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    • 31. 发明授权
    • Incorporable photoinitiator
    • 可并入的光引发剂
    • US07588880B2
    • 2009-09-15
    • US10512300
    • 2003-04-17
    • Jean-Pierre WolfRinaldo HüslerWolfgang PeterReinhard H. SommerladeSouâd Boulmaâz
    • Jean-Pierre WolfRinaldo HüslerWolfgang PeterReinhard H. SommerladeSouâd Boulmaâz
    • G03C1/73G03C1/735G03F7/028C08F2/50C07C49/12
    • C08F2/50B33Y70/00
    • Compounds of formula I Y is, for example, C3-C12alkylene, butenylene, butynylene, or C4-C12alkylene interrupted one or more times by non-consecutive —O— or —NR2—; R1 is a reactive group selected from OH, SH, NR3R4, —(CO)—OH, —(CO)—NH2, SO3H, —C(R5)═CR6R7, oxiranyl, —O—(CO)—NH—R8—NCO and —O—(CO)—R9—(CO)—X; R2 is hydrogen, C1-C4alkyl or C2-C4hydroxyalkyl; R3 and R4 are each independently of the other hydrogen, C1-C4alkyl or C2-C4hydroxyalkyl; R5, R6 and R7 are each independently of the others hydrogen or methyl; R8 is, for example, linear or branched C4-C12alkylene, or phenylene; R9 is, for example, linear or branched C1-C16alkylene, —CH═CH—, —CH═CH—CH2—, C6-cycloalkylene, phenylene or naphthylene; and X, X1 and X2 are each independently of the others OH, Cl, OCH3 or OC2H5; are suitable as photoinitiators that can be incorporated in a formulation to be cured.
    • 式I Y的化合物是例如C 3 -C 12亚烷基,亚丁烯基,亚丁炔基或C 4 -C 12亚烷基被非连续的-O-或-NR 2 - 间隔一次或多次; R1是选自OH,SH,NR3R4, - (CO)-OH, - (CO)-NH2,SO3H,-C(R5)-CR6R7,环氧乙烷基,-O-(CO)-NH-R8- NCO和-O-(CO)-R9-(CO)-X; R2是氢,C1-C4烷基或C2-C4羟烷基; R 3和R 4各自独立地为氢,C 1 -C 4烷基或C 2 -C 4羟烷基; R5,R6和R7各自独立地为氢或甲基; R8是例如直链或支链C 4 -C 12亚烷基或亚苯基; R 9为例如直链或支链C 1 -C 16亚烷基,-CH-CH-,-CH-CH-CH 2 - ,C 6 - 亚环烷基,亚苯基或亚萘基; X,X 1和X 2各自独立地为OH,Cl,OCH 3或OC 2 H 5; 适合作为可引入待固化制剂中的光引发剂。