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    • 2. 发明申请
    • Templated Monolayer Polymerization and Replication
    • 模板单层聚合和复制
    • US20130280920A1
    • 2013-10-24
    • US13919185
    • 2013-06-17
    • Joseph M. JacobsonDavid W. Mosley
    • Joseph M. JacobsonDavid W. Mosley
    • H01L21/02H01L21/283
    • H01L21/02112B05D1/185B82Y30/00B82Y40/00G01N31/22G03F7/165H01L21/283Y10S977/882Y10S977/883
    • A self-replicating monolayer system employing polymerization of monomers or nanoparticle ensembles on a defined template provides synthesis of two-dimensional single molecule polymers. Systems of self-replicating monolayers are used as templates for growth of inorganic colloids. A preferred embodiment employs SAM-based replication, wherein an initial monolayer is patterned and used as a template for self-assembly of a second monolayer by molecular recognition. The second monolayer is polymerized in place and the monolayers are separated to form a replicate. Both may then function as templates for monolayer assemblies. A generic self-replicating monomer unit comprises a polymerizable moiety attached by methylene repeats to a recognition element and an ending unit that will not interfere with the chosen recognition chemistry. The recognition element is self-complementary, unless two replicating monomers with compatible cross-linking chemistry are employed. After replication, selective mineralization and/or electroless plating may produce a two-dimensional inorganic sheet having patterned domains within it.
    • 使用单体或纳米颗粒合成体在定义的模板上进行聚合的自复制单层体系提供二维单分子聚合物的合成。 自复制单层系统用作无机胶体生长的模板。 优选的实施方案采用基于SAM的复制,其中初始单层被图案化并用作通过分子识别自组装第二单层的模板。 将第二单层聚合就位,并将单层分离形成复制物。 然后两者都可以作为单层组件的模板。 一般的自复制单体单元包括通过亚甲基重复序列连接到识别元件的可聚合部分和不会干扰所选择的识别化学物质的结束单元。 识别元件是自互补的,除非使用具有相容的交联化学的两种复制单体。 复制后,选择性矿化和/或化学镀可以产生其内具有图案区的二维无机片。
    • 3. 发明授权
    • Templated monolayer polymerization and replication
    • 模板单层聚合和复制
    • US08465803B2
    • 2013-06-18
    • US13556148
    • 2012-07-23
    • Joseph M. JacobsonDavid W. Mosley
    • Joseph M. JacobsonDavid W. Mosley
    • B05D3/00B05D1/18
    • H01L21/02112B05D1/185B82Y30/00B82Y40/00G01N31/22G03F7/165H01L21/283Y10S977/882Y10S977/883
    • A self-replicating monolayer system employing polymerization of monomers or nanoparticle ensembles on a defined template provides synthesis of two-dimensional single molecule polymers. Systems of self-replicating monolayers are used as templates for growth of inorganic colloids. A preferred embodiment employs SAM-based replication, wherein an initial monolayer is patterned and used as a template for self-assembly of a second monolayer by molecular recognition. The second monolayer is polymerized in place and the monolayers are separated to form a replicate. Both may then function as templates for monolayer assemblies. A generic self-replicating monomer unit comprises a polymerizable moiety attached by methylene repeats to a recognition element and an ending unit that will not interfere with the chosen recognition chemistry. The recognition element is self-complementary, unless two replicating monomers with compatible cross-linking chemistry are employed. After replication, selective mineralization and/or electroless plating may produce a two-dimensional inorganic sheet having patterned domains within it.
