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    • 41. 发明授权
    • Templated monolayer polymerization and replication
    • 模板单层聚合和复制
    • US07563482B2
    • 2009-07-21
    • US11963970
    • 2007-12-24
    • Joseph M. JacobsonDavid W. Mosley
    • Joseph M. JacobsonDavid W. Mosley
    • B05B3/00
    • H01L21/02112B05D1/185B82Y30/00B82Y40/00G01N31/22G03F7/165H01L21/283Y10S977/882Y10S977/883
    • A self-replicating monolayer system employing polymerization of monomers or nanoparticle ensembles on a defined template provides a method for synthesis of two-dimensional single molecule polymers. Systems of self-replicating monolayers are used as templates for growth of inorganic colloids. A preferred embodiment employs SAM-based replication, wherein an initial monolayer is patterned and used as a template for self-assembly of a second monolayer by molecular recognition. The second monolayer is polymerized in place and the monolayers are separated to form a replicate. Both may then function as templates for monolayer assemblies. A generic self-replicating monomer unit comprises a polymerizable moiety attached by methylene repeats to a recognition element and an ending unit that will not interfere with the chosen recognition chemistry. The recognition element is self-complementary, unless a set of two replicating monomers with compatible cross-linking chemistry is employed. In a two-component replication system utilizing two different kinds of recognition chemistries, the initial template undergoes replication cycles, while maintaining two-dimensional segregation of the two types of monomers. During subsequent replications, the component domains experience little or no mixing, allowing the two-component, patterned assembly to be exponentially replicated. After replication, selective mineralization and/or electroless plating may produce a two-dimensional inorganic sheet having patterned domains within it.
    • 使用单体或纳米颗粒聚合体在定义的模板上进行聚合的自复制单层体系提供了合成二维单分子聚合物的方法。 自复制单层系统用作无机胶体生长的模板。 优选的实施方案采用基于SAM的复制,其中初始单层被图案化并用作通过分子识别自组装第二单层的模板。 将第二单层聚合就位,并将单层分离形成复制物。 然后两者都可以作为单层组件的模板。 一般的自复制单体单元包括通过亚甲基重复序列连接到识别元件的可聚合部分和不会干扰所选择的识别化学物质的结束单元。 识别元件是自互补的,除非使用具有相容的交联化学的两组复制单体。 在使用两种不同类型的识别化学物质的双组分复制系统中,初始模板经历复制循环,同时保持两种类型的单体的二维分离。 在随后的复制过程中,组件域经历很少或不混合,允许双组分图案化组件以指数方式复制。 复制后,选择性矿化和/或化学镀可以产生其内具有图案区的二维无机片。
    • 48. 发明授权
    • Flexible displays
    • 柔性显示
    • US06639578B1
    • 2003-10-28
    • US09140879
    • 1998-08-27
    • Barrett ComiskeyJonathan D. AlbertJoseph M. JacobsonLibing ZhangAndrew LoxleyRobert FeeneyPaul Drzaic
    • Barrett ComiskeyJonathan D. AlbertJoseph M. JacobsonLibing ZhangAndrew LoxleyRobert FeeneyPaul Drzaic
    • G09G334
    • G02B26/026G02F1/133305G02F1/13336G02F1/167
    • A process for creating an electronically addressable display includes multiple printing operations, similar to a multi-color process in conventional screen printing. In some of the process steps, electrically non-active inks are printed onto areas of the receiving substrate, and in other steps, electrically active inks are printed onto different areas of the substrate. The printed display can be used in a variety of applications. This display can be used as an indicator by changing state of the display after a certain time has elapsed, or when a certain pressure, thermal, radiative, moisture, acoustic, inclination, pH, or other threshold is passed. In one embodiment, the display is incorporated into a battery indicator. A sticker display is described. The sticker is adhesive backed and may then be applied to a surface to create a functional information display unit. This invention also features a display that is both powered and controlled using radio frequencies. It describes a complete system for controlling, addressing, and powering a display. The system includes an antenna or antennae, passive charging circuitry, and active control system, a display, and an energy storage unit. There is also a separate transmitter that provides the remote power for the display. The system is meant to be used anywhere it is useful to provide intermittent updates of information such as in a store, on a highway, or in an airport. A tile-based display allowing a modular system for large area display is created using a printable display material.
    • 用于创建电子可寻址显示器的过程包括多个打印操作,类似于常规丝网印刷中的多色处理。 在一些工艺步骤中,将非活性油墨印刷到接收基材的区域上,而在其它步骤中,将电活性油墨印刷到基材的不同区域上。 印刷的显示器可用于各种应用。 该显示可以通过在经过一定时间之后改变显示状态,或当通过一定压力,热,辐射,湿度,声学,倾斜度,pH值或其他阈值时用作指示器。 在一个实施例中,显示器被并入电池指示器中。 描述了贴纸显示。 该贴纸是粘合剂背面的,然后可以施加到表面以形成功能信息显示单元。 本发明还具有使用无线电频率供电和控制的显示器。 它描述了一个用于控制,寻址和为显示器供电的完整系统。 该系统包括天线或天线,无源充电电路,主动控制系统,显示器和能量存储单元。 还有一个单独的发射器,为显示器提供远程电源。 该系统旨在用于提供信息的间歇性更新,例如在商店,高速公路或机场中的任何有用的位置。 使用可打印的显示材料创建允许用于大面积显示的模块化系统的基于瓦片的显示器。