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41. 发明授权

US5403964A Process for conversion of ethers to alcohols and olefins 失效
标题翻译：将醚转化为醇和烯烃的方法
公开(公告)号：US5403964A
公开(公告)日：1995-04-04
申请号：US187672
申请日：1994-01-27
申请人： Ramzi Y. Saleh , Joel R. Livingston, Jr. , Michael Siskin , Glen B. Brons
发明人： Ramzi Y. Saleh , Joel R. Livingston, Jr. , Michael Siskin , Glen B. Brons
IPC分类号： C07C1/20 , C07C11/02 , C07C29/10 , C07C31/10 , C07C31/12 , C07C27/00 , C07C29/00
CPC分类号： C07C31/12 , C07C1/20 , C07C29/10 , C07C31/10
摘要： The present invention relates to enhanced process for converting certain ethers, such as sec-butyl ether and isopropyl ether to their corresponding reaction products in the presence of water. This may be accomplished by adding a rate enhancing surfactant, such as an anionic or cationic surfactant to a mixture of the ether and water, preferably least about 10.sup.-5 molar surfactant. Under those conditions the reaction shows an increase in reaction rate over the rate of the process wherein surfactant is not used.
摘要翻译：本发明涉及在水存在下将某些醚如仲丁醚和异丙醚转化成其相应的反应产物的增强方法。这可以通过将速率增强表面活性剂例如阴离子或阳离子表面活性剂加入到醚和水的混合物中，优选至少约10-5摩尔表面活性剂来实现。在这些条件下，该反应显示反应速率相对于不使用表面活性剂的方法的速率增加。

42. 发明授权

US5338442A Process for converting and upgrading organic resource materials in aqueous environments 失效
标题翻译：在水环境中转化和提升有机资源材料的过程
公开(公告)号：US5338442A
公开(公告)日：1994-08-16
申请号：US852438
申请日：1992-03-16
申请人： Michael Siskin , Alan R. Katritzky , Glen B. Brons
发明人： Michael Siskin , Alan R. Katritzky , Glen B. Brons
IPC分类号： B01J21/16 , B01J27/10 , C07B61/00 , C10G1/00 , C10G1/04 , C10G31/08
CPC分类号： C10G31/08 , C10G1/04
摘要： The invention is a process for the aqueous conversion and upgrading of organic resource materials carried out by contacting organic resource materials selected from the group consisting of coal, shale, coal liquids, shale oil, and bitumen with liquid water in the absence of externally supplied hydrogen or reducing agents, controlling the temperature in the range from above about 200.degree. C. to below the critical temperature of water to maintain water in a liquid phase, wherein the pressure is the corresponding vapor pressure (autogenous pressure) of the system, for a time sufficient to effect the conversion and upgrading process. Additionally, the contacting may be conducted in the presence of a catalyst selected from the group consisting of a brine catalyst, clay catalyst and mixtures thereof.
摘要翻译：本发明是通过在不存在外部供应的氢的情况下将选自煤，页岩，煤液，页岩油和沥青的有机资源材料与液态水接触而进行的有机资源材料的水转化和升级的方法或还原剂，将温度控制在高于约200℃至低于水的临界温度的范围内，以将水保持在液相中，其中压力是系统的相应蒸气压（自生压力），对于时间足以影响转换升级过程。另外，接触可以在选自盐水催化剂，粘土催化剂及其混合物的催化剂的存在下进行。

43. 发明授权

US5283318A Process for depolymerization of butyl rubbers and halobutyl rubbers using hot liquid water 失效
标题翻译：使用热液体水解丁基橡胶和卤代丁基橡胶的方法
公开(公告)号：US5283318A
公开(公告)日：1994-02-01
申请号：US812175
申请日：1991-12-20
申请人： Ramzi Y. Saleh , Michael Siskin , George Knudsen
发明人： Ramzi Y. Saleh , Michael Siskin , George Knudsen
IPC分类号： C08C19/08 , C08F8/26 , C08F8/50 , C08F6/04
CPC分类号： C08F8/26 , C08F8/50
摘要： The present invention relates to a process for depolymerizing and dehalogenating rubber materials by heating the rubber materials with neutral liquid water at temperatures from about 200.degree. C. up to the critical temperature of water at autogenous pressure. The process has utility in degrading rubber materials, and further does not release hydrogen halogen into a gas phase.
摘要翻译：本发明涉及一种通过在约200℃至约自然压力的水临界温度的温度下用中性液体水加热橡胶材料来解聚和脱卤橡胶材料的方法。该方法可用于降解橡胶材料，并且不会将氢卤素释放到气相中。

