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    • 41. 发明申请
    • Plasma oxidation of a memory layer to form a blocking layer in non-volatile charge trap memory devices
    • 存储层的等离子体氧化在非挥发性电荷陷阱存储器件中形成阻挡层
    • US20090242962A1
    • 2009-10-01
    • US12080175
    • 2008-03-31
    • Krishnaswamy RamkumarSagy LevyJeong Byun
    • Krishnaswamy RamkumarSagy LevyJeong Byun
    • H01L21/28H01L29/423
    • H01L21/28282H01L29/4234H01L29/792
    • A blocking layer of a non-volatile charge trap memory device is formed by oxidizing a portion of a charge trapping layer of the memory device. In one embodiment, the blocking layer is grown by a radical oxidation process at temperature below 500° C. In accordance with one implementation, the radical oxidation process involves flowing hydrogen (H2) and oxygen (O2) gas mixture into a process chamber and exposing the substrate to a plasma. In a preferred embodiment, a high density plasma (HDP) chamber is employed to oxidize a portion of the charge trapping layer. In further embodiments, a portion of a silicon-rich silicon oxynitride charge trapping layer is consumptively oxidized to form the blocking layer and provide an increased memory window relative to oxidation of a nitrogen-rich silicon oxynitride layer.
    • 通过氧化存储器件的电荷俘获层的一部分来形成非易失性电荷陷阱存储器件的阻挡层。 在一个实施方案中,通过自由基氧化法在低于500℃的温度下生长阻挡层。根据一个实施方案,自由基氧化过程包括将氢(H 2)和氧(O 2)气体混合物流入处理室并暴露 衬底到等离子体。 在优选实施例中,使用高密度等离子体(HDP)室来氧化电荷俘获层的一部分。 在另外的实施例中,一部分富硅氧氮化硅电荷捕获层被消耗氧化以形成阻挡层,并且相对于富氮氧氮化硅层的氧化提供增加的存储窗口。
    • 47. 发明授权
    • Semiconductor topography including a thin oxide-nitride stack and method for making the same
    • 包括薄氧化物氮化物堆叠的半导体形貌及其制造方法
    • US07867918B1
    • 2011-01-11
    • US12046073
    • 2008-03-11
    • Krishnaswamy Ramkumar
    • Krishnaswamy Ramkumar
    • H01L21/31
    • H01L21/28282H01L21/02164H01L21/0217H01L21/022H01L21/02233H01L21/02271H01L21/28202H01L21/28273H01L21/3143H01L29/513H01L29/518
    • A semiconductor topography is provided which includes a silicon dioxide layer with a thickness equal to or less than approximately 10 angstroms and a silicon nitride layer arranged upon the silicon dioxide layer. In addition, a method is provided which includes growing an oxide film upon a semiconductor topography in the presence of an ozonated substance and depositing a silicon nitride film upon the oxide film. In some embodiments, the method may include growing the oxide film in a first chamber at a first temperature and transferring the semiconductor topography from the first chamber to a second chamber while the semiconductor topography is exposed to a substantially similar temperature as the first temperature. In either embodiment, the method may be used to form a semiconductor device including an oxide-nitride gate dielectric having an electrical equivalent oxide gate dieletric thickness of less than approximately 20 angstroms.
    • 提供半导体形貌,其包括厚度等于或小于约10埃的二氧化硅层和布置在二氧化硅层上的氮化硅层。 此外,提供了一种方法,其包括在存在臭氧化物质的情况下在半导体形貌上生长氧化膜并在氧化物膜上沉积氮化硅膜。 在一些实施例中,该方法可以包括在第一温度下在第一室中生长氧化膜并将半导体形貌从第一室转移到第二室,同时将半导体形貌暴露于与第一温度基本相似的温度。 在任一实施例中,该方法可用于形成半导体器件,其包括具有小于约20埃的电等效氧化物栅极薄膜厚度的氧化物 - 氮化物栅极电介质。
    • 50. 发明授权
    • SONOS structure including a deuterated oxide-silicon interface and method for making the same
    • SONOS结构包括氘代氧化硅界面及其制造方法
    • US07042054B1
    • 2006-05-09
    • US10740205
    • 2003-12-18
    • Krishnaswamy RamkumarFrederick B. Jenne
    • Krishnaswamy RamkumarFrederick B. Jenne
    • H01L29/76H01L29/94H01L31/062H01L31/113H01L31/119
    • H01L21/28176H01L21/28194H01L21/28202H01L21/28282H01L21/3003H01L29/513H01L29/518H01L29/792
    • A method for processing a semiconductor topography is provided, which includes diffusing deuterium across one or more interfaces of a silicon-oxide-nitride-oxide-silicon (SONOS) structure. In particular, the method may include diffusing deuterium across one or more interfaces of a SONOS structure during a reflow of a dielectric layer spaced above the SONOS structure. In some embodiments, the method may include forming a deutereated nitride layer above the SONOS structure prior to the reflow process. In addition or alternatively, the method may include forming a deutereated nitride layer within the SONOS structure prior to the reflow process. In some cases, the method may further include annealing the SONOS structure with a deutereated substance prior to forming the deutereated nitride layer. In either embodiment, a SONOS structure may be formed which includes deuterium arranged within an interface of a silicon layer and an oxide layer of the structure.
    • 提供了一种用于处理半导体形貌的方法,其包括在氧化硅 - 氮化物 - 氧化物 - 硅(SONOS)结构的一个或多个界面上扩散氘。 特别地,该方法可以包括在SONOS结构之间隔开的电介质层的回流期间扩散氘穿过SONOS结构的一个或多个界面。 在一些实施方案中,该方法可以包括在回流工艺之前在SONOS结构之上形成去氢化氮化物层。 另外或替代地,该方法可以包括在回流工艺之前在SONOS结构内形成一个去氢化氮化物层。 在一些情况下,该方法可以进一步包括在形成去氢化氮化物层之前用缺失的物质退火SONOS结构。 在任一实施例中,可以形成SONOS结构,其包括排列在硅层和该结构的氧化物层的界面内的氘。