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    • 31. 发明授权
    • Metal separator for fuel cell and manufacturing method thereof
    • 燃料电池用金属隔板及其制造方法
    • US08298723B2
    • 2012-10-30
    • US12594825
    • 2008-03-05
    • Shinichi TanifujiHirotaka ItoToshiki SatoJun SuzukiYoshinori ItoJun Hisamoto
    • Shinichi TanifujiHirotaka ItoToshiki SatoJun SuzukiYoshinori ItoJun Hisamoto
    • H01M8/04
    • C23C14/22C22C5/02C22C5/04C22C14/00C22C16/00C22C27/02C23C14/16C23C14/165C23C14/345H01M8/0206H01M8/0208H01M8/021H01M8/0228Y02P70/56
    • A metal separator 1 for a fuel cell according to the invention is a metal separator for a fuel cell manufactured by using a metal substrate 2 with a flat surface, or with concave gas flow paths formed on at least a part of the surface. The metal separator 1 includes an acid-resistant metal film 3 formed over the surface of the metal substrate 2, and containing one or more kinds of non-noble metals selected from the group comprised of Zr, Nb, and Ta, and a conductive alloy film 4 formed over the acid-resistant metal film 3, and containing one or more kinds of noble metals selected from the group comprised of Au and Pt, and one or more kinds of non-noble metals selected from the group comprised of Zr, Nb, and Ta. A method for manufacturing the metal separator for a fuel cell according to the invention includes a step S1 of depositing an acid-resistant metal film, and a step S2 of depositing a conductive alloy film. With this structure, the invention provides the metal separator for a fuel cell with an excellent acid resistance and a low contact resistance, and a manufacturing method thereof.
    • 根据本发明的用于燃料电池的金属隔板1是通过使用具有平坦表面的金属基板2或者形成在表面的至少一部分上的凹入气体流路而制造的用于燃料电池的金属隔板。 金属隔板1包括在金属基板2的表面上形成的耐酸金属膜3,并且含有选自Zr,Nb,Ta中的一种以上的非贵金属和导电性合金 在耐酸金属膜3上形成的含有选自Au和Pt的一种或多种贵金属的一种或多种选自Zr,Nb ,和Ta。 根据本发明的燃料电池用金属隔板的制造方法包括沉积耐酸金属膜的工序S1和沉积导电性合金膜的工序S2。 利用该结构,本发明提供了具有优异的耐酸性和低接触电阻的燃料电池用金属隔板及其制造方法。
    • 36. 发明授权
    • Solid polymer type fuel cell separator and method of production of same
    • 固体聚合物型燃料电池隔板及其制造方法
    • US08182961B2
    • 2012-05-22
    • US12224429
    • 2007-02-27
    • Koki TanakaYouichi IkematsuHiroshi KihiraMichio KanekoWataru HisadaTamotsu Itoh
    • Koki TanakaYouichi IkematsuHiroshi KihiraMichio KanekoWataru HisadaTamotsu Itoh
    • H01M8/04
    • H01M8/0228H01M8/0206H01M8/0208H01M8/021H01M8/0213H01M2008/1095Y02P70/56
    • The present invention provides a separator for a solid polymer type fuel cell superior in low contact resistance of the fuel cell separator surface with carbon paper and flatness and a method of production of the same, that is, a separator for a solid polymer type fuel cell comprising a substrate of stainless steel or titanium or a titanium alloy having a surface layer part on which conductive compound particles are fixed, wherein said conductive compound particles are comprised of one or more types of metal borides, metal carbides, and metal nitrides with an average particle size of 0.01 to 20 μm, said conductive compound particles are present in a region from said substrate surface to a depth of 10 μm, and a distribution of concentration of the metal element forming the conductive compound in said region satisfies relations between a concentration C of the metal element forming the conductive compound and a depth x from the substrate surface shown by equation (C=A·exp(−x/t)+B) and equation (10≦A≦90, −4.0≦B≦1.0, 0.5≦t≦4.0).
    • 本发明提供了一种固体聚合物型燃料电池用隔膜,其特征在于,具有碳纸和平坦度的燃料电池隔板表面的低接触电阻优良的固体聚合物型燃料电池及其制造方法,即固体聚合物型燃料电池用隔板 包括不锈钢或钛的基板或具有固定有导电化合物颗粒的表面层部分的钛合金,其中所述导电化合物颗粒由一种或多种金属硼化物,金属碳化物和金属氮化物组成,平均 所述导电化合物颗粒存在于从所述基板表面到10μm深度的区域中,并且在所述区域中形成导电化合物的金属元素的浓度分布满足浓度C 形成导电化合物的金属元素和由式(1)表示的衬底表面的深度x(C = A·exp(-x / t)+ B)和等式<2>(10&nlE; A&nlE; 90,-4.0&nlE; B&nlE; 1.0,0.5&nlE; t&nlE; 4.0)。