44. 发明授权

US4576707A Process for beneficiating coal 失效
标题翻译：精选煤的工艺
公开(公告)号：US4576707A
公开(公告)日：1986-03-18
申请号：US686609
申请日：1984-12-27
申请人： Michael Siskin , Glen B. Brons
发明人： Michael Siskin , Glen B. Brons
IPC分类号： C10G1/00 , C10G1/04 , C10L9/02
CPC分类号： C10G1/04 , C10G1/00 , C10L9/02
摘要： Disclosed is a process for beneficiating coal by contacting the coal with (a) an ammonium salt solution and (b) an organic solvent, at a temperature from about 0.degree. C. to about 300.degree. C.
摘要翻译：公开了一种通过使煤与（a）铵盐溶液和（b）有机溶剂在约0℃至约300℃的温度下接触来优化煤的方法。

45. 发明授权

US4491514A Process for beneficiating oil-shale 失效
标题翻译：油页岩选矿工艺
公开(公告)号：US4491514A
公开(公告)日：1985-01-01
申请号：US600432
申请日：1984-04-16
申请人： Michael Siskin , Glen B. Brons
发明人： Michael Siskin , Glen B. Brons
IPC分类号： C10G1/00 , C10G1/04 , C10L9/02
CPC分类号： C10G1/00 , C10G1/04 , C10L9/02
摘要： Disclosed is a process for removing mineral matter from oil-shale which method comprises contacting the oil-shale with (a) an ammonium salt solution, and (b) a nonionic surfactant at a temperature from about 0.degree. C. to about 300.degree. C. for a time which is sufficient to substantially separate at least about 80 wt. % of the carbonate mineral matter of the oil-shale.
摘要翻译：公开了一种从油页岩中去除矿物质的方法，该方法包括使油页岩与（a）铵盐溶液接触，和（b）非离子表面活性剂在约0℃至约300℃的温度下一段时间足以基本上分离出至少约80wt。％的油页岩的碳酸盐矿物质。

46. 发明授权

US4491513A Process for beneficiating oil-shale 失效
标题翻译：油页岩选矿工艺
公开(公告)号：US4491513A
公开(公告)日：1985-01-01
申请号：US600431
申请日：1984-04-16
申请人： Michael Siskin , Glen B. Brons
发明人： Michael Siskin , Glen B. Brons
IPC分类号： C10G1/00 , C10G1/04 , C10L9/02
CPC分类号： C10L9/02 , C10G1/00 , C10G1/04
摘要： Disclosed is a process for removing mineral matter from oil-shale by contacting the oil-shale with (a) an ammonium salt solution and (b) an organic solvent, at a temperature from about 0.degree. C. to about 300.degree. C. for a time which is sufficient to substantially separate at least about 80 wt. % of the carbonate mineral matter from the oil-shale.
摘要翻译：公开了一种通过使油页岩与（a）铵盐溶液和（b）有机溶剂在约0℃至约300℃的温度下接触来从油页岩中除去矿物质的方法，用于足以基本分离至少约80wt。来自油页岩的碳酸盐矿物质的百分比。

47. 发明授权

US4069268A Regeneration of metal halide catalysts via halogenation 失效
标题翻译：通过卤化再生金属卤化物催化剂
公开(公告)号：US4069268A
公开(公告)日：1978-01-17
申请号：US628587
申请日：1975-11-04
申请人： Michael Siskin , Ronald J. Gillespie
发明人： Michael Siskin , Ronald J. Gillespie
IPC分类号： B01J27/32 , C07C2/54 , C07C2/60 , C07C2/68 , C07C5/22 , C07C5/28 , C07C3/54 , C10G35/06
CPC分类号： C07C2/68 , B01J27/32 , C07C2/54 , C07C2/60 , C07C5/2253 , C07C2527/1206 , C07C2527/133 , Y02P20/584
摘要： Deactivated or partially deactivated hydrocarbon conversion catalysts comprising (a) one or more Lewis acids of the formula MX.sub.n where M is a component selected from Group IIIA, IVB, V, VIB or VIII Elements of the Periodic Table or their mixtures, X is a halogen, and n is the atomic ratio of halogen to M and varies from 1 to 8, and (b) a strong Bronsted acid, may be regenerated by contacting said catalysts with a halogen selected from the group consisting of fluorine or chlorine. If a portion of the catalyst has been hydrolyzed, the catalyst may be regenerated via halogenation as above or by contact with a hydrogen halide selected from the group consisting of hydrogen fluoride or hydrogen chloride and then fluorine. The preferred Lewis acid is a metal halide, preferably tantalum pentafluoride, niobium pentafluoride or mixtures thereof. The preferred Bronsted acid is a hydrogen halide, preferably hydrogen fluoride.
摘要翻译：包括（a）一种或多种式MXn的路易斯酸，其中M是选自元素周期表的IIIA，IVB，V，VIB或VIII族元素的组分或其混合物，X是卤素，n为卤素与M的原子比，为1〜8，（b）强布朗斯台德酸可通过使所述催化剂与选自氟或氯的卤素接触而再生。如果催化剂的一部分已经被水解，则催化剂可以通过如上所述的卤化或通过与选自氟化氢或氯化氢然后氟化物的卤化氢接触来再生。优选的路易斯酸是金属卤化物，优选五氟化钽，五氟化铌或其混合物。优选的布朗斯台德酸是卤化氢，优选氟化氢。

