： C07C29/154
摘要： The invention provides for a method of making isoalcohols using syngas-to-alcohol catalyst and method of making it. The catalyst is a highly dispersed, alkali promoted, La stabilized, microcrystalline Cu.sub.2 O having a particle size of .ltoreq.6 nm in the presence of an alumina structural promoter, wherein on a mole % alkali free metals-only basis Cu is present in from 45 to 55%, Zn from 10 to 20%, Al from 10 to 25%, La from 5 to 15%, and wherein the alkali is from 0.01 to 0.91% K and from 3 to 6.5% Cs. The method of making it involves coprecipitation at a constant pH from a solution of soluble metal salts of copper, zinc, lanthanum and aluminum with an alkali hydroxide, washing the coprecipitate in the essential absence of CO.sub.2, drying and calcining it, then contacting it with K and Cs to form the promoted catalyst. The promoted catalyst is dried and recalcining to produce a catalyst precursor with highly dispersed CuO crystallites. The catalyst is activated in flowing hydrogen.
摘要翻译：本发明提供了使用合成气 - 醇催化剂制备异构醇的方法及其制备方法。该催化剂是在氧化铝结构促进剂的存在下具有大小分散的碱促进的La稳定的微晶Cu2O，其具有的颗粒尺寸为<6nm，其中基于无碱金属的摩尔％的Cu存在于 45〜55％，Zn为10〜20％，Al为10〜25％，La为5〜15％，碱为0.01〜0.91％，Cs为3〜6.5％。其制备方法涉及在铜，锌，镧和铝的可溶性金属盐与碱金属氢氧化物的溶液的恒定pH下共沉淀，在基本不存在CO 2的情况下洗涤共沉淀物，干燥并煅烧，然后将其与 K和Cs形成促进催化剂。将促进的催化剂干燥并重新煅烧以产生具有高度分散的CuO微晶的催化剂前体。催化剂在流动的氢气中活化。

48. 发明授权

US5691268A Isoalcohol synthesis catalyst 失效
标题翻译：异构醇合成催化剂
公开(公告)号：US5691268A
公开(公告)日：1997-11-25
申请号：US569531
申请日：1995-12-08
申请人： Russell John Koveal , Thomas Henry Vanderspurt
发明人： Russell John Koveal , Thomas Henry Vanderspurt
IPC分类号： B01J23/83 , C07C29/154 , B01J23/72
CPC分类号： C07C29/154 , B01J23/83 , Y02P20/52
摘要： The invention provides for a method of making isoalcohols using syngas-to-alcohol catalyst and method of making it. The catalyst is a highly dispersed, alkali promoted, La stabilized, microcrystalline Cu.sub.2 O having a particle size of .ltoreq.6 nm in the presence of an alumina structural promoter, wherein on a mole % alkali free metals-only basis Cu is present in from 45 to 55%, Zn from 10 to 20%, Al from 10 to 25%, La from 5 to 15%, and wherein the alkali is from 0.01 to 0.91% K and from 3 to 6.5% Cs. The method of making it involves coprecipitation at a constant pH from a solution of soluble metal salts of copper, zinc, lanthanum and aluminum with an alkali hydroxide, washing the coprecipitate in the essential absence of CO.sub.2, drying and calcining it, then contacting it with K and Cs to form the promoted catalyst. The promoted catalyst is dried and recalcining to produce a catalyst precursor with highly dispersed CuO crystallites. The catalyst is activated in flowing hydrogen.
摘要翻译：本发明提供了使用合成气 - 醇催化剂制备异构醇的方法及其制备方法。该催化剂是在氧化铝结构促进剂的存在下具有大小分散的碱促进的La稳定的微晶Cu2O，其具有的颗粒尺寸为<6nm，其中基于无碱金属的摩尔％的Cu存在于 45〜55％，Zn为10〜20％，Al为10〜25％，La为5〜15％，碱为0.01〜0.91％，Cs为3〜6.5％。其制备方法涉及在铜，锌，镧和铝的可溶性金属盐与碱金属氢氧化物的溶液的恒定pH下共沉淀，在基本不存在CO 2的情况下洗涤共沉淀物，干燥并煅烧，然后将其与 K和Cs形成促进催化剂。将促进的催化剂干燥并重新煅烧以产生具有高度分散的CuO微晶的催化剂前体。催化剂在流动的氢气中活化。

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