    • 使用单体或纳米颗粒合成体在定义的模板上进行聚合的自复制单层体系提供二维单分子聚合物的合成。 自复制单层系统用作无机胶体生长的模板。 优选的实施方案采用基于SAM的复制,其中初始单层被图案化并用作通过分子识别自组装第二单层的模板。 将第二单层聚合就位,并将单层分离形成复制物。 然后两者都可以作为单层组件的模板。 一般的自复制单体单元包括通过亚甲基重复序列连接到识别元件的可聚合部分和不会干扰所选择的识别化学物质的结束单元。 识别元件是自互补的,除非使用具有相容的交联化学的两种复制单体。 复制后,选择性矿化和/或化学镀可以产生其内具有图案区的二维无机片。
    • 5. 发明授权
    • Method of making a nanostructured electrode
    • 制造纳米结构电极的方法
    • US07858550B2
    • 2010-12-28
    • US11513434
    • 2006-08-25
    • Walter J. DressickCynthia N. KostelanskyTerence L. Schull
    • Walter J. DressickCynthia N. KostelanskyTerence L. Schull
    • H01M4/88H01M4/02H01M4/36H01M4/92B01J21/18B01J23/40B01J23/74B01J31/00
    • H01M4/8807H01M4/8817H01M4/8825H01M4/92H01M8/1007Y02P70/56Y10S977/882Y10S977/883
    • A method of making a nanostructured electrode comprising depositing a self-assembled monolayer on a substrate, depositing a catalyst nanoparticle covalently bonded to a ligand, and depositing a material capable of binding to the self-assembled monolayer. The method includes depositing on a conductive electrode substrate a catalytic nanoparticle stabilized by a covalently-bound ligand bearing a peripheral functional group and depositing a material capable of binding to the peripheral functional group, wherein the conductive electrode substrate is chemically modified to create a surface functional group capable of supporting multilayer deposition. The method can include covalent grafting of a functional group to create an initial layer of positive charge on the surface, depositing a platinum nanoparticle stabilized by negatively-charged ligands onto the functional group, and providing a polymer component. The ligand can have a peripheral functional group that has a charge opposite to or chemical reactivity amenable with that of the self-assembled monolayer. The material capable of binding to the peripheral functional group is such that successive layers of the catalytic nanoparticle within a multilayered system are bridged by the material. The material can be selected from semiconductors, RuO2, ITO, TiO2, surface oxidized carbon colloid, polyoxometalate, and metal ions.
    • 一种制造纳米结构电极的方法,包括在衬底上沉积自组装单层,沉积与配体共价键合的催化剂纳米颗粒,以及沉积能够结合自组装单层的材料。 该方法包括在导电电​​极基底上沉积通过带有外围官能团的共价结合配体稳定的催化纳米颗粒,并沉积能够结合外周官能团的材料,其中导电电极基底经化学修饰以产生表面功能 能够支持多层沉积的组。 该方法可以包括官能团的共价接枝以在表面上产生正电荷的初始层,将由负电荷的配体稳定的铂纳米颗粒沉积到官能团上,并提供聚合物组分。 配体可以具有与自组装单层的电荷相反或具有化学反应性的电荷的外围官能团。 能够结合周边官能团的材料使得多层系统内的催化纳米颗粒的连续层被材料桥接。 该材料可以选自半导体,RuO2,ITO,TiO2,表面氧化碳胶体,多金属氧酸盐和金属离子。
    • 7. 发明申请
    • Templated Monolayer Polymerization and Replication
    • 模板单层聚合和复制
    • US20090326269A1
    • 2009-12-31
    • US12505508
    • 2009-07-19
    • Joseph M. JacobsonDavid W. Mosley
    • Joseph M. JacobsonDavid W. Mosley
    • B05D1/38C07C55/00
    • H01L21/02112B05D1/185B82Y30/00B82Y40/00G01N31/22G03F7/165H01L21/283Y10S977/882Y10S977/883
    • A self-replicating monolayer system employing polymerization of monomers or nanoparticle ensembles on a defined template provides a method for synthesis of two-dimensional single molecule polymers. Systems of self-replicating monolayers are used as templates for growth of inorganic colloids. A preferred embodiment employs SAM-based replication, wherein an initial monolayer is patterned and used as a template for self-assembly of a second monolayer by molecular recognition. The second monolayer is polymerized in place and the monolayers are separated to form a replicate. Both may then function as templates for monolayer assemblies. A generic self-replicating monomer unit comprises a polymerizable moiety attached by methylene repeats to a recognition element and an ending unit that will not interfere with the chosen recognition chemistry. The recognition element is self-complementary, unless a set of two replicating monomers with compatible cross-linking chemistry is employed. In a two-component replication system utilizing two different kinds of recognition chemistries, the initial template undergoes replication cycles, while maintaining two-dimensional segregation of the two types of monomers. During subsequent replications, the component domains experience little or no mixing, allowing the two-component, patterned assembly to be exponentially replicated. After replication, selective mineralization and/or electroless plating may produce a two-dimensional inorganic sheet having patterned domains within it.
