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31. 发明授权

US5612175A Epitaxially sensitized tabular grain emulsions exhibiting enhanced speed and contrast 失效
标题翻译：显示出增强的速度和对比度的外源敏化的片状颗粒乳剂
公开(公告)号：US5612175A
公开(公告)日：1997-03-18
申请号：US592169
申请日：1996-01-26
申请人： Lyn M. Eshelman , Paul J. Madigan , Joseph C. Deaton , David A. Dumont , Michael G. Antoniades , Sharon G. Johnston
发明人： Lyn M. Eshelman , Paul J. Madigan , Joseph C. Deaton , David A. Dumont , Michael G. Antoniades , Sharon G. Johnston
IPC分类号： G03C1/035 , G03C1/005 , G03C1/09 , G03C1/12 , G03K1/035
CPC分类号： G03C1/0051 , G03C1/09 , G03C1/12
摘要： A radiation-sensitive spectrally sensitized tabular grain emulsion is disclosed which exhibits improved speed and contrast. The tabular grains have {111} major faces, contain greater than 70 mole percent bromide and up to 10 mole percent iodide, based on silver, account for greater than 90 percent of total grain projected area, and have an average equivalent circular diameter of at least 3.5 .mu.m. The tabular grains have latent image forming chemical sensitization sites on their surfaces including epitaxially deposited silver halide protrusions of a face centered cubic rock salt crystal lattice structure forming epitaxial junctions with the tabular grains. The protrusions are restricted to those portions of the tabular grains located nearest peripheral edges of and accounting for less than 10 percent of the {111} major faces of the tabular grains, accounting for less than 5 percent of total silver forming the tabular grains and protrusions, containing a silver chloride concentration at least 10 mole percent higher than that of the tabular grains, and contain at least 1 mole percent iodide, based on silver in the protrusions.
摘要翻译：公开了辐射敏感的光谱敏化片状颗粒乳剂，其显示出改进的速度和对比度。片状颗粒具有{111}主面，含有大于70摩尔百分比的溴和基于银的高达10摩尔％的碘，占总颗粒投影面积的大于90％，并且具有平均当量圆直径至少3.5亩。片状颗粒在它们的表面上具有潜像形成的化学增感位点，包括外面沉积的卤化银突起，其表面立方岩盐晶格结构与片状颗粒形成外延结。突出部分限于位于最近周边边缘的片状颗粒的部分，并且占片状颗粒的{111}主面的少于10％，占形成片状颗粒和突起的总银的小于5％，其含有比片状颗粒高至少10摩尔％的氯化银浓度，并且基于突起中的银含有至少1摩尔％的碘化物。

32. 发明授权

US5610005A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US5610005A
公开(公告)日：1997-03-11
申请号：US662290
申请日：1996-06-12
申请人： Hiroshi Kawakami , Junji Nishigaki
发明人： Hiroshi Kawakami , Junji Nishigaki
IPC分类号： G03C7/00 , G03C1/08 , G03C1/09 , G03C1/16 , G03C1/29 , G03C7/26
CPC分类号： G03C1/08 , G03C1/16 , G03C1/29
摘要： A color photographic light-sensitive material which has a high storage stability and a high sensitivity and in which photographic properties vary little with the passage of time from photography to development is provided. At least one light-sensitive silver halide emulsion layer constituting a silver halide color photographic light-sensitive material is spectrally sensitized with at least one type of a spectral sensitizing dye represented by Formula (I) below, and at least one silver halide emulsion contained in this light-sensitive silver halide emulsion layer is subjected to reduction sensitization in the manufacturing process of the emulsion. (In Formula (I), each of R.sub.11 and R.sub.12 represents an alkyl group, Z.sub.11 represents a group of atoms required to form a benzene ring, Z.sub.12 represents a group of atoms required to form a benzothiazole nucleus, a benzoselenazole nucleus, a benzoxazole nucleus, or a naphthoxazole nucleus, and X.sub.11 represents a charge-balancing counter anion.)Formula (I) ##STR1##
摘要翻译：提供了一种具有高储存稳定性和高灵敏度的摄影感光材料，其中摄影性能随着从摄影到发展的时间的流逝变化很小。构成卤化银彩色照相感光材料的至少一种感光卤化银乳剂层用至少一种由下式（I）表示的光谱增感染料和至少一种卤化银乳剂进行光谱增感，该感光卤化银乳剂层在乳液的制造过程中进行还原增感。（式（I）中，R 11和R 12分别表示烷基，Z 11表示形成苯环所需的原子团，Z 12表示形成苯并噻唑核所需的原子团，苯并硒唑核，苯并恶唑核，或萘并恶唑核，X11表示电荷平衡反阴离子。）式（I）

