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    • 36. 发明申请
    • Method For The Production Of Copolymers
    • 共聚物生产方法
    • US20120035301A1
    • 2012-02-09
    • US13133047
    • 2009-01-13
    • Mario VierleChristian Scholz
    • Mario VierleChristian Scholz
    • C08F222/06C08K3/00
    • C08F290/142C08F290/062C08L51/003C08L2666/02C08L2666/04
    • The invention relates to a process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus, comprising a polymerization reactor connected to a metering device, in each case acid monomer being initially taken in the metering device and polyether macromonomer and water in the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, free radical polymerization initiator being passed into the polymerization reactor before and/or during the metering of the acid monomer into the polymerization reactor so that an aqueous medium in which acid monomer and polyether macromonomer are reacted with formation of the copolymer by free radical polymerization forms in the polymerization reactor, the free radical polymerization initiator used being an H2O2— or alkali metal peroxodisulphate-containing redox initiator system, the temperature of the aqueous medium during the polymerization being adjusted to 5 to 43° C., the temperature of the aqueous medium being not more than 28° C. at the beginning of the polymerization, altogether 1 to 20 mol of acid monomer being metered into the polymerization reactor per mole of polyether macromonomer used, the weight ratio of polyether macromonomer used to water used being 5:1 to 1:5, at least 70% by weight of the water initially taken in the polymerization reactor being provided in the manner such that it is either added to the polymerization reactor at a temperature of not more than 19° C. or it is combined with the polyether macromonomer before it is added to the polymerization reactor and thus has a temperature of not more than 19° C.
    • 本发明涉及一种在聚合设备中半连续操作中制备共聚物的方法,包括连接到计量装置的聚合反应器,在每种情况下,酸性单体最初被摄入计量装置中,聚醚大分子单体和水在聚合中 反应器,酸性单体从计量装置计量到聚合反应器中,自由基聚合引发剂在酸性单体计量之前和/或期间进入聚合反应器,使得其中含有酸单体和 聚合物大分子单体与聚合反应器中的自由基聚合形式与共聚物反应形成,所用的自由基聚合引发剂是H 2 O 2 - 或含碱金属过氧化二硫酸盐的氧化还原引发剂体系,聚合过程中水性介质的温度被调节 至5至43° C.在聚合开始时,水性介质的温度不超过28℃,每摩尔使用的聚醚大分子单体,在聚合反应器中加入1至20mol酸单体,聚醚的重量比 用于所用水的大分子单体为5:1至1:5,最初在聚合反应器中摄取的水的至少70重量%以使其在不超过该温度的温度下加入到聚合反应器中的方式提供 或者在将聚醚单体加入到聚合反应器中之前与聚醚大分子单体组合,因此温度不超过19℃。
    • 40. 发明申请
    • POLYMERS PREPARED FROM MIXTURES OF MULTIFUNCTIONAL N-VINYLFORMAMIDE AND HYBRID REACTIVE N-VINYLFORMAMIDE CROSSLINKING MONOMER MOIETIES AND USES THEREOF
    • 由多官能N-乙烯酰胺和混合反应性N-乙烯基酰胺交联单体的混合物制备的聚合物及其用途
    • US20110166308A1
    • 2011-07-07
    • US12984926
    • 2011-01-05
    • Osama M. MusaIlya MakarovskyLei Cuiyue
    • Osama M. MusaIlya MakarovskyLei Cuiyue
    • C08F222/38C08F226/02C08F22/40C08F26/06C08F22/38C08F20/32C08F224/00C08F222/06C08F226/06C08F228/02
    • The present invention provides polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a multifunctional N-vinylformamide crosslinking moiety; polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality; polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a multifunctional N-vinylformamide crosslinking moiety; and polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality. The invention further provides a wide variety of compositions comprising the novel crosslinked polymers.
    • 本发明提供由至少一种反应性乙烯基单体部分和多官能N-乙烯基甲酰胺交联部分聚合得到的聚合物; 由至少一个反应性乙烯基单体部分和具有至少一个N-乙烯基甲酰胺官能团的至少一种其它反应性乙烯基官能团的杂化N-乙烯基甲酰胺交联部分的聚合产生的聚合物; 由具有一个N-乙烯基甲酰胺官能度的至少一种杂化反应性N-乙烯基甲酰胺单体部分和至少一种其它反应性非乙烯基官能团和多官能N-乙烯基甲酰胺交联部分聚合得到的聚合物; 以及由具有一个N-乙烯基甲酰胺官能团的至少一种杂化反应性N-乙烯基甲酰胺单体部分和至少一种其它反应性非乙烯基官能团的聚合产生的聚合物和具有至少一个N-乙烯基甲酰胺官能度的杂化N-乙烯基甲酰胺交联部分, 至少一个其他反应性乙烯基官能团。 本发明还提供了包含新型交联聚合物的各种组合物。