    • 使用单体或纳米颗粒聚合体在定义的模板上进行聚合的自复制单层体系提供了合成二维单分子聚合物的方法。 自复制单层系统用作无机胶体生长的模板。 优选的实施方案采用基于SAM的复制,其中初始单层被图案化并用作通过分子识别自组装第二单层的模板。 将第二单层聚合就位,并将单层分离形成复制物。 然后两者都可以作为单层组件的模板。 一般的自复制单体单元包括通过亚甲基重复序列连接到识别元件的可聚合部分和不会干扰所选择的识别化学物质的结束单元。 识别元件是自互补的,除非使用具有相容的交联化学的两组复制单体。 在使用两种不同类型的识别化学物质的双组分复制系统中,初始模板经历复制循环,同时保持两种类型的单体的二维分离。 在随后的复制过程中,组件域经历很少或不混合,允许双组分图案化组件以指数方式复制。 复制后,选择性矿化和/或化学镀可以产生其内具有图案区的二维无机片。
    • 10. 发明授权
    • Templated monolayer polymerization and replication
    • 模板单层聚合和复制
    • US07563482B2
    • 2009-07-21
    • US11963970
    • 2007-12-24
    • Joseph M. JacobsonDavid W. Mosley
    • Joseph M. JacobsonDavid W. Mosley
    • B05B3/00
    • H01L21/02112B05D1/185B82Y30/00B82Y40/00G01N31/22G03F7/165H01L21/283Y10S977/882Y10S977/883
    • A self-replicating monolayer system employing polymerization of monomers or nanoparticle ensembles on a defined template provides a method for synthesis of two-dimensional single molecule polymers. Systems of self-replicating monolayers are used as templates for growth of inorganic colloids. A preferred embodiment employs SAM-based replication, wherein an initial monolayer is patterned and used as a template for self-assembly of a second monolayer by molecular recognition. The second monolayer is polymerized in place and the monolayers are separated to form a replicate. Both may then function as templates for monolayer assemblies. A generic self-replicating monomer unit comprises a polymerizable moiety attached by methylene repeats to a recognition element and an ending unit that will not interfere with the chosen recognition chemistry. The recognition element is self-complementary, unless a set of two replicating monomers with compatible cross-linking chemistry is employed. In a two-component replication system utilizing two different kinds of recognition chemistries, the initial template undergoes replication cycles, while maintaining two-dimensional segregation of the two types of monomers. During subsequent replications, the component domains experience little or no mixing, allowing the two-component, patterned assembly to be exponentially replicated. After replication, selective mineralization and/or electroless plating may produce a two-dimensional inorganic sheet having patterned domains within it.
    • 使用单体或纳米颗粒聚合体在定义的模板上进行聚合的自复制单层体系提供了合成二维单分子聚合物的方法。 自复制单层系统用作无机胶体生长的模板。 优选的实施方案采用基于SAM的复制,其中初始单层被图案化并用作通过分子识别自组装第二单层的模板。 将第二单层聚合就位,并将单层分离形成复制物。 然后两者都可以作为单层组件的模板。 一般的自复制单体单元包括通过亚甲基重复序列连接到识别元件的可聚合部分和不会干扰所选择的识别化学物质的结束单元。 识别元件是自互补的,除非使用具有相容的交联化学的两组复制单体。 在使用两种不同类型的识别化学物质的双组分复制系统中,初始模板经历复制循环,同时保持两种类型的单体的二维分离。 在随后的复制过程中,组件域经历很少或不混合,允许双组分图案化组件以指数方式复制。 复制后,选择性矿化和/或化学镀可以产生其内具有图案区的二维无机片。