48. 发明授权

US3948761A Isomerization of aliphatic hydrocarbons 失效
标题翻译：脂肪族烃的异构化
公开(公告)号：US3948761A
公开(公告)日：1976-04-06
申请号：US445163
申请日：1974-02-25
申请人： Michael Siskin , Joseph J. Porcelli
发明人： Michael Siskin , Joseph J. Porcelli
IPC分类号： B01J27/08 , C07C5/27 , C07C5/28 , C10G35/06
CPC分类号： C07C5/2721 , B01J27/08 , C07C2527/08 , C07C2527/10 , C07C2527/11 , C07C2527/12 , C07C2527/1206 , C07C2527/125 , C07C2527/126 , C07C2527/132 , C07C2527/133 , C07C2527/135
摘要： Acyclic and alicyclic aliphatic hydrocarbons are isomerized by contacting the same with hydrogen in the presence of a difficultly reduceable metal halide in combination with at least a molar equivalent of hydrogen halide. The preferred catalyst system is tantalum pentafluoride, niobium pentafluoride or their mixtures in combination with at least a five-fold molar excess of hydrogen fluoride.
摘要翻译：通过在难以还原的金属卤化物与至少一摩尔当量的卤化氢的组合的存在下使其与氢接触来使非环和脂环族脂族烃异构化。优选的催化剂体系是五氟化钽，五氟化铌或其混合物与至少五倍摩尔过量的氟化氢的组合。

49. 发明授权

US09376756B2 Inhibition of corrosion in boiler systems with etheramines 有权
标题翻译：用醚胺抑制锅炉系统的腐蚀
公开(公告)号：US09376756B2
公开(公告)日：2016-06-28
申请号：US14285686
申请日：2014-05-23
申请人： Michael Siskin , Robert Basil Fedich , Michel A. Daage
发明人： Michael Siskin , Robert Basil Fedich , Michel A. Daage
IPC分类号： C23F11/14 , F22B1/00 , F22B37/02
CPC分类号： C23F11/146 , C23F11/141 , F22B1/00 , F22B37/025
摘要： Aminoethers are used as corrosion inhibitors in boiler systems in which a working fluid comprising water with an aminoether corrosion inhibitor is circulated from a heater to a utilization site at which the working fluid gives up energy and decreases in temperature. A preferred class of aminoethers are the alkoxytriethyleneglycol-tert-alkylamines such as methoxy triethyleneglycol-tert-butylamine.
摘要翻译：氨基醚用作锅炉系统中的腐蚀抑制剂，其中包含水与氨基醚腐蚀抑制剂的工作流体从加热器循环到工作流体释放能量并降低温度的使用场所。优选的氨基醚类是烷氧基三乙二醇 - 叔烷基胺，例如甲氧基三乙二醇 - 叔丁胺。

50. 发明申请

US20160038872A1 NON-AQUEOUS AMINE SCRUBBING FOR REMOVAL OF CARBON DIOXIDE 有权
标题翻译：用于去除二氧化碳的非水性氨洗涤剂
公开(公告)号：US20160038872A1
公开(公告)日：2016-02-11
申请号：US14885214
申请日：2015-10-16
申请人： David Charles CALABRO , Lisa Saunders Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis George Peiffer , Quanchang Li
发明人： David Charles CALABRO , Lisa Saunders Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis George Peiffer , Quanchang Li
IPC分类号： B01D53/14
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.
摘要翻译：描述了一种从混合气流中分离CO 2和/或H 2 S的方法，其通过使气流与初级和/或仲脂族胺的非水性液体吸收介质接触，优选非水性，极性，非质子溶剂在足以吸附至少一些CO 2的条件下进行。然后可以处理含有吸收的CO 2的溶液以解吸酸性气体。该方法通常作为连续循环吸附 - 脱附方法运行，吸附在吸附区中进行，其中液体吸收剂的循环流与气体流接触以形成富CO 2的吸附溶液，然后循环至用于解吸CO 2的再生区（有利地<100℃）。在释放CO 2时，再生的贫溶液可以再循环到吸附塔。 CO 2：（初级+仲胺）吸附摩尔比> 0.5:1（接近1：1）。

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