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    • 47. 发明授权
    • Combating pests with novel phenoxypyridylmethyl esters
    • 用新的苯氧基吡啶甲基酯来防治害虫
    • US4491585A
    • 1985-01-01
    • US355044
    • 1982-03-05
    • Rainer FuchsIngeborg HammannBernhard HomeyerWilhelm Stendel
    • Rainer FuchsIngeborg HammannBernhard HomeyerWilhelm Stendel
    • A01N53/04A01N43/40A01N53/00A01N53/08C07D213/64C07D213/643C07D213/647
    • C07D213/643A01N43/40A01N53/00C07D213/647
    • New phenoxypyridylmethyl esters of the general formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given in the description andR represents the radical ##STR2## wherein R.sup.4 and R.sup.5 have the meaning given in the description, and represents the radical ##STR3## wherein R.sup.6 and R.sup.7 have the meaning given in the description, are obtained by a process in which carboxylic acids of the general formulaR--COOH (II)wherein R has the meaning given previously, or reactive derivatives of these acids, are reacted with phenoxypyridyl alcohols of the general formula ##STR4## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given above, or with reactive derivatives of these alcohols, if appropriate in the presence of acid acceptors, if appropriate in the presence of catalysts and if appropriate in the presence of diluents. The new phenoxypyridylmethyl esters of the formula (I) are distinguished by a high pesticidal, particularly insecticidal and acardicidal activity.
    • 新颖的通式(I)的苯氧基吡啶甲基酯其中R1,R2和R3具有说明书中给出的含义,R代表基团,其中R4和R5具有说明书中给出的含义,并且表示基团 其中R6和R7具有说明书中给出的含义,通过其中R具有以前给出的含义或这些酸的反应性衍生物的通式为R-COOH(II)的羧酸为 与式(III)的苯氧基吡啶醇反应,其中R 1,R 2和R 3具有上述含义,或与这些醇的活性衍生物反应,如果合适,在酸受体存在下,如果合适的话,在催化剂存在下 并在适当的情况下在稀释剂存在下进行。 式(I)的新的苯氧基吡啶基甲基酯的特征在于高杀虫性,特别是杀虫和杀虫活性。
    • 50. 发明授权
    • N-Methyl-N-(sulphonic acid amide-n'-sulphenyl)-carbamic acid esters
    • N-甲基-N-(磺酰胺 - 正 - 硫苯基) - 氨基甲酸酯
    • US4212887A
    • 1980-07-15
    • US948190
    • 1978-10-02
    • Alfons HartmannEngelbert KuhleIngeborg HammannWolfgang BehrenzBernhard Homeyer
    • Alfons HartmannEngelbert KuhleIngeborg HammannWolfgang BehrenzBernhard Homeyer
    • A01N47/24A01P5/00A01P7/02A01P7/04C07C67/00C07C325/00C07C381/08C07D307/86C07D317/08C07D317/24C07D317/46C07D339/06A01N9/16A01N57/06C07C119/18C07F9/02
    • C07D317/24A01N47/24C07D307/86C07D339/06
    • N-Methyl-N-(sulphonic acid amide-N'-sulphenyl)-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1 to 4 carbon atoms in each alkyl radical, phenyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trihalogenomethyl substituent,R.sup.2 is alkyl with 2 to 8 carbon atoms, cycloalkyl, phenyl or cycloalkyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trifluoromethyl substituent, andR.sup.3 is phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl; phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl substituted at least once by trihalogenomethyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto, alkynylmercapto or dialkylamino, each with up to 4 carbon atoms per aliphatic moiety, or an oxime radical of the formula ##STR2## R.sup.4 and R.sup.5 each independently is cyano or alkyl, alkoxy, alkylthio, alkoxycarbonyl, dialkylcarbamoyl or dialkoxyphosphoryl with up to 4 carbon atoms per alkyl moiety, orR.sup.4 and R.sup.5, conjointly with the adjacent carbon atom, form an optionally methyl- or phenyl-substituted dithiolane, dithiane, oxathiolane or oxathiane ring.
    • 具有式(I)的N-甲基-N-(磺酰胺-N'-硫苯基) - 氨基甲酸酯,其中R 1是每个烷基中具有1至4个碳原子的二烷基氨基,苯基或苯基 至少一个卤素,具有1至4个碳原子的烷基,硝基或三卤代甲基取代基,R 2是具有2至8个碳原子的烷基,环烷基,苯基或环烷基或带有至少一个卤素的苯基,具有1至4个碳原子的烷基,硝基或 三氟甲基取代基,R 3为苯基,萘基,苯并二恶烷基,二氢苯并呋喃基或茚满基; 苯基,萘基,苯并二氧杂环戊烷基,二氢苯并呋喃基或茚满烷基,其被三卤代甲基,卤素,硝基,氰基,环烷基,甲酰氨基,二烷基或二氧戊环,或烷基,烯基,炔基,烷氧基,链烯氧基,炔氧基,烷基巯基,烯基巯基,炔基巯基或 每个脂族部分具有至多4个碳原子的二烷基氨基,或下式的肟基团R 4和R 5各自独立地为氰基或烷基,烷氧基,烷硫基,烷氧基羰基,二烷基氨基甲酰基或每烷基具有至多4个碳原子的二烷氧基磷酰基 部分,或R 4和R 5与相邻的碳原子一起形成任选的甲基 - 或苯基取代的二硫戊环,二噻烷,氧硫杂环戊烷或氧硫杂环。