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41. 发明授权

US07452932B2 Highly stable polymer dispersions and method for the production thereof 有权
标题翻译：高度稳定的聚合物分散体及其制备方法
公开(公告)号：US07452932B2
公开(公告)日：2008-11-18
申请号：US10526435
申请日：2003-08-27
申请人： Markus Scherer , Alexander Dardin , Wolfgang Tschepat , Stephan Massoth
发明人： Markus Scherer , Alexander Dardin , Wolfgang Tschepat , Stephan Massoth
IPC分类号： C08K5/10 , C08K5/06
CPC分类号： C10M169/044 , C10M2203/1006 , C10M2205/02 , C10M2205/022 , C10M2205/024 , C10M2205/04 , C10M2205/06 , C10M2207/046 , C10M2209/084 , C10M2209/104 , C10M2209/108 , C10N2230/02 , C10N2250/12
摘要： The present invention relates to a polymer dispersion having high stability, comprising A) at least one dispersed polyolefin, B) at least one dispersing component, C) mineral oil and D) at least one compound comprising (oligo)oxyalkyl groups.
摘要翻译：本发明涉及具有高稳定性的聚合物分散体，其包含A）至少一种分散的聚烯烃，B）至少一种分散组分，C）矿物油和D）至少一种包含（低聚）烷氧基的化合物。

42. 发明申请

US20050283027A1 Process for the synthesis of cycloorganylphosphanes and di (alkyli metal/alkaline earth metal)oligophosphanediides 有权
标题翻译：合成环亚烷基磷烷和二（烷基金属/碱土金属）低聚二氧化膦的方法
公开(公告)号：US20050283027A1
公开(公告)日：2005-12-22
申请号：US10535372
申请日：2003-11-24
申请人： Hansjorg Grutzmacher , Jens Geier , Hartmut Schonberg , Markus Scherer , Daniel Stein , Souad Boulmaaz
发明人： Hansjorg Grutzmacher , Jens Geier , Hartmut Schonberg , Markus Scherer , Daniel Stein , Souad Boulmaaz
IPC分类号： C07F9/6564 , C07F9/6568 , C07F9/6596 , C07F9/547
CPC分类号： C07F9/6568 , C07F9/6596
摘要： The invention relates to a process for the preparation of cycloorganylphosphanes of formula 1 (R1P)n by reaction of dihalo(organyl)phosphanes of formula R1PHaI2 with: a) activated zinc in an organic solvent, or with: b) an alkali metal or alkaline earth metal in a non-polar organic solvent in the presence of an activator, wherein R1 is C1-C12alkyl; C3-C12 cycloalkyl, aryl or heteroaryl, Hal is F, Cl, Br or I, and n is a number from 3 to 20. The invention relates also to novel di(alkali metal/alkaline earth metal) oligophosphanediides and to the use thereof in the preparation of organophosphorus compounds.
摘要翻译：本发明涉及通过式R 1的二卤代（有机基）磷烷的反应来制备式1的环氧基磷烷（R 1 P 1）n的方法，其中：a）在有机溶剂中活化的锌，或者在b）碱金属或碱土金属的非极性有机溶剂中，在活化剂存在下，其中 R 1是C 1 -C 12烷基; R 1是C 1 -C 12烷基; C 3 -C 12环烷基，芳基或杂芳基，Hal是F，Cl，Br或I，n是3至20的数。本发明还涉及新型二（碱金属/碱土金属）低聚二氧化膦及其在制备有机磷化合物中的应用。

