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31. 发明授权

US07491317B2 Desulfurization in turbulent fluid bed reactor 有权
标题翻译：湍流床反应器中的脱硫
公开(公告)号：US07491317B2
公开(公告)日：2009-02-17
申请号：US11147045
申请日：2005-06-07
申请人： Paul F. Meier , Max W. Thompson , Victor G. Hoover , Guido R. Germana
发明人： Paul F. Meier , Max W. Thompson , Victor G. Hoover , Guido R. Germana
IPC分类号： C10G45/02
CPC分类号： C10G25/09 , B01J8/1872 , B01J8/26 , B01J8/34 , B01J2208/0084 , B01J2208/00991 , B01J2219/00006 , C10G25/12
摘要： A method and apparatus for removing sulfur from a hydrocarbon-containing fluid stream wherein desulfurization is enhanced by improving the contacting of the hydrocarbon-containing fluid stream and sulfur-sorbing solid particulates in a fluidized bed reactor.
摘要翻译：一种用于从含烃流体物流中除去硫的方法和装置，其中通过改进流化床反应器中含烃流体物流和吸附硫的固体颗粒的接触来增强脱硫。

32. 发明申请

US20060241330A1 Method for separating hydrocarbons and use of a zeolite therefor 失效
标题翻译：烃的分离方法和沸石的使用
公开(公告)号：US20060241330A1
公开(公告)日：2006-10-26
申请号：US10568723
申请日：2004-08-17
申请人： Joeri Denayer , Refik Ocakoglu , Gino Baron
发明人： Joeri Denayer , Refik Ocakoglu , Gino Baron
IPC分类号： C07C7/12
CPC分类号： B01D15/00 , B01D15/08 , B01D15/1821 , B01J20/18 , B01J29/70 , C07C7/12 , C10G25/003 , C10G25/12 , C07C9/00
摘要： A method for separating a mixture of hydrocarbons into fractions enriched in linear, mono-branched, or multi-branched hydrocarbons is disclosed. In particular, mono-branched alkanes are separated from a mixture of alkanes containing multi-branched, mono-branched and linear alkanes, by selectively adsorbing the mono-branched alkanes on a zeolitic adsorbent. The zeolitic adsorbent MCM-22 is particularly suitable for carrying out the method.
摘要翻译：公开了将烃混合物分离成富含线性，单支链或多支链烃的馏分的方法。特别地，通过在沸石吸附剂上选择性吸附单支链烷烃，单链烷烃与含有多支链，单支链和直链烷烃的烷烃的混合物分离。沸石吸附剂MCM-22特别适用于实施该方法。

33. 发明申请

US20050161340A1 PROCESS FOR THE RECOVERY OF MATERIALS FROM A DESULFURIZATION REACTION 有权
标题翻译：从脱硫反应中回收材料的方法
公开(公告)号：US20050161340A1
公开(公告)日：2005-07-28
申请号：US10905782
申请日：2005-01-20
申请人： John Gordon , Ashok Joshi
发明人： John Gordon , Ashok Joshi
IPC分类号： C07F7/04 , C22B3/04 , C22B7/00 , C25C3/02
CPC分类号： C10G25/12 , C10G19/08 , C22B1/08 , C22B3/045 , C22B7/002 , C22B7/007 , C22B23/00 , C22B26/12 , C25B1/24 , C25C3/02 , Y02P10/234
摘要： Disclosed herein is an improved method for regenerating materials from a desulfurization/demetallation reaction. The desulfurization/demetallation reaction preferably has products including one or more of an alkali sulfide, polysulfide or hydrosulfide, or alkali earth sulfide, polysulfide, or hydrosulfide. The method includes the steps of reacting the desulfurization/demetallation products with a halogen, liberating and removing sulfur from the product, and then electrolyzing the halogenated products to separate the halogen from the alkali metal or alkali earth metal.
摘要翻译：本文公开了一种用于从脱硫/脱金属反应再生材料的改进方法。脱硫/脱金属反应优选具有包括碱金属硫化物，多硫化物或氢硫化物或碱土金属硫化物，多硫化物或氢硫化物中的一种或多种的产物。该方法包括以下步骤：使脱硫/脱金属产物与卤素反应，从产物中释放和除去硫，然后电解卤化产物以将卤素与碱金属或碱土金属分离。

