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41. 发明申请

US20120157642A1 Catalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Polymer from Same 失效
标题翻译：具有烷氧基烷基酯内部电子供体和聚合物的催化剂组合物
公开(公告)号：US20120157642A1
公开(公告)日：2012-06-21
申请号：US12974322
申请日：2010-12-21
申请人： Linfeng Chen , Kelly Gonzalez
发明人： Linfeng Chen , Kelly Gonzalez
IPC分类号： C08F2/38 , C08F110/06 , C08F210/06 , B01J31/14
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions include an internal electron donor with a compounded alkoxyalkyl ester and optionally a mixed external electron donor. The present catalyst compositions improve catalyst selectivity, improve catalyst activity, and/or improve hydrogen response. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 10 g/10 min.
摘要翻译：本文公开了催化剂组合物和聚合物，即由其制备的基于丙烯的聚合物。本催化剂组合物包括具有化合的烷氧基烷基酯和任选的混合的外电子给体的内电子给体。本催化剂组合物改善催化剂选择性，改善催化剂活性和/或改善氢气响应。由本催化剂组合物制备的丙烯类聚合物的熔体流动速率大于10g / 10min。

42. 发明授权

US08106138B2 Random propylene copolymer compositions, articles and process 有权
标题翻译：无规丙烯共聚物组合物，制品和工艺
公开(公告)号：US08106138B2
公开(公告)日：2012-01-31
申请号：US12650633
申请日：2009-12-31
申请人： William G. Sheard , Linfeng Chen , Daniel W. Baugh, III , Peter S. Martin
发明人： William G. Sheard , Linfeng Chen , Daniel W. Baugh, III , Peter S. Martin
IPC分类号： C08F210/02 , C08F210/06 , C08F2/00 , C08F210/00
CPC分类号： C08F10/06 , C07C37/02 , C07C37/14 , C07C37/16 , C07C37/50 , C07C37/56 , C07C37/60 , C07C67/14 , C08F110/06 , C08F210/06 , C07C69/78 , C08F4/651 , C08F210/16 , C08F2500/12 , C07C39/08 , C08F4/6494 , C08F4/6465 , C08F2500/18 , C08F4/6545
摘要： The present disclosure is directed to random propylene/α-olefin compositions, articles, and processes for producing the same. The present compositions contain a random copolymer of propylene and α-olefin. Polymerization with an improved catalyst composition increases the molecular weight distribution of the copolymer and increases the randomness of comonomer distribution to yield random propylene/α-olefin copolymers with improved stiffness and/or improved optical properties.
摘要翻译：本公开内容涉及无规丙烯/α-烯烃组合物，制品及其制备方法。本发明组合物含有丙烯与α-烯烃的无规共聚物。具有改进的催化剂组合物的聚合增加了共聚物的分子量分布，并增加了共聚单体分布的随机性，从而产生随机的丙烯/α-烯烃共聚物，具有改进的刚性和/或改善的光学性能。

43. 发明授权

US07893003B2 Catalyst composition with mixed selectivity control agent and method 有权
标题翻译：催化剂组成与混合选择性控制剂及方法
公开(公告)号：US07893003B2
公开(公告)日：2011-02-22
申请号：US12390785
申请日：2009-02-23
申请人： Linfeng Chen
发明人： Linfeng Chen
IPC分类号： C08F4/649 , B01J31/00
CPC分类号： B01J8/1872 , B01J8/1809 , B01J31/0201 , B01J31/0212 , B01J31/0272 , B01J31/128 , B01J31/143 , B01J31/2213 , B01J31/2226 , C08F10/02 , C08F10/06 , C08F110/06 , C08F210/06 , C08F2400/02 , C08F2/40 , C08F2/34 , C08F2/00 , C08F4/6465 , C08F4/6494 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F210/16
摘要： The present disclosure provides a Ziegler-Natta catalyst composition comprising a procatalyst, a cocatalyst and a mixed external electron donor comprising a first selectivity control agent, a second selectivity control agent, and an activity limiting agent. A polymerization process incorporating the present catalyst composition produces a high-stiffness propylene-based polymer with a melt flow rate greater than about 50 g/10 min. The polymerization process occurs in a single reactor, utilizing standard hydrogen concentration with no visbreaking.
摘要翻译：本公开提供了齐格勒 - 纳塔催化剂组合物，其包含前催化剂，助催化剂和包含第一选择性控制剂，第二选择性控制剂和活性限制剂的混合外电子供体。掺入本催化剂组合物的聚合方法产生熔体流动速率大于约50g / 10min的高刚性丙烯基聚合物。聚合过程发生在单个反应器中，利用没有减粘裂化的标准氢浓度。