33. 发明授权

US5576172A Elevated iodide surface laminae tabular grain emulsions 失效
标题翻译：升高的碘化物表面片状颗粒乳剂
公开(公告)号：US5576172A
公开(公告)日：1996-11-19
申请号：US442232
申请日：1995-05-15
申请人： Myra T. Olm , Roger A. Bryant , Elizabeth K. Lelental , Sharon Gould , Sherrill A. Puckett
发明人： Myra T. Olm , Roger A. Bryant , Elizabeth K. Lelental , Sharon Gould , Sherrill A. Puckett
IPC分类号： G03C1/035 , G03C1/005 , G03C1/08 , G03C1/09
CPC分类号： G03C1/0051 , G03C1/08 , G03C1/09
摘要： A tabular grain emulsion is disclosed that combines increased speed, reduced low intensity reciprocity failure, and low levels of pressure sensitivity. The tabular grains containing greater than 70 mole percent bromide and laminae located adjacent the {111} major faces each having a thickness of less than 35 nanometers and containing at least 1 mole percent higher iodide than a host portion of the tabular grains on which they are deposited. The tabular grains contain an iridium dopant capable of reducing low intensity failure in one interior grain portion and a Group 8 speed enhancing dopant present in a concentration of from 20 to 300 molar parts per million in another interior grain portion separated from the iridium containing grain portion by at least 10 percent of the silver forming the grain structure.
摘要翻译：公开了一种片状颗粒乳剂，其结合了增加的速度，降低的低强度互易性故障和低水平的压力敏感性。含有大于70摩尔％溴化物的片状颗粒和位于{111}主面附近的薄片各自具有小于35纳米的厚度，并且含有比它们的片状颗粒的主体部分高至少1摩尔％的碘化物存放片状颗粒含有能够降低一个内部颗粒部分中的低强度破坏的铱掺杂剂和在与含有铱的颗粒部分分离的另一内部颗粒部分中存在的浓度为20至300摩尔百万分之一的第8族速度增强掺杂剂至少10％的银形成晶粒结构。

34. 发明授权

US5573899A Silver halide photographic material 失效
标题翻译：卤化银照相材料
公开(公告)号：US5573899A
公开(公告)日：1996-11-12
申请号：US245071
申请日：1994-05-17
申请人： Akira Kase
发明人： Akira Kase
IPC分类号： G03C1/035 , G03C1/09 , G03C1/34 , G03C1/825 , G03C1/83
CPC分类号： G03C1/09 , G03C1/035 , G03C1/825 , G03C2001/03517 , G03C2001/03535
摘要： A silver halide photographic material having at least one light-sensitive emulsion layer containing a silver halide emulsion on a support, in which at least one silver halide emulsion layer contains silver halide grains of silver chloride or silver chlorobromide having a silver chloride content of 90 mol % or more, the silver halide grains being tellurium-sensitized, and at least one of light-sensitive emulsion layers or non-light-sensitive emulsion layers on the support contains at least one specific compound represented by formula (I), (II) or (III) herein. The material has excellent rapid processability and a high sensitivity. It involves little photographic fluctuation before and after continuous processing thereof and little photographic fluctuation due to variation of the ambient humidity during exposure thereof. The image sharpness of the material may be noticeably improved without appreciably detracting from the sensitivity thereof.
摘要翻译：一种卤化银照相材料，其具有至少一种在载体上含有卤化银乳剂的感光乳剂层，其中至少一个卤化银乳剂层含有氯化银的卤化银颗粒或氯化银氯化银含量为90mol ％以上的卤化银颗粒是碲敏化的，载体上的感光乳剂层或非感光乳剂层中的至少一种含有至少一种由式（I），（II）表示的特定化合物，或（III）。该材料具有优异的快速加工性和高灵敏度。它在连续处理之前和之后涉及很少的照相波动，并且由于曝光期间环境湿度的变化而引起的照相波动很小。材料的图像清晰度可以明显改善，而不会明显地降低其灵敏度。