43. 发明申请

US20050261143A1 Highly stable polymer dispersions and method for the production thereof 有权
标题翻译：高度稳定的聚合物分散体及其制备方法
公开(公告)号：US20050261143A1
公开(公告)日：2005-11-24
申请号：US10526435
申请日：2003-08-27
申请人： Markus Scherer , Alexander Dardin , Wolfgang Tschepat , Stephan Massoth
发明人： Markus Scherer , Alexander Dardin , Wolfgang Tschepat , Stephan Massoth
IPC分类号： C10M169/04 , C10M101/00
CPC分类号： C10M169/044 , C10M2203/1006 , C10M2205/02 , C10M2205/022 , C10M2205/024 , C10M2205/04 , C10M2205/06 , C10M2207/046 , C10M2209/084 , C10M2209/104 , C10M2209/108 , C10N2230/02 , C10N2250/12
摘要： The present invention relates to a polymer dispersion having high stability, comprising A) at least one dispersed polyolefin, B) at least one dispersing component, C) mineral oil and D) at least one compound comprising (oligo)oxyalkyl groups.
摘要翻译：本发明涉及具有高稳定性的聚合物分散体，其包含A）至少一种分散的聚烯烃，B）至少一种分散组分，C）矿物油和D）至少一种包含（低聚）烷氧基的化合物。

44. 发明申请

US20050148749A1 Copolymers as dewaxing additives 有权
标题翻译：共聚物作为脱蜡添加剂
公开(公告)号：US20050148749A1
公开(公告)日：2005-07-07
申请号：US10505370
申请日：2003-02-14
申请人： Markus Scherer , Michael Mueller , Jean-Luc Herbeaux , Dieter Janssen , Melanie Croessmann
发明人： Markus Scherer , Michael Mueller , Jean-Luc Herbeaux , Dieter Janssen , Melanie Croessmann
IPC分类号： B01D11/04 , C08F212/02 , C08F220/18 , C08F226/06 , C10G73/04 , C10G73/06 , C08F118/02
CPC分类号： C08F220/18 , C08L33/08 , C10G73/08 , C08F2220/1891 , C08F212/08 , C08F220/30 , C08F2220/1825
摘要： The invention relates to copolymers which are suitable for producing additives for solvent deparaffination of paraffin-containing mineral oil distillates and which consist of radically polymerized monomers of formulas A and B, wherein the radicals have the meaning cited in the description. The invention also relates to the use of said copolymers for the production of dewaxing additives.
摘要翻译：本发明涉及适用于制备用于溶剂脱蜡的含石蜡矿物油馏分的添加剂的共聚物，其由式A和B的自由基聚合单体组成，其中基团具有本说明书引用的含义。本发明还涉及所述共聚物用于生产脱蜡添加剂的用途。

45. 发明授权

US06639029B1 Process for continuous synthesis of polymer compositions as well as use of same 有权
标题翻译：连续合成聚合物组合物的方法及其用途
公开(公告)号：US06639029B1
公开(公告)日：2003-10-28
申请号：US09709354
申请日：2000-11-13
申请人： Markus Scherer , Joseph Martin Bollinger , David J. Cooper, Jr. , Larry Stephen Tillery , Robert Woodruff
发明人： Markus Scherer , Joseph Martin Bollinger , David J. Cooper, Jr. , Larry Stephen Tillery , Robert Woodruff
IPC分类号： C08F472
CPC分类号： C08F4/00
摘要： The present invention relates to a process for synthesis of polymer compositions, wherein ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable atom or group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, the process being characterized in that the polymerization takes place by means of continuous process operation.
摘要翻译：本发明涉及一种合成聚合物组合物的方法，其中烯属不饱和单体通过含有可转移原子或原子团的引发剂和一种或多种包含至少一种过渡金属的催化剂在配体存在下聚合，所述配体可以与金属催化剂或催化剂形成配位化合物，其特征在于聚合是通过连续工艺操作进行的。