44. 发明申请

US20100204506A1 Production of Substituted Phenylene Aromatic Diesters and Compositions 有权
标题翻译：取代苯亚芳基二酯和组合物的生产
公开(公告)号：US20100204506A1
公开(公告)日：2010-08-12
申请号：US12651268
申请日：2009-12-31
申请人： Linfeng Chen , Tak W. Leung , Tao Tao , Xiaodong Huang , Kuanqiang Gao , James X. Shu
发明人： Linfeng Chen , Tak W. Leung , Tao Tao , Xiaodong Huang , Kuanqiang Gao , James X. Shu
IPC分类号： C07C69/76
CPC分类号： C07C69/78 , C07C69/753 , C07C69/76 , C07C69/92
摘要： The present disclosure provides processes for the production of substituted phenylene aromatic diesters and the resultant compositions. The processes include reacting an aromatic diol with an aromatic carboxylic acid or a derivative thereof. The aromatic diol and/or the aromatic carboxylic acid (or derivative thereof) is/are substituted. The reaction forms a substituted phenylene aromatic diester with the structure (II): wherein R1-R14 are the same or different. At least one of R1-R14 is selected from a substituted hydrocarbyl group having 1 to 20 carbon atoms, an unsubstituted hydrocarbyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a heteroatom, and combinations thereof.
摘要翻译：本公开提供了制备取代的亚苯基芳族二酯和所得组合物的方法。该方法包括使芳族二醇与芳族羧酸或其衍生物反应。芳族二醇和/或芳族羧酸（或其衍生物）被取代。该反应形成具有结构（II）的取代的亚苯基芳族二酯：其中R1-R14相同或不同。 R1-R14中的至少一个选自碳原子数1〜20的取代烃基，碳原子数1〜20的未取代烃基，碳原子数1〜20的烷氧基，杂原子及其组合。

45. 发明申请

US20100174105A1 Production of Substituted Phenylene Aromatic Diesters 失效
标题翻译：取代苯亚芳基二酯的生产
公开(公告)号：US20100174105A1
公开(公告)日：2010-07-08
申请号：US12651142
申请日：2009-12-31
申请人： Tak W. Leung , Gary A. Roth , Tao Tao , Kuanqiang Gao , Linfeng Chen
发明人： Tak W. Leung , Gary A. Roth , Tao Tao , Kuanqiang Gao , Linfeng Chen
IPC分类号： C07C67/00 , C07C37/00 , C07C45/00 , C07C39/24
CPC分类号： C08F10/06 , C07C37/02 , C07C37/14 , C07C37/16 , C07C37/50 , C07C37/56 , C07C37/60 , C07C67/14 , C08F110/06 , C08F210/06 , C07C69/78 , C08F4/651 , C08F210/16 , C08F2500/12 , C07C39/08 , C08F4/6494 , C08F4/6465 , C08F2500/18 , C08F4/6545
摘要： The present disclosure is directed to the production of 5-tert-butyl-3-methyl-1,2-phenylene dibenzoate and the purification thereof. Synthesis pathways for a precursor to 5-tert-butyl-3-methyl-1,2-phenylene dibenzoate are provided. The precursor is 5-tert-butyl-3-methylcatechol.
摘要翻译：本公开涉及5-叔丁基-3-甲基-1,2-亚苯基二苯甲酸酯的制备及其纯化。提供了5-叔丁基-3-甲基-1,2-亚苯基二苯甲酸酯的前体的合成途径。前体是5-叔丁基-3-甲基儿茶酚。