35. 发明授权

US5561039A Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US5561039A
公开(公告)日：1996-10-01
申请号：US458245
申请日：1995-06-02
申请人： Yoshiro Ochiai
发明人： Yoshiro Ochiai
IPC分类号： G03C7/00 , G03C1/035 , G03C1/09 , G03C1/12 , G03C1/20 , G03C1/34
CPC分类号： C09B23/0066 , C09B23/0075 , G03C1/09 , G03C1/127 , G03C1/34
摘要： A silver halide photographic light-sensitive material. It comprises a support and at least one silver halide emulsion layer thereon, wherein at least one silver halide emulsion layer comprises silver chlorobromide emulsion particles containing 95 mol % or more of silver chloride or silver chloride emulsion particles as well as at least one thiosulfonic compound of formula (X) and at least one sulfinic compound of formula (Y), and the particles contained in the silver halide emulsion layer are sensitized by gold, selenium, or tellurium, and are spectrally sensitized by a red-sensitive methine dye represented by formula (I): ##STR1## wherein Q, R.sup.1 and other symbols each independently represents a specific atom or group, n is an integer from 0 to 6, M is a counter ion which neutralizes an electric charge, and m is 0 or 1.
摘要翻译：卤化银照相感光材料。它包括载体和至少一个卤化银乳剂层，其中至少一个卤化银乳剂层包含含有95mol％或更多氯化银或氯化银乳剂颗粒的氯化银溴化银乳剂颗粒以及至少一种硫代磺酸化合物式（X）和至少一种式（Y）的亚磺酸化合物，并且包含在卤化银乳剂层中的颗粒被金，硒或碲致敏，并且由式（X）表示的红色敏感的次甲基染料进行光谱增感（I）：其中Q，R 1和其它符号各自独立地表示特定的原子或基团，n是0至6的整数，M是中和的抗衡离子（I）的化合物（I）R21SO2SM21（X）R22SO2M22 电荷，m为0或1。

36. 发明授权

US5556738A Silver halide photographic element and processing method thereof 失效
标题翻译：卤化银照相材料及其加工方法
公开(公告)号：US5556738A
公开(公告)日：1996-09-17
申请号：US502216
申请日：1995-07-13
申请人： Yasuhiko Takamuki , Ken Nagami
发明人： Yasuhiko Takamuki , Ken Nagami
IPC分类号： G03C1/005 , G03C1/09 , G03C1/32 , G03C1/95 , G03C5/31 , G03C1/77
CPC分类号： G03C5/31 , G03C1/32 , G03C1/95 , G03C1/0051 , G03C1/09
摘要： A silver halide photographic element with enhanced sensitivity and improved pressure resistance is disclosed, comprising a support having, on at least one side thereof, hydrophilic colloidal layers including a light-sensitive silver halide emulsion layer and a nonlight-sensitive hydrophilic colloidal layer, wherein the nonlight-sensitive layer contains organic material-aggregation particles; and gelatin contained in the total hydrophilic colloidal layers provided on one side of the support amounts to a range of 1.3 to 2.5 g per m.sup.2.
摘要翻译：公开了一种具有增强的灵敏度和改善的耐压性的卤化银照相元件，其包括在至少一侧具有包括感光卤化银乳剂层和非光敏感亲水性胶体层的亲水性胶体层的载体，其中，非光敏层包含有机材料聚集颗粒; 并且在载体一侧上提供的总亲水性胶体层中所含的明胶的含量为1.3-2.5g / m2。