46. 发明授权

US06610801B1 Processes for synthesis of polymer compositions 有权
标题翻译：聚合物组合物的合成方法及其用途
公开(公告)号：US06610801B1
公开(公告)日：2003-08-26
申请号：US09709531
申请日：2000-11-13
申请人： Markus Scherer
发明人： Markus Scherer
IPC分类号： C08F406
CPC分类号： C08F20/12
摘要： The present invention relates to processes for synthesis of poly(meth)acrylate compositions, wherein ethylenically unsaturated monomers are transformed to polymers by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, wherein ethylenically unsaturated monomers containing 50 to 100 wt %, relative to the total weight of ethylenically unsaturated monomers, of (meth)acrylates of formula (I) are polymerized wherein R denotes hydrogen or methyl, R1 denotes a straight-chain or branched alkyl group with 8 to 40, carbon atoms, R2 and R3 independently denote hydrogen or a group of the formula —COOR1, wherein R′ denotes hydrogen or a straight-chain or branched alkyl group with 8 to 40, carbon atoms, in the presence of copper, the total concentration of copper of oxidation numbers (I) and (II) in the polymerization composition being ≦200 ppm relative to the total weight of the composition.
摘要翻译：本发明涉及合成聚（甲基）丙烯酸酯组合物的方法，其中烯属不饱和单体通过含有可转移原子基团的引发剂和包含至少一种过渡金属的一种或多种催化剂在存在下转化成聚合物可以与金属催化剂或催化剂形成配位化合物的配体，其中相对于烯属不饱和单体的总重量为50-100重量％的式（I）的（甲基）丙烯酸酯的烯属不饱和单体是聚合的，其中R表示氢或甲基，R 1表示具有8至40个碳原子的直链或支链烷基，R 2和R 3独立地表示氢或式-COOR 1的基团，其中R'表示氢或直链或支链烷基具有8至40个碳原子，在铜的存在下，聚合共聚物中氧化数（I）和（II）的铜的总浓度相对于组合物的总重量，调整为<= 200ppm。

47. 发明授权

US06403746B1 Method for preparation of a composition that contains polymer ester compounds with long-chain alkyl residues and use of this composition 有权
标题翻译：制备包含具有长链烷基残基的聚合物酯化合物并使用该组合物的组合物的方法
公开(公告)号：US06403746B1
公开(公告)日：2002-06-11
申请号：US09450746
申请日：1999-11-30
申请人： Sebastian Roos , Joseph Martin Bollinger , Markus Scherer , Boris Eisenberg
发明人： Sebastian Roos , Joseph Martin Bollinger , Markus Scherer , Boris Eisenberg
IPC分类号： C08F11802
CPC分类号： C10M145/14 , C08F4/10 , C08F20/12 , C08F20/18 , C08F2220/1891 , C10M145/16 , C10M149/06 , C10M2209/084 , C10M2209/086 , C08F220/14
摘要： This invention concerns a method for preparation of poly(meth)acrylate composition, in which ethylenically unsaturated monomers are polymerized by means of initiators that have a transferable atomic group, and one or more catalysts that include at least one transition metal, in the presence of ligands that can form a coordination compound with the metallic catalyst(s) to form polymers, where ethylenically unsaturated monomers that contain 50-100 wt %, with respect to the total weight of the ethylenically unsaturated monomers, (meth)acrylates of formula (I) where R means hydrogen or methyl, R1 means a linear or branched alkyl residue with 6-40 carbon atoms, R2 and R3 independently mean hydrogen or a group of the formula—COOR′, where R′ is hydrogen or a linear or branched alkyl residue with 6-40 carbon atoms, is polymerized in the presence of 5-95 wt % mineral oil, with respect to the total weight of the composition.
摘要翻译：本发明涉及一种制备聚（甲基）丙烯酸酯组合物的方法，其中烯属不饱和单体通过具有可转移原子团的引发剂聚合，以及一种或多种包含至少一种过渡金属的催化剂，在存在可以与金属催化剂形成配位化合物以形成聚合物的配体，其中相对于烯属不饱和单体的总重量为50-100重量％的烯属不饱和单体，式（I）的（甲基）丙烯酸酯）其中R表示氢或甲基，R1表示具有6-40个碳原子的直链或支链烷基，R2和R3独立地表示氢或式-COOR'的基团，其中R'是氢或直链或支链烷基相对于组合物的总重量，在5-95重量％的矿物油的存在下聚合具有6-40个碳原子的残基。

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