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41. 发明授权

US06992057B2 Fatty acids, soaps, surfactant systems, and consumer products based thereon 失效
公开(公告)号：US06992057B2
公开(公告)日：2006-01-31
申请号：US10422886
申请日：2003-04-24
申请人： Daniel Stedman Connor , Jeffrey John Scheibel , Deborah Jean Back , Toan Trinh , Phillip Kyle Vinson , Roland George Severson , Thomas Anthony Cripe , James Charles Theophile Roger Burckett-St. Laurent , Mark Robert Sivik , Errol Hoffman Wahl , Gayle Marie Frankenbach , Marc Johan Declercq , Hugo Jean Marie Demeyere
发明人： Daniel Stedman Connor , Jeffrey John Scheibel , Deborah Jean Back , Toan Trinh , Phillip Kyle Vinson , Roland George Severson , Thomas Anthony Cripe , James Charles Theophile Roger Burckett-St. Laurent , Mark Robert Sivik , Errol Hoffman Wahl , Gayle Marie Frankenbach , Marc Johan Declercq , Hugo Jean Marie Demeyere
IPC分类号： C11D1/62
CPC分类号： C11D3/2093 , A61K8/361 , A61Q19/00 , C11D1/04 , C11D1/62 , C11D3/0015 , C11D3/2079 , C11D9/005 , C11D9/007 , C11D10/04
摘要： Novel fatty acids and derivatives thereof such as salts, new surfactant systems comprising one or more of these compounds, consumer products such as laundry products, personal care products, pharmaceutical compositions, industrial cleaners, and the like comprising said compounds or surfactant systems.

44. 发明授权

US06673961B2 Processes for making surfactants via absorptive separation and products thereof 失效
标题翻译：通过吸收分离制备表面活性剂的方法及其制品
公开(公告)号：US06673961B2
公开(公告)日：2004-01-06
申请号：US10304920
申请日：2002-11-26
申请人： Daniel Stedman Connor , Jeffrey John Scheibel , James Charles Theophile Roger Burckett-St. Laurent , Thomas Anthony Cripe , Kevin Lee Kott , Phillip Kyle Vinson
发明人： Daniel Stedman Connor , Jeffrey John Scheibel , James Charles Theophile Roger Burckett-St. Laurent , Thomas Anthony Cripe , Kevin Lee Kott , Phillip Kyle Vinson
IPC分类号： C07C30901
CPC分类号： C07C303/06 , C07C7/13 , C07C15/02 , C07C9/00 , C07C309/31
摘要： Processes for making particularly branched, especially monomethyl-branched or nongeminal dimethyl-branched surfactants used in cleaning products; preferred processes comprising particular combinations of two or more adsorptive separation steps and, more preferably, particular alkylation steps; products of such processes, including certain modified alkylbenzenes, modified alkylbenzenesulfonate surfactants, and consumer cleaning products, especially laundry detergents, containing them. Preferred processes herein more specifically use specific, unconventional sequences of sorptive separation steps to secure certain branched hydrocarbon fractions which are used in further process steps as alkylating agents for arenes or for other useful surfactant-making purposes. Surprisingly, such fractions can even be derived from effluents from current linear alkylbenzene manufacture.
摘要翻译：用于制造特别是支链的，特别是用于清洁产品中的单甲基支链或非农业二甲基支链表面活性剂的方法; 优选的方法包括两个或多个吸附分离步骤的特定组合，更优选特定的烷基化步骤; 这些方法的产物，包括某些改性烷基苯，改性烷基苯磺酸盐表面活性剂，以及含有它们的消费者清洁产品，特别是衣物洗涤剂。本文优选的方法更具体地使用吸附分离步骤的特定的非常规序列，以确保在进一步的工艺步骤中使用的某些支链烃馏分作为芳烃的烷基化剂或其它有用的表面活性剂制备目的。令人惊讶的是，这些馏分甚至可以从目前的直链烷基苯生产的流出物得到。

45. 发明授权

US06602845B2 Fatty acids, soaps, surfactant systems, and consumer products based thereon 有权
标题翻译：脂肪酸，肥皂，表面活性剂体系和基于其的消费品
公开(公告)号：US06602845B2
公开(公告)日：2003-08-05
申请号：US10143356
申请日：2002-05-10
申请人： Daniel Stedman Connor , Jeffrey John Scheibel , Deborah Jean Back , Toan Trinh , Phillip Kyle Vinson , Roland George Severson , Thomas Anthony Cripe , James Charles Theophile Roger Burckett-St. Laurent , Mark Robert Sivik , Errol Hoffman Wahl , Gayle Marie Frankenbach , Marc Johan Declercq , Hugo Jean Marie Demeyere
发明人： Daniel Stedman Connor , Jeffrey John Scheibel , Deborah Jean Back , Toan Trinh , Phillip Kyle Vinson , Roland George Severson , Thomas Anthony Cripe , James Charles Theophile Roger Burckett-St. Laurent , Mark Robert Sivik , Errol Hoffman Wahl , Gayle Marie Frankenbach , Marc Johan Declercq , Hugo Jean Marie Demeyere
IPC分类号： C11D104
CPC分类号： A61Q19/00 , A61K8/361 , C11D1/04 , C11D1/62 , C11D1/65 , C11D3/0015 , C11D3/2079 , C11D3/2093 , C11D3/43 , C11D9/005 , C11D9/007 , C11D10/04 , Y02P20/582
摘要： Novel fatty acids and derivatives thereof such as salts, new surfactant systems comprising one or more of these compounds, consumer products such as laundry products, personal care products, pharmaceutical compositions, industrial cleaners, and the like comprising said compounds or surfactant systems.
摘要翻译：新型脂肪酸及其衍生物如盐，包含一种或多种这些化合物的新型表面活性剂体系，消费品如洗衣产品，个人护理产品，药物组合物，工业清洁剂等，其包含所述化合物或表面活性剂体系。

