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    • 41. 发明授权
    • Silver halide photographic photosensitive materials
    • 卤化银感光材料
    • US5312724A
    • 1994-05-17
    • US61008
    • 1993-05-14
    • Toru HaradaKiyoshi Kawai
    • Toru HaradaKiyoshi Kawai
    • C09B53/00G03C1/83G03C1/815G03C1/825
    • G03C1/83C09B53/00
    • Disclosed is a silver halide photographic photosensitive material comprising a support having thereon a layer which contains at least one dye represented by general formula (I): ##STR1## wherein, R.sup.1 represents a hydrogen atom, a halogen atom, a sulfonic acid group, a carboxylic acid group or a CONHR, SO.sub.2 NHR, NHSO.sub.2 R, NHCOR or NHCONHR group (where R is an alkyl group, an aryl group or a heterocyclic group); R.sup.2 represents a group represented by SO.sub.2 R, COR or CONHR (where R has the same significance as before); R.sup.3 and R.sup.4 are the same or different, and each represents a hydrogen atom, an alkyl group, an alkoxy group, a hydroxy group, an amino group or a halogen atom; R.sup.5 and R.sup.6 are the same or different, and each represents an alkyl group, an aryl group, an acyl group or a sulfonyl group; R.sup.5 and R.sup.6 may be joined together to form a five or six membered ring; R.sup.5 and R.sup.6 may be joined with the adjacent R.sup.4 respectively to form five or six membered rings; n represents an integer of value 0 to 3; provided that there are at least three acidic substituent groups within the dye.
    • 公开了一种卤化银照相感光材料,其包括其上具有包含至少一种由通式(I)表示的染料的层的载体:其中,R 1表示氢原子,卤素原子,磺酸 基团,羧酸基或CONHR,SO 2 NHR,NHSO 2 R,NHCOR或NHCONHR基团(其中R是烷基,芳基或杂环基); R2表示由SO2R,COR或CONHR表示的基团(其中R与以前相同) R 3和R 4相同或不同,各自表示氢原子,烷基,烷氧基,羟基,氨基或卤原子; R5和R6相同或不同,各自表示烷基,芳基,酰基或磺酰基; R5和R6可以连接在一起形成五元或六元环; R5和R6可以分别与相邻的R 4连接形成五或六元环; n表示0〜3的整数, 条件是染料内至少有三个酸性取代基。
    • 42. 发明授权
    • Silver halide photographic photosensitive materials
    • 卤化银感光材料
    • US5312723A
    • 1994-05-17
    • US61017
    • 1993-05-14
    • Toru HaradaKiyoshi Kawai
    • Toru HaradaKiyoshi Kawai
    • G03C1/83G03C1/815G03C1/825
    • G03C1/83
    • Disclosed is a silver halide photographic photosensitive material which contains at least dye by general formula (I) below: ##STR1## wherein R.sup.1 represents a hydrogen atom, a halogen atom, a sulfonic acid group, a carboxylic acid group or a CONHR, SO.sub.2 NHR, NHSO.sub.2 R, NHCOR or NHCONHR group (where R is an alkyl group, an aryl group or a heterocyclic group); R.sup.2 and R.sup.3 are the same or different and each represents a hydrogen atom, an alkyl group or an NHSO.sub.2 R or NHCOR group (where R has the same meaning as above) or a halogen atom, or R.sup.2 and R.sup.3 may be joined together and represent a group of atoms which is required to form an aromatic ring; R.sup.4 and R.sup.5 are the same or different and each represents a hydrogen atom, an alkyl group, an alkoxy group, a hydroxy group, an amino group or a halogen atom; R.sup.6 and R.sup.7 are the same or different and each represents an alkyl group, an aryl group, an acyl group or a sulfonyl group; R.sup.6 and R.sup.7 may be joined together to form a five or six membered ring; R.sup.6 or R.sup.7 may be joined with the adjacent R.sup.5 respectively to form a five or six membered ring; n represents an integer of 0 to 3; wherein that there are at least five acidic substituent groups within the dye.
