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41. 发明授权

US06833470B2 Method for producing formylphenylboronic acids 有权
公开(公告)号：US06833470B2
公开(公告)日：2004-12-21
申请号：US10433827
申请日：2003-06-05
申请人： Andreas Meudt , Stefan Scherer , Frank Vollmueller , Michael Erbes
发明人： Andreas Meudt , Stefan Scherer , Frank Vollmueller , Michael Erbes
IPC分类号： C07F502
CPC分类号： C07F5/025
摘要： A process for preparing formylphenylboronic acids of the formula (I) by reaction of protected chlorobenzaldehydes of the formula (II) with lithium in an inert solvent to form compounds of the formula (III) and subsequent reaction with a boron compound of the formula BY3 to give compounds of the formula (I).

42. 发明授权

US06566546B2 Process for preparing 4-substituted 2-alkylbiphenyls and 2-alkoxylbiphenyls 失效
标题翻译：制备4-取代的2-烷基联苯和2-烷氧基联苯的方法
公开(公告)号：US06566546B2
公开(公告)日：2003-05-20
申请号：US10073568
申请日：2002-02-11
申请人： Andreas Meudt , Stefan Scherer , Frank Vollmüller , Heinz Georg Kautz
发明人： Andreas Meudt , Stefan Scherer , Frank Vollmüller , Heinz Georg Kautz
IPC分类号： C07C25300
CPC分类号： C07C253/00 , C07B37/04 , C07C17/093 , C07C209/62 , C07C209/68 , C07C231/14 , C07C25/18 , C07C211/45 , C07C233/07 , C07C255/50
摘要： A process for preparing 4-substituted 2-alkylbiphenyls and 2-alkoxybiphenyls of the formula (I),
摘要翻译：制备式（I）的4-取代的2-烷基联苯和2-烷氧基联苯的方法，

43. 发明授权

US06420597B2 Process for preparing highly pure formylphenylboronic acids 失效
标题翻译：制备高纯度甲酰基苯基硼酸的方法
公开(公告)号：US06420597B2
公开(公告)日：2002-07-16
申请号：US09897566
申请日：2001-07-02
申请人： Frank Vollmüller , Andreas Meudt , Stefan Scherer
发明人： Frank Vollmüller , Andreas Meudt , Stefan Scherer
IPC分类号： C07F502
CPC分类号： C07F5/025
摘要： A process for purifying formylphenylboronic acids of the formula (I) where the formyl function is located in the ortho, meta or para position relative to the boronic acid function, by dissolving the crude formylphenylboronic acids in an alkaline solvent having a pH in the range from 8 to 11 separating off the insoluble organic impurities and subsequently acidifying the alkaline boronic acid solution and separating off and working up the precipitated boronic acid. The crude formylphenylboronic acid is preferably dissolved in aqueous alkali metal or alkaline earth metal oxide, hydroxide, carbonate or phosphate solutions at temperatures in the range from 5 to 50° C. The formylphenylboronic acids obtained have a purity of ≧99% and are suitable as precursors for liquid-crystalline compounds, as liquid crystals or as constituents of liquid-crystalline mixtures or as pharmaceutical intermediates.
摘要翻译：通过将粗甲酰基苯基硼酸溶解在碱性溶剂中，其中pH为在下列范围内，其中甲酰基官能位于相对于硼酸官能团的邻位，间位或对位的式（I）的甲酰基苯基硼酸的方法分离出不溶性有机杂质，然后酸化碱性硼酸溶液，分离和处理沉淀的硼酸。粗甲酰基苯基硼酸优选在5至50℃的温度范围内溶解在碱金属或碱土金属氧化物，氢氧化物，碳酸盐或磷酸盐水溶液中。得到的甲酰基苯基硼酸的纯度> 99％，适用作为液晶化合物的前体，作为液晶或作为液晶混合物的组分或作为药物中间体。

44. 发明授权

US06392051B2 Process for preparing 4-(4′-carboxyphenyl)pyridine 失效
标题翻译：制备4-（4'-羧基苯基）吡啶的方法
公开(公告)号：US06392051B2
公开(公告)日：2002-05-21
申请号：US09784535
申请日：2001-02-15
申请人： Andreas Meudt , Stefan Scherer , Peter Koch , Gerhard Demmer , Frank Vollmüller
发明人： Andreas Meudt , Stefan Scherer , Peter Koch , Gerhard Demmer , Frank Vollmüller
IPC分类号： C07D21170
CPC分类号： C07D211/82 , C07D213/55
摘要： The invention relates to a process for preparing 4-(4′-carboxyphenyl)pyridine, which comprises oxidizing a 4-phenyl-N-acyldihydropyridine of the formula (II) where R1 is a bulky alkyl, alkylaryl, arylalkyl or alkoxy group and R2 is a straight-chain or branched, substituted or unsubstituted alkyl radical having from 1 to 8 carbon atoms, by means of an oxidizing agent selected from the group consisting of permanganates, nitric acid, Cr(VI) compounds, oxygen and air to give the compound of the formula (I) where M is a cation.
摘要翻译：本发明涉及一种制备4-（4'-羧基苯基）吡啶的方法，其包括将式（II）的4-苯基-N-酰基二氢吡啶氧化为其中R1是大体积烷基，烷基芳基，芳烷基或烷氧基，R2是直链或支链的，取代或未取代的具有1至8个碳原子的烷基，通过选自高锰酸盐，硝酸，Cr（VI）化合物，氧气和空气的氧化剂，得到式（I）其中M是阳离子。