46. 发明授权

US06589927B1 Detergent compositions containing modified alkylaryl sulfonate surfactants 失效
标题翻译：含有改性烷基芳基磺酸盐表面活性剂的洗涤剂组合物
公开(公告)号：US06589927B1
公开(公告)日：2003-07-08
申请号：US09980800
申请日：2001-12-03
申请人： Kevin Lee Kott , Jeffrey John Scheibel , Roland George Severson , Thomas Anthony Cripe , James Charles Theophile Roger Burckett-St. Laurent
发明人： Kevin Lee Kott , Jeffrey John Scheibel , Roland George Severson , Thomas Anthony Cripe , James Charles Theophile Roger Burckett-St. Laurent
IPC分类号： C11D1700
CPC分类号： C11D1/65 , C11D1/22 , C11D1/83 , C11D1/86 , C11D1/94
摘要： The present invention is in the field of processes for making alkylbenzenesulfonate surfactants. The processes herein include a combination of two essential steps, delinearization and alkylation. The delinearization step selected herein introduces particular types of limited branching into an aliphatic hydrocarbon having ten or more, but no more than about 16, carbon atoms. The hydrocarbon includes olefin having a hydrocarbon chain length suitable for detergent manufacture, e.g., C10-C14, or a corresponding paraffin. The second essential step is an alkylation step having an internal isomer selectivity of from 0 to no more than about 40 in which the hydrocarbon is used to monoalkylate benzene catalytically with an alkylation catalyst. Such alkylation catalysts preferably comprise an at least partially crystalline porous zeolite-containing solid, the zeolite having moderate acidity and intermediate pore size. Preferred alkylation catalysts include certain at least partially dealuminized acidic nonfluorinated mordenites. The processes herein further comprise sulfonating, neutralizing and incorporating the resulting modified alkylbenzenesulfonate surfactants into consumer products. The invention relates also to the products of the processes, including modified surfactants and consumer cleaning products containing them.
摘要翻译：本发明涉及制备烷基苯磺酸盐表面活性剂的方法领域。本文的方法包括两个必要步骤，划线和烷基化的组合。本文选择的描述步骤将特定类型的有限支化引入具有10个或更多个但不超过约16个碳原子的脂族烃。烃包括具有适于洗涤剂制造的烃链长度的烯烃，例如C10-C14或相应的石蜡。第二个关键步骤是烷基化步骤，其内部异构体选择性为0至不超过约40，其中烃用烷基化催化剂催化苯烷基化。这种烷基化催化剂优选包括至少部分结晶的含多孔沸石的固体，沸石具有适度的酸度和中等孔径。优选的烷基化催化剂包括某些至少部分脱铝的酸性非氟化丝光沸石。本文的方法还包括将所得的改性烷基苯磺酸盐表面活性剂磺化，中和并并入消费品中。本发明还涉及该方法的产品，包括改性表面活性剂和含有它们的消费者清洁产品。

47. 发明授权

US06566318B2 Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids 有权
公开(公告)号：US06566318B2
公开(公告)日：2003-05-20
申请号：US10093115
申请日：2002-03-07
申请人： Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent , Michael Eugene Burns
发明人： Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent , Michael Eugene Burns
IPC分类号： C11D732
CPC分类号： C11D3/3907 , C11D3/168 , C11D3/3932 , C11D3/3945
摘要： Laundry or cleaning composition comprising: (a) an effective amount, preferably from about 0.0001% to about 99.9%, more typically from about 0.1% to about 25%, of a bleach activator and/or organic percarboxylic acid; (b) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (c) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts in combination with bleach activators and/or organic percarboxylic acids.