34. 发明授权

US06914033B2 Desulfurization and novel compositions for same 有权
标题翻译：脱硫和新型组合物相同
公开(公告)号：US06914033B2
公开(公告)日：2005-07-05
申请号：US10218752
申请日：2002-08-13
申请人： Jason J. Gislason , Robert W. Morton , Roland Schmidt , M. Bruce Welch
发明人： Jason J. Gislason , Robert W. Morton , Roland Schmidt , M. Bruce Welch
IPC分类号： B01J20/02 , B01J20/06 , B01J23/10 , B01J23/16 , B01J23/60 , B01J23/66 , B01J23/83 , B01J23/94 , B01J37/02 , C10G25/00 , C10G25/12
CPC分类号： C10G25/003 , B01J20/02 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/106 , B01J20/3204 , B01J20/3236 , B01J23/10 , B01J23/16 , B01J23/60 , B01J23/66 , B01J23/83 , B01J23/94 , B01J37/0236 , C10G25/12
摘要： A composition comprising a promoter and a metal oxide selected from the group consisting of a cerium oxide, a scandium oxide, a lanthanum oxide, and combinations of any two or more thereof, wherein at least a portion of the promoter is present as a reduced valence promoter and methods of preparing such composition are disclosed. The thus-obtained composition is employed in a desulfurization zone to remove sulfur from a hydrocarbon stream.
摘要翻译：一种组合物，其包含选自氧化铈，氧化钪，氧化镧及其任何两种或更多种的组合的助催化剂和金属氧化物，其中所述助催化剂的至少一部分以降低的价态存在公开了制备这种组合物的启动子和方法。由此获得的组合物用于脱硫区以从烃流中除去硫。

35. 发明申请

US20040251168A1 Process improvement for desulfurization unit 审中-公开
标题翻译：脱硫装置工艺改进
公开(公告)号：US20040251168A1
公开(公告)日：2004-12-16
申请号：US10461077
申请日：2003-06-13
发明人： Paul F. Meier , Steven L. Lacy , Jason J. Gislason
IPC分类号： C10G025/12 , C10G025/00 , C10G029/04 , B01J008/18
CPC分类号： C10G25/12 , B01J8/0035 , B01J8/1872 , B01J8/26 , B01J8/44 , B01J2208/00769 , C10G25/09
摘要： A desulfurization system employing fluidizable and circulatable finely divided solid sorbent particulates that are transported between reactor, regenerator, and reducer vessels. Agglomeration of the sorbent particulates is minimized and circulation of the sorbent particulates is enhanced by controlling the location at which the sorbent particulates are withdrawn from the reducer.
摘要翻译：一种脱硫系统，其采用可流动和可循环的细分固体吸附剂颗粒，其在反应器，再生器和还原剂容器之间运输。通过控制吸附剂微粒从还原剂中排出的位置，使吸附剂颗粒的聚集最小化并吸收剂颗粒的循环得到增强。

36. 发明授权

US06635795B2 Desulfurization with improved sorbent regeneration 有权
标题翻译：改进吸附剂再生脱硫
公开(公告)号：US06635795B2
公开(公告)日：2003-10-21
申请号：US10025343
申请日：2001-12-19
申请人： Jason J. Gislason , Ronald E. Brown , Robert W. Morton , Glenn W. Dodwell
发明人： Jason J. Gislason , Ronald E. Brown , Robert W. Morton , Glenn W. Dodwell
IPC分类号： C10G2904
CPC分类号： C10G25/12 , B01J20/06 , B01J20/3433 , B01J20/3458 , C10G25/003
摘要： While contacting under regeneration conditions an oxygen-containing stream with a sorbent comprising a promoter metal and zinc sulfide which has been sulfurized by contact with sulfur-containing hydrocarbons such as cracked-gasolines and diesel fuel, the oxygen partial pressure is controlled in a range of 0.5 to 2.0 psig to minimize sulfation of the sorbent.
摘要翻译：当在再生条件下接触含氧流与包含助催化剂金属和硫化锌的吸附剂，其通过与含硫烃如裂化汽油和柴油燃料接触而被硫化时，将氧分压控制在 0.5至2.0psig以使吸附剂的硫酸化最小化。