    • 公开了至少含有通式(I)的染料的卤化银照相感光材料:其中R1表示氢原子,卤素原子,磺酸基,羧酸基或CONHR的(I) ,SO2NHR,NHSO2R,NHCOR或NHCONHR基团(其中R是烷基,芳基或杂环基); R2和R3相同或不同,各自表示氢原子,烷基或NHSO2R或NHCOR基团(其中R具有与上述相同的含义)或卤素原子,或者R 2和R 3可以连接在一起并表示 需要形成芳环的原子团; R4和R5相同或不同,各自表示氢原子,烷基,烷氧基,羟基,氨基或卤素原子; R6和R7相同或不同,各自表示烷基,芳基,酰基或磺酰基; R6和R7可以连接在一起形成五元或六元环; R 6或R 7可以分别与相邻的R 5连接形成五元或六元环; n表示0〜3的整数, 其中染料内至少有五个酸性取代基。
    • 49. 发明申请
    • ALUMINUM SILICATE, METAL ION ADSORBENT, AND METHOD FOR PRODUCING SAME
    • 硅酸铝,金属离子吸附剂及其生产方法
    • US20140309106A1
    • 2014-10-16
    • US14004581
    • 2011-12-07
    • Hiroki MikuniKiyoshi Kawai
    • Hiroki MikuniKiyoshi Kawai
    • B01J20/28B01J20/16
    • B01J20/2808B01J20/10B01J20/16B01J20/28061B01J20/28069B01J20/28078B01J20/3085C01B33/26C01P2002/72C01P2006/12C01P2006/14C01P2006/16C02F1/281C02F2101/20
    • The aluminum silicate of the invention has: an element ratio of Si and Al, represented by Si/Al, of from 0.3 to 1.0 by molar ratio; a peak at approximately 3 ppm in a 27Al-NMR spectrum; peak A at approximately −78 ppm and peak B at approximately −85 ppm in a 29Si-NMR spectrum; and a peak at approximately 2θ=26.9° and a peak at approximately 2θ=40.3° in a powder X-ray diffraction spectrum. The aluminum silicate has an area ratio of peak B with respect to peak A of from 2.0 to 9.0, or does not include a tubular substance having a length of 50 nm or more as observed in a transmission electron microscope (TEM) photograph of the aluminum silicate taken at a magnification of 100,000. The aluminum silicate is produced by a method comprising: subjecting a reaction product of a silicate ion solution and an aluminum ion solution to desalting and solid separation; subjecting a resultant to a thermal treatment in an aqueous medium in the presence of an acid under concentration conditions in an aqueous medium such that a silicon atom concentration is 100 mmol/L or more and an aluminum atom concentration is 100 mmol/L or more; and subjecting a resultant to further desalting and solid separation.
    • 本发明的硅酸铝具有以Si / Al表示的Si与Al的摩尔比为0.3〜1.0的元素比; 在27Al-NMR光谱中约为3ppm的峰; 峰A在约-78ppm,峰B在约-85ppm的29Si-NMR光谱中; 并且在粉末X射线衍射光谱中在约2θ= 26.9°处的峰值和约2θ处的峰值= 40.3°。 硅酸铝的峰值B相对于峰值A的面积比为2.0〜9.0,或者不包括在铝的透射电子显微镜(TEM)照片中观察到的长度为50nm以上的管状物质 硅酸盐以100,000的倍数拍摄。 硅酸铝是通过以下方法制造的:将硅酸盐离子溶液和铝离子溶液的反应产物进行脱盐和固体分离; 在水介质中,在浓度条件下,在酸性存在下,在水介质中进行热处理,使得硅原子浓度为100mmol / L以上,铝原子浓度为100mmol / L以上; 并使所得物进一步脱盐和固体分离。