48. 发明授权

US06274540B1 Detergent compositions containing mixtures of crystallinity-disrupted surfactants 失效
标题翻译：含有结晶破坏表面活性剂混合物的洗涤剂组合物
公开(公告)号：US06274540B1
公开(公告)日：2001-08-14
申请号：US09479369
申请日：2000-01-07
申请人： Jeffrey John Scheibel , Thomas Anthony Cripe , Kevin Lee Kott , Daniel Stedman Connor , James Charles Theophile Roger Burckett-St. Laurent , Phillip Kyle Vinson
发明人： Jeffrey John Scheibel , Thomas Anthony Cripe , Kevin Lee Kott , Daniel Stedman Connor , James Charles Theophile Roger Burckett-St. Laurent , Phillip Kyle Vinson
IPC分类号： C11D1700
CPC分类号： C11D1/22
摘要： A cleaning composition comprising: a) about 0.1% to about 99.9% by weight of said composition of an alkylarylsulfonate surfactant system comprising from about 10% to about 100% by weight of said surfactant system of two or more crystallinity-disrupted alkylarylsulfonate surfactants of formula (B-Ar-D)a(Mq+)b(Defined herein after); and b) from about 0.00001% to about 99.9% by weight of said composition of cleaning composition adjunct ingredients, at least one of which is selected from the group consisting of: i) detersive enzymes; ii) organic detergent builders; iii) oxygen bleaching agent; iv) bleach activators; v) transition metal bleach catalysts; vi) oxygen transfer agents and precursors; vii) polymeric soil release agents; viii) water-soluble ethoxylated amines having clay soil removal and antiredeposition properties; ix) polymeric dispersing agents; x) polymeric dye transfer inhibiting agents; xi) alkoxylated polycarboxylates; and xii) mixtures thereof.
摘要翻译：一种清洁组合物，其包含：a）约0.1％至约99.9％重量的所述组合物的烷基芳基磺酸盐表面活性剂体系，其包含约10％至约100％重量的所述表面活性剂体系，两种或更多种结晶度破坏的烷基芳基磺酸盐表面活性剂）为所述组合物的约0.00001％至约99.9％重量的清洁组合物辅助成分，其中至少一种选自：i）去污酶; ii）有机洗涤剂助剂; iii）氧漂剂; iv）漂白活化剂; v）过渡金属漂白剂催化剂; vi）氧传递剂和前体; vii）聚合物去污剂; viii）具有粘土去除和抗再沉积性质的水溶性乙氧基化胺; ix）聚合物分散剂; x）聚合染料转移抑制剂; xi）烷氧基化多羧酸盐; 和xii）其混合物。

49. 发明授权

US06153577A Polyoxyalkylene surfactants 失效
标题翻译：聚氧化烯表面活性剂
公开(公告)号：US06153577A
公开(公告)日：2000-11-28
申请号：US426594
申请日：1999-10-26
申请人： Thomas Anthony Cripe , Daniel Stedman Connor , Phillip Kyle Vinson , James Charles Theophile Roger Burckett-St. Laurent , Kenneth William Willman
发明人： Thomas Anthony Cripe , Daniel Stedman Connor , Phillip Kyle Vinson , James Charles Theophile Roger Burckett-St. Laurent , Kenneth William Willman
IPC分类号： C07C43/11 , C11D1/72 , C11D1/722 , C11D1/66
CPC分类号： C07C43/11 , C11D1/72 , C11D1/722
摘要： Mid-chain branched primary alkyl polyoxyalkylene surfactants useful in laundry and cleaning compositions, especially granular and liquid detergent compositions. These surfactants are also suitable for formulation with other surfactants for the purpose of providing improved surfactant systems, especially for use in detergent compositions which will be used in laundry processes involving low water temperature wash conditions. The present invention also relates to novel mid-chain branched primary alkyl polyoxyalkylene surfactants suitable for use in the surfactant mixtures.
摘要翻译：用于洗衣和清洁组合物的中链支链伯烷基聚氧化烯表面活性剂，特别是颗粒和液体洗涤剂组合物。为了提供改进的表面活性剂体系，这些表面活性剂也适用于与其它表面活性剂的配制，特别是用于洗涤剂组合物中，该组合物将用于涉及低水温洗涤条件的洗衣过程中。本发明还涉及适用于表面活性剂混合物的新型中链支链伯烷基聚氧化烯表面活性剂。

50. 发明授权

US5753138A Bleaching detergent compositions comprising bleach activators effective at low perhydroxyl concentrations 失效
标题翻译：漂白洗涤剂组合物，其包含在低全羟基浓度下有效的漂白活化剂
公开(公告)号：US5753138A
公开(公告)日：1998-05-19
申请号：US768188
申请日：1996-12-17
申请人： Randall Alan Watson , Kevin Lee Kott , Alan David Willey , Gregory Scot Miracle , James Charles Theophile Roger Burckett-St. Laurent
发明人： Randall Alan Watson , Kevin Lee Kott , Alan David Willey , Gregory Scot Miracle , James Charles Theophile Roger Burckett-St. Laurent
IPC分类号： C11D3/39 , C01B11/00 , C01B7/00 , C11D3/02
CPC分类号： C11D3/392
摘要： Bleaching detergent compositions comprising particular bleach activators are provided. Excellent bleaching is secured through the selection of bleach activators which operate successfully under mildly alkaline washing conditions or in the presence of reduced levels of hydrogen peroxide.
摘要翻译：提供了包含特定漂白活化剂的漂白洗涤剂组合物。通过选择在弱碱性洗涤条件下或在降低水平的过氧化氢存在下成功操作的漂白活化剂来确保优异的漂白。

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