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    • 45. 发明授权
    • Process of and apparatus for heat-treating II-VI compound semiconductors and semiconductor heat-treated by the process
    • 用于热处理II-VI化合物半导体的工艺和设备,以及通过该工艺热处理的半导体
    • US06881658B2
    • 2005-04-19
    • US10243198
    • 2002-09-13
    • Yasuo Namikawa
    • Yasuo Namikawa
    • H01L29/221C30B31/10C30B33/00H01L21/22H01L21/225H01L21/324H01L21/385H01L21/477H01L33/28H01L21/28
    • H01L21/385C30B29/48C30B33/00H01L33/0095H01L33/28
    • A process of heat-treating II-VI compound semiconductors reduces the electrical resistivity without the decrease in crystallinity resulting from the increase in dislocation density. The process comprises the following steps:(a) placing at least one II-VI compound semiconductor in contact with aluminum in a heat-treating chamber having the inside surface formed by at least one material selected from the group consisting of pyrolytic born nitride, hexagonal-system boron nitride, sapphire, alumina, aluminum nitride, and polycrystalline diamond; and (b) heat-treating the II-VI compound semiconductor or semiconductors in a gaseous atmosphere containing the group II element constituting part of the II-VI compound semiconductor or semiconductors. A II-VI compound semiconductor is heat-treated by the foregoing process. An apparatus for heat-treating II-VI compound semiconductors comprises components for performing the foregoing process.
    • 一种热处理II-VI化合物半导体的方法降低了电阻率,而不会由于位错密度的增加而导致结晶度的降低。 该方法包括以下步骤:(a)将至少一种与铝接触的II-VI化合物半导体放置在热处理室中,所述热处理室具有由至少一种选自热解出的氮化物,六方晶系的材料形成的内表面 系统氮化硼,蓝宝石,氧化铝,氮化铝和多晶金刚石; 和(b)在构成II-VI族化合物半导体或半导体的一部分的II族元素的气氛气氛中热处理II-VI族化合物半导体或半导体。 通过上述方法对II-VI化合物半导体进行热处理。 用于热处理II-VI化合物半导体的装置包括用于执行上述方法的组分。
    • 46. 发明授权
    • Crystal manufacturing apparatus
    • 水晶制造装置
    • US5846323A
    • 1998-12-08
    • US725939
    • 1996-10-08
    • Masahiro EgamiYuh ShioharaYasuo Namikawa
    • Masahiro EgamiYuh ShioharaYasuo Namikawa
    • C30B15/00C30B15/26C30B29/22C30B35/00
    • C30B29/22C30B15/26Y10T117/1032Y10T117/1068Y10T117/1088
    • A crystal pulling apparatus is designed to generate a thermal gradient across the melt surface to prevent nucleation of stray crystals and production of floating debris to produce a high quality crystal, and has special provisions for observing the growth behavior and crystal dimension measurements. The apparatus includes a cylindrical chamber, a crucible disposed centrally within the chamber, a cylindrical heater surrounding the crucible, an insulation member disposed on the top section of the crucible, a first transparent plate and a second transparent plate for closing the center hole in the insulation member, a pull rod passing through the center hole of the transparent plates, a crystal illumination mechanism, a crystal size determination mechanism and an ambient atmosphere flowing mechanism. The crystal size determination mechanism is provided with a quartz prism, an infrared transmitting filter on a side wall of the chamber, a revolution count circuit, phase angle setting circuit, a CCD camera, an image processing section, and a crystal size determination device having a TV monitor.
    • 设计了一种晶体拉制装置,以在熔体表面上产生热梯度,以防止杂散晶体的成核和浮选碎屑的产生,产生高质量的晶体,并且具有观察生长行为和晶体尺寸测量的特殊规定。 该装置包括圆柱形腔室,设置在腔室中心的坩埚,围绕坩埚的圆柱形加热器,设置在坩埚顶部的绝缘构件,第一透明板和第二透明板,用于封闭坩埚中的中心孔 绝缘构件,穿过透明板的中心孔的拉杆,晶体照明机构,晶体尺寸确定机构和环境大气流动机构。 晶体尺寸确定机构设置有石英棱镜,在室的侧壁上的红外透射滤光器,转数计算电路,相位角设置电路,CCD照相机,图像处理部分和晶体尺寸确定装置,其具有 电视监视器。
    • 49. 发明授权
    • Method of retaining melt of oxide
    • 保留氧化物熔体的方法
    • US5632811A
    • 1997-05-27
    • US420519
    • 1995-04-12
    • Yasuo NamikawaYasuji YamadaSatoshi KoyamaYuh ShioharaShoji Tanaka
    • Yasuo NamikawaYasuji YamadaSatoshi KoyamaYuh ShioharaShoji Tanaka
    • C30B9/00C30B15/00C30B15/12C30B29/22H01B13/00H01L21/208C30B29/16
    • C30B29/225C30B15/12C30B9/00
    • In order to stably retain an oxide-based melt consisting essentially of yttrium or a lanthanoid element, barium, copper and oxygen at a prescribed temperature with no impurity contamination thereby preparing a large oxide crystal of high quality from the melt, an oxide melt consisting essentially of yttrium or a lanthanoid element, barium, copper and oxygen is stored in a first crucible, which in turn is held in a second crucible. The first crucible is made of a material which is an oxide of at least one element forming the melt having a melting point higher by at least 10.degree. C. than a melt retention temperature and causing no structural phase transition up to a temperature higher by 10.degree. C. than the aforementioned prescribed temperature, with solubility of not more than 5 atomic percent with respect to the melt in a temperature range from the room temperature to a temperature higher by 10.degree. C. than the melt retention temperature. The second crucible is made of a material substantially causing neither melting nor chemical reaction with respect to the oxide-based melt, which can retain the melt more stably than the first material. Even if the melt overflows the first crucible, this overflow is suppressed by the second crucible. It is possible to prepare a crystal of an oxide superconductor such as YBa.sub.2 Cu.sub.3 O.sub.7-x (0.ltoreq.X.ltoreq.1) by the pulling method from the melt which is stored in the first crucible.
    • 为了稳定地保持基本上由钇或镧系元素,钡,铜和氧组成的氧化物基熔体,在规定的温度下没有杂质污染,从而从熔体制备高质量的大的氧化物晶体,基本上由 的钇或镧系元素,钡,铜和氧储存在第一坩埚中,第一坩埚又保持在第二坩埚中。 第一坩埚由至少一种形成熔体的元素的氧化物的材料制成,其熔点比熔融保持温度高至少10℃,并且不会导致结构相变达到高于10℃的温度 ℃以上的规定温度,相对于熔体,在室温至高于熔融保持温度10℃的温度范围内的溶解度为5原子%以下。 第二坩埚由相对于基于氧化物的熔体基本上不熔化和化学反应的材料制成,其可以比第一材料更稳定地保持熔体。 即使熔体溢出第一坩埚,这种溢流被第二坩埚抑制。 可以通过从存储在第一坩埚中的熔体的拉伸方法制备氧化物超导体的晶体,例如YBa2Cu3O7-x(0≤X1)。