37. 发明授权

US06544410B1 Desulfurization with improved sorbent regeneration 有权
标题翻译：改进吸附剂再生脱硫
公开(公告)号：US06544410B1
公开(公告)日：2003-04-08
申请号：US10025345
申请日：2001-12-19
申请人： Jason J. Gislason , Ronald E. Brown , Robert W. Morton , Glenn W. Dodwell
发明人： Jason J. Gislason , Ronald E. Brown , Robert W. Morton , Glenn W. Dodwell
IPC分类号： B01J3804
CPC分类号： C10G25/12 , B01J20/0244 , B01J20/06 , B01J20/08 , B01J20/3433 , B01J20/3458 , C10G25/003
摘要： During the regeneration of a sulfurized sorbent comprising zinc aluminate, a promoter metal and zinc sulfide by contact with an oxygen-containing stream to convert at least a portion of said zinc sulfide to zinc oxide the average sulfur dioxide partial pressure in the regeneration zone is controlled within the range of from about 0.1 to about 10 psig to minimize sulfation of the sorbent.
摘要翻译：在通过与含氧流接触以将至少一部分所述硫化锌转化为氧化锌的含铝酸锌，助催化剂金属和硫化锌的硫化吸附剂的再生期间，控制再生区中的平均二氧化硫分压在约0.1至约10psig的范围内，以使吸附剂的硫酸化最小化。

38. 发明授权

US5520798A Process for reforming hydrocarbon feedstocks over a sulfur sensitive catalyst 失效
标题翻译：在硫敏感催化剂上重整烃原料的方法
公开(公告)号：US5520798A
公开(公告)日：1996-05-28
申请号：US264439
申请日：1994-06-23
申请人： Robert A. Innes
发明人： Robert A. Innes
IPC分类号： B01J29/62 , C10G25/00 , C10G25/05 , C10G25/08 , C10G25/12 , C10G35/04 , C10G35/095 , C10G35/10 , C10G35/12 , C10G45/02 , C10G45/10 , C10G45/12 , C10G45/18 , C10G45/62 , C10G45/64 , C10G61/06 , C10G35/09
CPC分类号： B01J8/12 , C10G25/003 , C10G25/08 , C10G25/12 , C10G35/12 , C10G45/10 , C10G45/18 , C10G45/62 , C10G45/64 , C10G61/06
摘要： Provided is a process for catalytically reforming a hydrocarbon feedstock using a highly sulfur sensitive catalyst. The process comprises contacting the hydrocarbon in a reaction zone, with the hydrocarbon feed and catalyst flowing in opposite directions. Once the catalyst has passed through the reaction zone, it is then passed to a regeneration zone for regeneration. The process eliminates the need of passing the hydrocarbon feed through a sulfur sorber prior to entry into the reaction zone, as the spent catalyst which is leaving the reaction zone for regeneration acts as a sulfur sorber and removes the sulfur from the feed entering the reaction zone.
摘要翻译：提供了一种使用高度硫敏感的催化剂催化重整烃原料的方法。该方法包括使反应区中的烃与在相反方向上流动的烃进料和催化剂接触。一旦催化剂通过反应区，然后将其送入再生区再生。该方法消除了在进入反应区之前使烃进料通过硫吸收剂的需要，因为离开反应区进行再生的废催化剂用作硫吸附剂并从进入反应区的进料中除去硫。

