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    • 41. 发明授权
    • Conductive elastomers from electrically conductive fibers in silicone
emulsion
    • 来自导电纤维的导电弹性体在硅氧烷乳液中
    • US4545914A
    • 1985-10-08
    • US645986
    • 1984-08-31
    • Daniel GraiverRobert E. Kalinowski
    • Daniel GraiverRobert E. Kalinowski
    • C08L83/00C08K3/34C08K7/04C08K13/04C08L83/04H01B1/20H01B1/22H05K9/00H01B1/06
    • H05K9/009C08K7/04H01B1/22
    • A composition which provides an electrically conductive product upon removal of the water at ambient conditions is described. The composition comprises a dispersed phase of elastomer and a continuous phase of water containing a material selected from the group comprising colloidal silica, alkali metal silicates, and organosilicates. Also present in the continuous phase is greater than 10 parts by weight of electrically conductive particles in the form of fibers having a diameter of less than 25 micrometers and a length of less than 10 millimeters with the ratio of length to diameter of greater than 10:1. Upon drying, the emulsion yields an electrically conductive elastic product having elastomer particles and electrically conductive fibers dispersed in a solid polar continuous phase. The electrically conductive product is particularly useful as an efficient shield for electromagnetic radiation in the radio and television frequencies.
    • 描述了在环境条件下去除水时提供导电产品的组合物。 该组合物包含弹性体的分散相和含有选自包含胶体二氧化硅,碱金属硅酸盐和有机硅酸盐的材料的水的连续相。 在连续相中也存在大于10重量份的直径小于25微米的纤维形式的导电颗粒和长度小于10毫米的长度与直径之比大于10的导电颗粒: 1。 干燥后,乳液产生具有分散在固体极性连续相中的弹性体颗粒和导电纤维的导电弹性体。 导电产品在无线电和电视频率中作为电磁辐射的有效屏蔽是特别有用的。
    • 48. 发明授权
    • Moisture curable oil and fat compositions and processes for preparing the same
    • 水溶性油脂组合物及其制备方法
    • US08110036B2
    • 2012-02-07
    • US12287100
    • 2008-10-06
    • Ramani NarayanDaniel GraiverKenneth W. FarminerMadhusudhan Srinivasan
    • Ramani NarayanDaniel GraiverKenneth W. FarminerMadhusudhan Srinivasan
    • C09D191/00C08L91/00C07F7/08
    • B01J31/122B01J31/0212B01J31/04B01J2531/42B01J2531/46C07F7/1804
    • A moisture-curable, silane-modified oil is disclosed. The silane-modified oil includes an unsaturated oil having at least one unsaturated aliphatic hydrocarbon chain per molecule of the unsaturated oil, and at least one hydrolysable silyl group grafted to the unsaturated aliphatic hydrocarbon chain. The silane-modified oil has a degree of unsaturation that is substantially similar that of the unsaturated oil. A process for forming the moisture-curable, silane-modified oil according to the disclosure includes reacting the unsaturated oil with an unsaturated hydrolysable silane in the presence of a free radical initiator. Also disclosed is a cured silane-modified oil which includes the reaction product of the silane-modified oil and water. Compositions according to the disclosure have relatively low viscosities (facilitating their application to a substrate) and have relatively high levels of silane grafting (resulting in non-leaching cured compositions with a high gel content).
    • 公开了一种可湿固化的硅烷改性油。 硅烷改性油包括每分子不饱和油具有至少一个不饱和脂族烃链的不饱和油和接枝到不饱和脂族烃链的至少一个可水解甲硅烷基。 硅烷改性油的不饱和度基本上类似于不饱和油。 根据本公开的形成可湿固化的硅烷改性油的方法包括在自由基引发剂存在下使不饱和油与不饱和可水解硅烷反应。 还公开了一种固化的硅烷改性油,其包括硅烷改性油与水的反应产物。 根据本公开的组合物具有相对低的粘度(促进其应用于基材)并且具有相对高水平的硅烷接枝(导致具有高凝胶含量的非浸出固化的组合物)。