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    • 41. 发明授权
    • Golf ball
    • 高尔夫球
    • US07723427B2
    • 2010-05-25
    • US12196547
    • 2008-08-22
    • Hiroshi HiguchiNobuyuki KataokaAtsushi NanbaHiroto Sasaki
    • Hiroshi HiguchiNobuyuki KataokaAtsushi NanbaHiroto Sasaki
    • A63B37/00C08L9/00
    • C08L9/00A63B37/0003A63B37/0051C08K5/098C08K5/14C08L2666/08
    • A golf ball which is formed from a vulcanized rubber compound composed of 100 parts by weight of a rubber base material, 10 to 60 parts by weight of an unsaturated carboxylic acid and/or a metal salt thereof, 0.1 to 5 parts by weight of an organosulfur compound, 5 to 80 parts by weight of an inorganic filler, and 0.1 to 3 parts by weight of an organic peroxide, the rubber base material being composed of a first polybutadiene accounting for 50 to 95 wt % and a second polybutadiene accounting for 5 to 50 wt %, both polybutadiene being synthesized by using a rare earth element-based catalyst, the first polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) no lower than 50 and the second polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+, (100° C.)) no higher than 45. The golf ball is characterized by good rebound resilience and good workability with which it is produced.
    • 由由100重量份的橡胶基材,10〜60重量份的不饱和羧酸和/或其金属盐组成的硫化橡胶混合物形成的高尔夫球,0.1〜5重量份的 有机硫化合物,5〜80重量份的无机填充剂和0.1〜3重量份的有机过氧化物,所述橡胶基材由第一聚丁二烯占50〜95重量%,第二聚丁二烯占5重量份 至50重量%,通过使用稀土元素系催化剂合成聚丁二烯,第一聚丁二烯含有不小于60重量%的顺式-1,4键,门尼粘度(ML1 + 4(100℃) ))不低于50,第二聚丁二烯含有不小于60重量%的顺式-1,4键,门尼粘度(ML1 +,(100℃))不高于45.高尔夫球的特征在于 良好的反弹弹性和良好的可加工性。
    • 43. 发明授权
    • Method for shaping semisolid metals
    • 半固态金属成型方法
    • US07121320B2
    • 2006-10-17
    • US11008749
    • 2004-12-09
    • Mitsuru AdachiHiroto SasakiYasunori HaradaTatsuo SakamotoSatoru Sato
    • Mitsuru AdachiHiroto SasakiYasunori HaradaTatsuo SakamotoSatoru Sato
    • B22D27/04
    • C22C1/005B22D17/007Y10S164/90
    • A method of shaping a semisolid metal comprising pouring a molten aluminum or magnesium alloy which contains a crystal grain refiner and which is superheated to less than 50° C. above a liquidus temperature of aluminum or magnesium, directly into a vessel without using a cooling jig, maintaining the alloy in the vessel for 30 seconds to 30 minutes as a resultant melt is cooled to a temperature where a specified liquid fraction is established such that a temperature of the poured alloy which is liquid and superheated to less than 10° C. above the liquidus temperature or which is partially solid, partially liquid and at a temperature of less than 5° C. below the liquidus temperature decreases from an initial level and passes through a temperature zone 5° C. below the liquidus temperature within at least 10 minutes, whereby fine primary crystals are generated in the alloy, recovering the alloy from the vessel, supplying the alloy into a mold, and shaping the alloy under pressure.