39. 发明授权

US4831207A Chemical processing with an operational step sensitive to a feedstream component 失效
标题翻译：具有对进料流组分敏感的操作步骤的化学处理
公开(公告)号：US4831207A
公开(公告)日：1989-05-16
申请号：US187844
申请日：1988-04-29
申请人： Luke F. O'Keefe , Warren Volles , Andrew S. Zarchy
发明人： Luke F. O'Keefe , Warren Volles , Andrew S. Zarchy
IPC分类号： C10G25/00 , C10G25/12 , C10G67/06
CPC分类号： C10G25/12 , C10G25/00 , C10G67/06 , Y10S502/517
摘要： The present invention relates to a chemical process involving a processing step which is sensitive to the presence of at least one component contained within the stream to be processed and to an economical and efficient method of temporarily removing such deleterious component from the stream so as to have the deleterious component by-pass the step which is sensitive to this component using an adsorbent for such removal wherein the adsorbent is regenerated by the product effluent stream leaving the sensitive processing step.
摘要翻译：本发明涉及一种化学方法，该方法涉及对待处理流中所含的至少一种组分的存在敏感的加工步骤以及从流中临时除去这些有害成分的经济有效的方法，以便具有有害组分通过对该组分敏感的步骤使用用于这种去除的吸附剂，其中吸附剂由离开敏感加工步骤的产物流出物流再生。

40. 发明授权

US4412914A Endothermic removal of coke deposited on sorbent materials during carbo-metallic oil conversion 失效
标题翻译：在碳 - 金属油转化期间吸附沉积在吸附剂材料上的焦炭的吸热除去
公开(公告)号：US4412914A
公开(公告)日：1983-11-01
申请号：US291656
申请日：1981-08-10
申请人： William P. Hettinger, Jr. , James F. Hoffman , Stephen M. Kovach
发明人： William P. Hettinger, Jr. , James F. Hoffman , Stephen M. Kovach
IPC分类号： C10G25/06 , C10G25/12 , C10G29/04
CPC分类号： C10G25/06 , C10G25/12
摘要： A process is disclosed for decarbonization-demetallization of a poor quality residual oil feed boiling above about 650.degree. F. and comprising substantial Conradson carbon components to provide a higher grade of oil feed by contacting the poor quality oil feed with sorbent particle material containing one or more metal additives selected to catalyze the endothermic removal of coke with CO.sub.2. Sorbent decarbonization conditions are selected so that substantial quantities of carbonaceous material and metals are deposited on the sorbent in the decarbonizing zone. Sorbent material with metals and hydrocarbonaceous deposits is regenerated in the presence of an oxygen and carbon dioxide containing gas streams in separate sorbent regeneration zones at a temperature sufficiently elevated to remove residual coke to a desired low level. Regenerated sorbent particle material at an elevated temperature below about 1500.degree. F. is recycled to the poor quality oil feed decarbonizing zone for contact with additional feed. A select metal additive is provided in the sorbent particle material in an amount sufficient to particularly catalyze the endothermic removal of coke in the presence of a carbon dioxide rich gas at a selected sorbent regeneration temperature. A sorbent particle composition suitable for use in the process comprises a kaolin clay containing one or more of the metal additives which may be introduced into the clay during the oil feed decarbonizing process or during sorbent manufacture. Metal additives include water soluble inorganic metal salts and hydrocarbon soluble organo-metallic compounds of a select group of metals.
摘要翻译：公开了一种在约650°F以上沸腾的质量差的剩余油料进行脱碳脱金属脱蜡的方法，并且包括大量的康拉逊碳组分，以通过使劣质油料与含有一种或多种的选择更多的金属添加剂来催化焦炭与CO 2的吸热去除。选择吸附剂脱碳条件使得大量的含碳材料和金属沉积在脱碳区的吸附剂上。具有金属和含烃沉积物的吸附剂材料在含有氧和二氧化碳的气流存在下在分离的吸附剂再生区中在足够升高的温度下再生以除去残留的焦炭至所需的低水平。在高于约1500°F的高温下再生的吸附剂颗粒材料被再循环到劣质的进料脱碳区域以与另外的进料接触。在吸附剂颗粒材料中提供选择金属添加剂，其量足以特别催化在选择的吸附剂再生温度下在富二氧化碳气体存在下吸热除去焦炭。适用于该方法的吸附剂颗粒组合物包含含有一种或多种金属添加剂的高岭土，其可在进油脱碳过程期间或在吸附剂制备期间引入粘土中。金属添加剂包括一组金属的水溶性无机金属盐和可溶于烃的有机金属化合物。

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