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    • 33. 发明授权
    • Compounds with isocyanate groups and masked groups reactive in relation
to isocyanates
    • 具有异氰酸酯基团和掩蔽基团的化合物与异氰酸酯相互反应
    • US6022938A
    • 2000-02-08
    • US91239
    • 1998-06-18
    • Bernd BruchmannHans RenzGunter Mohrhardt
    • Bernd BruchmannHans RenzGunter Mohrhardt
    • C08G18/80C07D317/14C07D319/06C08G18/28C08G18/32C09D175/00C09D175/04
    • C07D317/14C07D319/06C08G18/2805C08G18/2825C08G18/2865C08G18/2875C08G18/32C09D175/00
    • Isocyanato compounds with capped, isocyanate-reactive groups are those of the formula I ##STR1## where R.sup.1 and R.sup.2 are hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.10 -aralkyl or together form C.sub.3 -C.sub.10 -alkanediyl,X and Y are --O--, --S-- or ##STR2## where R.sup.4 is hydrogen, C.sub.1 -C.sub.20 -alkyl which is uninterrupted or interrupted by oxygen atoms in ether function, or is C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.10 -aralkyl,R.sup.3 is C.sub.1 -C.sub.10 -alkanediyl which together with --X--CR.sup.1 R.sup.2 --Y-- forms a 4-7-membered ring,in which either one hydrogen in R.sup.3 or the radical R.sup.4 in ##STR3## is replaced by an allophanate group R.sup.Ia ##STR4## in which R.sup.5 is a divalent aliphatic, alicyclic, araliphatic or aromatic C.sub.2 -C.sub.20 hydrocarbon unit,R.sup.6 is a single bond or a divalent aliphatic, alicyclic, araliphatic or aromatic C.sub.1 -C.sub.20 hydrocarbon unit or a mono- or poly(C.sub.2 -C.sub.4 -alkylene oxide) unit, andR.sup.7 is a carbamoyl radical ##STR5## or a biuret group R.sup.Ib ##STR6## in which one R.sup.8 is hydrogen and the other is as defined for R.sup.7 or a biuret group R.sup.Ic ##STR7## in which one R.sup.9 is as defined for R.sup.7 and the other is as defined for R.sup.1or a thioallophanate group R.sup.Id ##STR8##
    • PCT No.PCT / EP96 / 05634 371日期1998年6月18日 102(e)1998年6月18日PCT PCT 1996年12月16日PCT公布。 公开号WO97 / 23536 日期1997年7月3日具有封端,异氰酸酯反应性基团的异氰酸酯化合物是式I的那些化合物,其中R 1和R 2是氢,C 1 -C 10 - 烷基,C 6 -C 10 - 芳基或C 7 -C 10 - 芳烷基或一起形成C 3 -C 10 - 烷二基,X和Y是-O - , - S-或其中R 4是氢,C 1 -C 20 - 烷基,其不受中间或由醚官能团中的氧原子间隔,或者是C 6 -C 10 - 芳基或C 7 -C 10 - 芳烷基 R 3是C 1 -C 10烷二基,其与-X-CR 1 R 2 -Y-一起形成4-7元环,其中R 3中的一个氢或基团R 4取代为其中R 5为 二价脂族,脂环族,芳脂族或芳族C2-C20烃单元,R6是单键或二价脂族,脂环族,芳脂族或芳族C1-C20烃单元或单或多(C2-C4-烯化氧)单元 ,R7是氨基甲酰基或缩二脲基RIb,其中一个R 8是氢,另一个如R7所定义或一个缩二脲基团,其中一个R 9如R7所定义,另一个i 其定义为R1或硫代山梨醇基团RId
    • 34. 发明授权
    • Method for low bake repair of composite color-plus-clear coatings, and
compositions for use therein
    • 复合彩色透明涂层的低烘烤修复方法及其中使用的组合物
    • US5972422A
    • 1999-10-26
    • US71083
    • 1998-05-01
    • Herbert L. Harmon
    • Herbert L. Harmon
    • B05D7/00B05D5/00C08G18/38C08G18/62C09D133/06C09D175/00C09D201/02C09D201/06B05D1/38B05D3/02B05D7/26B32B35/00
    • C09D133/062B05D5/005C09D201/02
    • The invention provides a method for providing a low bake repair to a cured coating, especially a composite coating and low bake repair compositions for use therein. The method of the invention involves the provision of a cured coated surface and the application of a low bake repair coating to at least a portion of the cured coated surface. The low bake repair coating of the invention has (A) a film forming component comprising (a) a first component comprising a compound having appended thereto at least one carbamate or urea functional group, or a group convertible to a carbamate or urea group, and (b) a second component comprising a compound reactive with said carbamate or urea groups on component (a), and (B) a catalyst comprising a compound selected from the group consisting of Al(ClO.sub.4).sub.2, Zr(ClO.sub.4).sub.2, and Al(NO.sub.3).sub.2. The low bake repair coating is cured at a temperature of less than 200.degree. F. for a time sufficient to cure the low bake repair coating.