46. 发明申请

US20100168342A1 Propylene Impact Copolymer and Method 有权
标题翻译：丙烯冲击共聚物和方法
公开(公告)号：US20100168342A1
公开(公告)日：2010-07-01
申请号：US12650625
申请日：2009-12-31
申请人： William G. Sheard , Linfeng Chen
发明人： William G. Sheard , Linfeng Chen
IPC分类号： C08F210/06
CPC分类号： C08F10/06 , C07C37/02 , C07C37/14 , C07C37/16 , C07C37/50 , C07C37/56 , C07C37/60 , C07C67/14 , C08F110/06 , C08F210/06 , C07C69/78 , C08F4/651 , C08F210/16 , C08F2500/12 , C07C39/08 , C08F4/6494 , C08F4/6465 , C08F2500/18 , C08F4/6545
摘要： Disclosed are propylene impact copolymer compositions, articles thereof, and processes for producing same. Polymerization with an improved catalyst composition provides a propylene impact copolymer with high melt flow and low volatiles content.
摘要翻译：公开了丙烯抗冲共聚物组合物，其制品及其制备方法。具有改进的催化剂组合物的聚合提供了具有高熔体流动性和低挥发物含量的丙烯抗冲共聚物。

47. 发明申请

US20080319146A1 Catalyst Composition with Monocarboxylic Acid Ester Internal Donor and Propylene Polymerization Process 失效
标题翻译：催化剂组合物与单羧酸酯内部供体和丙烯聚合方法
公开(公告)号：US20080319146A1
公开(公告)日：2008-12-25
申请号：US12145061
申请日：2008-06-24
申请人： Jeffery S. Bradley , Linfeng Chen , William G. Sheard , Michael P. Zummallen
发明人： Jeffery S. Bradley , Linfeng Chen , William G. Sheard , Michael P. Zummallen
IPC分类号： C08F4/00 , B01J31/02
CPC分类号： B01J31/128 , B01J31/0212 , B01J31/04 , B01J31/143 , B01J2231/122 , B01J2531/22 , B01J2531/46 , C08F110/06 , C08F4/6494 , C08F4/651 , C08F4/6465 , C08F2500/12 , C08F2500/18
摘要： A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more monoesters of aromatic carboxylic acid internal electron donors; one or more aluminum containing cocatalyst; and a mixture of two or more different selectivity control agents, said SCA mixture comprising from 70 to 98 mol percent of one or more esters of one or more aromatic monocarboxylic acids or substituted derivatives thereof, and from 30 to 2 mol percent of one or more alkoxysilane compounds containing one or more 5- or 6-membered cyclic groups optionally containing one or more Group 14, 15 or 16 heteroatoms.
摘要翻译：一种用于丙烯聚合的催化剂组合物，其包含一种或多种齐格勒 - 纳塔前催化剂组合物，其包含一种或多种过渡金属化合物和一种或多种芳族羧酸内电子给体的单酯; 一种或多种含铝助催化剂; 和两种或更多种不同选择性控制剂的混合物，所述SCA混合物包含70至98mol％的一种或多种一种或多种芳族单羧酸或其取代衍生物的酯，以及30至2mol％的一种或多种含有一个或多个任选含有一个或多个第14,15或16个杂原子的5或6元环基团的烷氧基硅烷化合物。