37. 发明授权

US5550003A Silver halide photographic photosensitive materials and a method of image formation in which they are used 失效
标题翻译：卤化银照相感光材料及其形成方法
公开(公告)号：US5550003A
公开(公告)日：1996-08-27
申请号：US301633
申请日：1994-09-07
申请人： Nobuaki Inoue
发明人： Nobuaki Inoue
IPC分类号： G03C1/04 , G03C1/06 , G03C1/09 , G03C5/315
CPC分类号： G03C1/09 , G03C1/04 , G03C1/061
摘要： A silver halide photographic photosensitive material comprises an emulsion layer which includes silver halide grains having a silver chloride content of at least 50 mol % and containing a rhodium compound. The material also comprises, (i) a hydrazine derivative according to formula (1), (2) or (3) which formulas are shown and defined in the specification, and (ii) at least one compound selected from colloidal silica and polyacrylamide derivatives. The material further comprises a protective layer, the outermost layer of which has a dynamic friction coefficient is not more than 0.35. The material may be processed in a developer having a pH of at least 9.6 but less than 11.0.
摘要翻译：卤化银照相感光材料包括含有氯化银含量至少为50摩尔％并含有铑化合物的卤化银颗粒的乳剂层。所述材料还包含（i）根据式（1），（2）或（3）的肼衍生物，其在说明书中示出和定义，和（ii）至少一种选自胶态二氧化硅和聚丙烯酰胺衍生物的化合物。该材料还包括保护层，其最外层的动摩擦系数不大于0.35。该材料可以在具有至少9.6但小于11.0的pH的显影剂中加工。

38. 发明授权

US5536632A Ultrathin tabular grain emulsions with dopants at selected locations 失效
标题翻译：在选定位置具有掺杂剂的超薄片状颗粒乳剂
公开(公告)号：US5536632A
公开(公告)日：1996-07-16
申请号：US441132
申请日：1995-05-15
申请人： Xin Wen , Richard L. Daubendiek , Donald L. Black , Joseph C. Deaton , Timothy R. Gersey , Joseph G. Lighthouse , Myra T. Olm , Robert D. Wilson
发明人： Xin Wen , Richard L. Daubendiek , Donald L. Black , Joseph C. Deaton , Timothy R. Gersey , Joseph G. Lighthouse , Myra T. Olm , Robert D. Wilson
IPC分类号： G03C1/005 , G03C1/08 , G03C1/46 , G03C1/035 , G03C1/09
CPC分类号： G03C1/0051 , G03C1/08 , G03C1/46
摘要： A chemically and spectrally sensitized ultrathin tabular grain emulsion is disclosed including tabular grains (a) having {111} major faces, (b) containing greater than 70 mole percent bromide, based on silver, (c) accounting for greater than 90 percent of total grain projected area, (d) exhibiting an average equivalent circular diameter of at least 0.7 .mu.m, and (e) exhibiting an average thickness of less than 0.07 .mu.m.Improved sensitivity is observed when the surface chemical sensitization sites include silver halide protrusions of a face centered cubic crystal lattice structure forming epitaxial junctions with the tabular grains and having a higher overall solubility than at least that portion of the tabular grains forming epitaxial junctions with the protrusions and a sensitivity enhancing combination of dopants are contained in the silver halide grains including a first sensitivity enhancing dopant capable of providing shallow electron trapping sites and a second sensitivity enhancing selenium dopant. To further enhance sensitivity, one of the sensitivity enhancing dopants is restricted to the tabular grains while the other is restricted to the silver halide epitaxy.
摘要翻译：公开了化学和光谱增感的超薄片状颗粒乳剂，其包括具有{111}主面的片状颗粒（a），（b）基于银含有大于70摩尔％的溴化物，（c）占总量的90％以上（d）平均当量圆直径至少为0.7μm，（e）平均厚度小于0.07μm。当表面化学增感部位包括面心立方晶格结构的卤化银突起形成与片状颗粒形成外延结和具有比至少部分形成与凸起的外延结的片状颗粒更高的总体溶解度时，观察到灵敏度提高并且包含掺杂剂的敏感度增强组合包含在包含能够提供浅电子捕获位点的第一灵敏度增强掺杂剂和第二灵敏度增强硒掺杂剂的卤化银颗粒中。为了进一步提高灵敏度，灵敏度增强掺杂剂之一限于片状晶粒，而另一种限于卤化银外延。