    • 一种成形半固体金属的方法,包括将含有晶粒细化剂的熔融铝或镁合金浇注,并将其过热至低于铝或镁的液相线温度以上的50℃以上,而不使用冷却夹具 ,将合金保持在容器中30秒至30分钟,将所得熔体冷却至指定液体分数建立的温度,使得液态并过热至低于10℃的浇注合金的温度高于 液相线温度或部分固体,部分液体,低于液相温度的温度低于5℃,从初始水平降低,并在至少10分钟内通过低于液相线温度5℃的温度区域 从而在合金中产生细的一次晶体,从容器中回收合金,将合金供给到模具中,并在压力下成形合金。
    • 44. 发明申请
    • Golf ball
    • 高尔夫球
    • US20060047082A1
    • 2006-03-02
    • US10929557
    • 2004-08-31
    • Hiroshi HiguchiAtsushi NanbaNobuyuki KataokaHiroto Sasaki
    • Hiroshi HiguchiAtsushi NanbaNobuyuki KataokaHiroto Sasaki
    • C08L23/00A63B37/00A63B37/12
    • A63B37/06A63B37/0003A63B37/0065C08K5/098C08K5/14C08L9/00C08L2666/08
    • A golf ball which is formed from a crosslinked rubber compound composed of, as essential components, (A) a rubber base material composed of (a) a polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) of 50 to 120, which is synthesized by using a group VIII catalyst element and/or a rare earth element-based catalyst, and (b) a solid isoprene rubber containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) of 70 to 90, with the ratio of (a) to (b) being from 96/4 to 99/1 by weight; (B) an unsaturated carboxylic acid and/or a metal salt thereof; and ((C) an organic peroxide. The golf ball is characterized by good rebound resilience and good workability with which it is produced.
    • 由(A)由(a)含有不少于60重量%的顺式-1,4键的聚丁二烯和具有门尼的(A)组成的橡胶基材组成的交联橡胶化合物形成的高尔夫球 通过使用VIII族催化剂元素和/或稀土元素类催化剂合成的粘度(ML 1 + 4(100℃))为50〜120,(b) 含有不小于60重量%的顺式-1,4键并且门尼粘度(ML 1 + 4(100℃))为70至90的固体异戊二烯橡胶,其比例 (a)至(b)的重量比为96/4至99/1; (B)不饱和羧酸和/或其金属盐; 和((C)有机过氧化物,高尔夫球的特点是具有良好的回弹性和良好的加工性能。
    • 49. 发明授权
    • Method and apparatus for shaping semisolid metals
    • 半固态金属成型方法和装置
    • US06851466B2
    • 2005-02-08
    • US10852952
    • 2004-05-24
    • Mitsuru AdachiHiroto SasakiYasunori HaradaTatsuo SakamotoSatoru Sato
    • Mitsuru AdachiHiroto SasakiYasunori HaradaTatsuo SakamotoSatoru Sato
    • B22D17/00C22C1/00B22D27/08
    • C22C1/005B22D17/007Y10S164/90
    • A method of shaping a semisolid metal to provide shaped parts which are produced in a convenient, easy and inexpensive manner, without relying upon the conventional mechanical or electromagnetic agitation. The method includes feeding, without using a cooling jig, into an insulating vessel, a molten alloy containing an element for promoting generation of crystal nuclei and being held to be superheated to less than 100° C. above a liquidus temperature of the alloy; maintaining the molten alloy in the insulating vessel for 5 seconds to 60 minutes as the alloy is cooled at a cooling rate of 0.01° C./s to 3.0° C./s thereby crystallizing fine primary spherical crystals in an alloy solution containing a specified liquid fraction; and feeding the alloy solution into a forming mold for shaping the alloy under pressure.
    • 一种使半固体金属成形以提供成形部件的方法,所述成形部件以方便,容易和便宜的方式制造,而不依赖于传统的机械或电磁搅拌。 该方法包括:在不使用冷却夹具的情况下,将绝缘容器,含有促进晶核产生的元素的熔融合金进料并保持过热至低于合金的液相线温度以下的100℃以下; 将熔融合金保持在绝缘容器中5秒至60分钟,因为合金以0.01℃/ s至3.0℃/ s的冷却速率冷却,从而使含有规定的合金溶液的合金溶液中的细小的初级球形晶体结晶 液体馏分 并将合金溶液进料到用于在压力下成形合金的成型模具中。