48. 发明申请

US20050003953A1 Olefin polymerization catalyst compositions and method of preparation 有权
标题翻译：烯烃聚合催化剂组合物及其制备方法
公开(公告)号：US20050003953A1
公开(公告)日：2005-01-06
申请号：US10903309
申请日：2004-07-30
申请人： Linfeng Chen , Richard Kemp , Thomas Nemzek
发明人： Linfeng Chen , Richard Kemp , Thomas Nemzek
IPC分类号： C08F4/654 , C08F4/658 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00 , C08F4/6574 , C08F4/6548 , C08F4/685 , C08F4/658 , C08F4/6565
摘要： A method of making a solid procatalyst composition for use in a Ziegler-Natta olefin polymerization catalyst composition, said method comprising: contacting a precursor composition comprising a magnesium compound with a titanium halide compound and an internal electron donor in any order, in a suitable reaction medium to prepare a solid procatalyst composition, separating the solid procatalyst from the reaction medium, extracting the solid procatalyst composition by contacting the same one or more times with a liquid diluent at an elevated temperature for a period of time sufficient to prepare a solid procatalyst composition having a decreased titanium content compared to the titanium content of the solid procatalyst composition before said extraction, and recovering the solid procatalyst composition.
摘要翻译：一种制备用于齐格勒 - 纳塔烯烃聚合催化剂组合物的固体前催化剂组合物的方法，所述方法包括：在合适的反应中以任何顺序将包含镁化合物的前体组合物与卤化钛化合物和内部电子给体接触培养基以制备固体前催化剂组合物，将固体前催化剂从反应介质中分离出来，通过在高温下将液体稀释剂与液体稀释剂接触一段或者多次，将其固体原料催化剂组合物提取一段时间足以制备固体前催化剂组合物在所述萃取之前，与固体前催化剂组合物的钛含量相比，钛含量降低，并且回收固体前催化剂组合物。

49. 发明授权

US09796796B2 Self-limiting catalyst composition with No silane 有权
公开(公告)号：US09796796B2
公开(公告)日：2017-10-24
申请号：US12674485
申请日：2008-08-20
申请人： Linfeng Chen , Richard E. Campbell, Jr.
发明人： Linfeng Chen , Richard E. Campbell, Jr.
IPC分类号： C08F4/64 , C08F4/44 , B01J37/00 , C08F4/02 , C08F10/06 , C08F110/02 , C08F110/06
CPC分类号： C08F10/06 , C08F110/02 , C08F110/06 , C08F4/6495 , C08F4/6494 , C08F4/651 , C08F2/40
摘要： A catalyst composition for the polymerization of propylene is provided. The catalyst composition includes one or more Ziegler-Natta procatalyst compositions having one or more transition metal compounds and an internal electron donor, one or more aluminum containing cocatalysts, and a selectivity control agent (SCA). The SCA is a mixture of an activity limiting agent (ALA) and selectivity determining agent (SDA) such as a non-silane composition. The present catalyst composition is silane-free, has high catalyst activity and high stereoselectivity, and is self-extinguishing.

50. 发明申请

US20140012035A1 Production of Substituted Phenylene Aromatic Diesters 审中-公开
标题翻译：取代苯亚芳基二酯的生产
公开(公告)号：US20140012035A1
公开(公告)日：2014-01-09
申请号：US14007188
申请日：2012-03-27
申请人： Linfeng Chen , Tak W. Leung , Kuanqiang Gao , Tao Tao
发明人： Linfeng Chen , Tak W. Leung , Kuanqiang Gao , Tao Tao
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , C07C37/002 , C07C37/02 , C07C37/055 , C07C37/62 , C07C41/18 , C07C41/30 , C07C45/515 , C07C67/14 , C07C39/27 , C07C39/08 , C07C43/23 , C07C69/78 , C07C47/565
摘要： Synthesis pathways for a precursor to 5-tert-butyl-3-methyl-1, 2-phenylene dibenzoate are provided. The precursor is methylcatechol and/or 5-tert-butyl-3-methylcatechol.
摘要翻译：提供了5-叔丁基-3-甲基-1,2-亚苯基二苯甲酸酯的前体的合成途径。前体是甲基儿茶酚和/或5-叔丁基-3-甲基儿茶酚。

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