39. 发明授权

US5518872A Emulsion and photographic element 失效
标题翻译：乳液和摄影元素
公开(公告)号：US5518872A
公开(公告)日：1996-05-21
申请号：US336817
申请日：1994-11-09
申请人： Roy King , Roger A. Weiss , Kenneth J. Reed , Gerald W. Klein
发明人： Roy King , Roger A. Weiss , Kenneth J. Reed , Gerald W. Klein
IPC分类号： G03C1/00 , G03C1/005 , G03C1/035 , G03C1/08 , G03C1/09 , G03C1/10 , G03C1/12
CPC分类号： G03C1/0051 , G03C1/08 , G03C1/10 , G03C1/12
摘要： Improved sensitivity and reduced minimum density are provided by an emulsion in which high bromide tabular grains exhibit an average thickness of less than 0.07 .mu.m and have latent image forming reduction chemical sensitization sites and adsorbed spectral sensitizing dye on their surfaces. The tabular grains contain a dopant capable of forming shallow electron trapping sites, and the spectral sensitizing dye exhibits an oxidation potential more positive than 1.2 volts. A photographic element is disclosed which locates the emulsion in a layer overlying a minus blue recording emulsion layer. Exceptionally sharp images are formed in the minus blue recording emulsion layer when in the overlying emulsion layer greater than 97 percent of the total projected area of the silver halide grains having an equivalent circular diameter of at least 0.2 .mu.m is accounted for by tabular grains having an average equivalent circular diameter of at least 0.7 .mu.m.
摘要翻译：提高灵敏度和降低最小密度由高溴化物片状颗粒表现出小于0.07μm的平均厚度并具有潜像形成还原化学增感位点和吸附的光谱增感染料在其表面上的乳液提供。片状晶粒包含能够形成浅电子捕获位点的掺杂剂，并且光谱增感染料表现出比1.2伏更正的氧化电位。公开了一种照相元件，其将乳剂定位在覆盖负蓝色记录乳剂层的层中。当在上覆的乳剂层中，当具有至少0.2μm等效圆直径的卤化银颗粒的总投影面积的97％以上时，在负蓝色记录乳剂层中形成非常清晰的图像，平均当量圆直径至少为0.7μm。

40. 发明授权

US5508156A Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US5508156A
公开(公告)日：1996-04-16
申请号：US350085
申请日：1994-11-29
申请人： Hiroshi Kawai
发明人： Hiroshi Kawai
IPC分类号： G03C7/00 , G03C1/035 , G03C1/09 , G03C1/76 , G03C1/83 , G03C7/26 , G03C7/30 , G03C1/10
CPC分类号： G03C1/832 , G03C1/035 , G03C1/09 , G03C1/76 , G03C7/30 , Y10S430/164
摘要： There is disclosed a silver halide photographic light-sensitive material. The photographic material comprises a support having thereon at least a silver halide emulsion layer containing silver halide grains, which grains have a silver chloride content of 95 mol % or more and are subjected to selenium, tellurium or gold sensitization, wherein the photographic material further contains a specific dye, and wherein the photographic material preferably has the pH value of the coated film of no more than 6.5.
摘要翻译：公开了一种卤化银照相感光材料。照相材料包括其上至少含有卤化银颗粒的卤化银乳剂层的载体，所述卤化银颗粒的氯化银含量为95摩尔％以上，并进行硒，碲或金增感，其中，照相材料还含有特定染料，并且其中所述照相材料优选具有不超过6.5的所述涂布膜的pH值。

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