    • 本发明提供了一种为固化涂层提供低烘烤修复的方法,特别是用于其中的复合涂层和低烘烤修复组合物。 本发明的方法包括提供固化的涂覆表面和将低烘烤修复涂层施加到固化的涂覆表面的至少一部分上。 本发明的低烘烤修复涂层具有(A)成膜组分,其包含(a)第一组分,其包含附有至少一个氨基甲酸酯或脲官能团的化合物或可转化为氨基甲酸酯或脲基的基团,以及 (b)第二组分,其包含与组分(a)上的所述氨基甲酸酯或脲基反应的化合物,和(B)包含选自Al(ClO 4)2,Zr(ClO 4)2和 Al(NO3)2。 低温烘烤修复涂层在低于200°F的温度下固化足够固化低温修复涂层的时间。
    • 40. 发明授权
    • Process for the preparation of a modified polymer for powder paints
    • 制备用于粉末涂料的改性聚合物的方法
    • US5830943A
    • 1998-11-03
    • US681413
    • 1996-07-23
    • Dirk A. W. Stanssens
    • Dirk A. W. Stanssens
    • C08G85/00C08G18/00C08G18/08C08G18/67C08G18/75C08G18/76C08G59/14C09D5/03C09D163/00C09D175/00C08J3/00C08F8/30C08K3/20C08L75/00
    • C09D5/03C08G18/672C08G18/753C08G18/7621C08G2150/20
    • The invention relates to a process for the preparation of a modified polymer by reaction between a reactive polymer and at least a compound containing two or more functional groups. The polymer, which is solid at room temperature, is mixed, at a temperature at which the viscosity of the polymer is lower than 10000 dPas (measured according to Emila), with a compound containing two or more functional groups in a mixing means for achieving a homogeneous product and the mean residence time and the residence time distribution being chosen so that more than 50% of the reactive groups of the polymer has reacted. As means to make the composition homogeneous use is made of a static mixer.The functional groups of the compound containing two or more functional groups have different reactivities. The invention also relates to a binder composition, which comprises the modified polymer thus obtained and a crosslinker.
    • 本发明涉及通过反应性聚合物与至少含有两个或多个官能团的化合物之间的反应制备改性聚合物的方法。 在室温下固体的聚合物在聚合物的粘度低于10000dPas(根据Emila测量)的温度下与在混合装置中含有两个或多个官能团的化合物混合,以实现 均匀的产物,并且选择平均停留时间和停留时间分布,使得多于50%的聚合物的反应性基团已经反应。 作为使组合物均匀使用的方法由静态混合器制成。 含有两个或多个官能团的化合物的官能团具有不同的反应性。 本发明还涉及粘合剂组合物,其包含由此获得的改性聚合物和交联剂。