45. 发明授权

US06392047B1 Process for preparing biaryls in the presence of palladophosphacyclobutane catalysts 失效
标题翻译：在存在palladophosphacloblobane催化剂的情况下制备联芳基的方法
公开(公告)号：US06392047B1
公开(公告)日：2002-05-21
申请号：US09615486
申请日：2000-07-13
申请人： Holger Geissler , Steffen Haber , Andreas Meudt , Frank Vollmueller , Stefan Scherer
发明人： Holger Geissler , Steffen Haber , Andreas Meudt , Frank Vollmueller , Stefan Scherer
IPC分类号： C07D40104
CPC分类号： C07D307/79 , B01J31/1845 , B01J31/24 , B01J31/2404 , B01J31/28 , B01J2231/4211 , B01J2531/824 , C07C17/263 , C07C25/18
摘要： Biaryls, e,g,. biphenyls, phenylpyridines, phenylfurans, phenylpyrroles, phenylthiophenes, bipyridines, pyridylfurans or pyridylpyrroles are prepared in high yields by coupling aromatics with an aromatic boric acid or boric ester in the presence of a palladaphosphacyclobutane catalyst.
摘要翻译：双芳烃，e，g，联苯，苯基吡啶，苯基呋喃，苯基吡咯，苯基噻吩，联吡啶，吡啶基呋喃或吡啶基吡咯通过偶联芳烃与芳族硼酸或硼酸酯在缓冲磷脂环丁烷催化剂存在下偶联而得到。

46. 发明授权

US06353136B1 Process for preparing aromatic amines in the presence of palladaphosphacyclobutane catalysts 失效
标题翻译：在缓冲磷酸环丁烷催化剂存在下制备芳香胺的方法
公开(公告)号：US06353136B1
公开(公告)日：2002-03-05
申请号：US09658830
申请日：2000-09-08
申请人： Holger Geissler , Steffen Haber , Stefan Scherer , Andreas Meudt , Frank Vollmueller
发明人： Holger Geissler , Steffen Haber , Stefan Scherer , Andreas Meudt , Frank Vollmueller
IPC分类号： C07C21100
CPC分类号： C07D231/12 , C07C209/08 , C07C209/10 , C07D209/08 , C07D209/10 , C07D233/56 , C07D249/08 , C07D307/66
摘要： Aromatic amines of the formula (I) Ar—[NR6R7]n (I) are prepared by reacting a haloaromatic of the formula (II) Ar—Hal (II) with an amine of the formula (III) R6R7NH (III) in the presence of a palladaphosphacyclobutane and a base and in the presence or absence of an ionic halide in a solvent at temperatures of from 20 to 200° C.
摘要翻译：式（I）的芳族胺通过式（II）的卤代芳族化合物与式（III）的胺在缓冲磷酸环丁烷和碱的存在下反应，并且在存在或不存在离子型卤化物的情况下溶剂，温度为20〜200℃

47. 发明授权

US6066766A Process for the preparation of 4-chlorobiphenyls 失效
标题翻译： 4-氯联苯的制备方法
公开(公告)号：US6066766A
公开(公告)日：2000-05-23
申请号：US366470
申请日：1999-08-03
申请人： Steffen Haber , Stefan Scherer , Andreas Meudt , Antje Noerenberg
发明人： Steffen Haber , Stefan Scherer , Andreas Meudt , Antje Noerenberg
IPC分类号： B01J31/24 , C07B49/00 , C07B61/00 , C07C17/26 , C07C17/263 , C07C25/18 , C07F7/12 , C07C43/02 , C07C22/00 , C07F7/04
CPC分类号： C07C17/263 , C07C17/2632
摘要： 4-Chlorobiphenyls are prepared by reacting a haloaromatic with an aryl Grignard compound, where halogen is chlorine, bromine or iodine, in the presence of a palladium catalyst of the formula (IV) ##STR1##
摘要翻译：通过卤代芳基与芳基格氏化合物（其中卤素是氯，溴或碘）在式（IV）的钯催化剂存在下反应制备4-氯联苯，

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