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31. 发明授权

US4629764A Polymer modified polyphenol compositions and thermosettable resins thereof 失效
标题翻译：聚合物改性多酚组合物及其热固性树脂
公开(公告)号：US4629764A
公开(公告)日：1986-12-16
申请号：US843523
申请日：1986-03-24
申请人： Robert E. Hefner, Jr.
发明人： Robert E. Hefner, Jr.
IPC分类号： C08G59/02 , C08G59/06 , C08F8/00
CPC分类号： C08G59/063 , C08G59/02
摘要： A composition comprising (A) a polyphenol such as bisphenol A, (B) a polymer resulting from polymerizing (1) an alkenyl phenol such as p-isopropenylphenol and (2) a polymerizable ethylenically unsaturated monomer such as 2-ethylhexyl acrylate can be converted to a copolymer modified polycyanate by reaction with a cyanogen halide such as cyanogen chloride in the presence of a base such as triethylamine. These polycyanates can be cured by trimerization in the presence of a suitable catalyst or by copolymerization with an epoxy resin. Epoxy resins can also be prepared from the composition comprising components (A) and (B) by reaction with an epihalohydrin such as epichlorohydrin and subsequent dehydrohalogenation with a basic acting compound such as a sodium hydroxide.
摘要翻译：包含（A）多酚如双酚A的组合物，（B）聚合产生的聚合物（1）链烯基苯酚如对异丙烯基苯酚和（2）可聚合烯属不饱和单体如丙烯酸2-乙基己酯可以转化通过在诸如三乙胺的碱的存在下与卤化氰如氯化氰反应而与共聚物改性的聚氰酸酯反应。这些聚氰化物可以在合适的催化剂存在下通过三聚化或通过与环氧树脂共聚来固化。环氧树脂也可以通过与表卤代醇如表氯醇反应，然后与碱性作用化合物如氢氧化钠进行脱卤化氢，由包含组分（A）和（B）的组合物制备。

32. 发明授权

US4337367A Oligomer of m-isopropenylphenol 失效
标题翻译：间 - 异丙烯基苯酚的低聚物
公开(公告)号：US4337367A
公开(公告)日：1982-06-29
申请号：US106845
申请日：1979-12-26
申请人： Shuichi Kanagawa , Shinji Nakao , Kiyoshi Nakai , Kunimasa Kamio , Shunsuke Matsushima , Kazuhiko Hata , Kentaro Mashita
发明人： Shuichi Kanagawa , Shinji Nakao , Kiyoshi Nakai , Kunimasa Kamio , Shunsuke Matsushima , Kazuhiko Hata , Kentaro Mashita
IPC分类号： C08G59/00 , C08G59/06 , C08G59/32 , C07C39/12 , C07C39/06
CPC分类号： C08G59/063 , C08G59/3218
摘要： An oligomer of m-isopropenylphenol is produced by subjecting m-isopropenylphenol to thermal polymerization in the absence of a catalyst.
摘要翻译：间 - 异丙烯基苯酚的低聚物是通过在不存在催化剂的情况下使间 - 异丙烯基苯酚进行热聚合而制备的。

33. 发明授权

US4307223A Solid resin prepared by polymerizing by-product tar formed during preparation of resorcinol 失效
标题翻译：通过聚合在间苯二酚制备过程中形成的副产物焦油制备的固体树脂
公开(公告)号：US4307223A
公开(公告)日：1981-12-22
申请号：US45624
申请日：1979-06-05
申请人： Akira Shintani , Katsuo Akagane , Yasuhisa Saito , Takashi Urata, deceased
发明人： Akira Shintani , Katsuo Akagane , Yasuhisa Saito , Takashi Urata, deceased
IPC分类号： C08L61/00 , C08G18/00 , C08G18/64 , C08G59/00 , C08G59/06 , C08G59/62 , C08G61/00 , C08G61/02 , C08G65/38 , C08G85/00 , C08L61/04 , C08L61/06 , C08L63/00 , C08L65/00 , C08G65/40
CPC分类号： C08G85/00 , C08G18/64 , C08G59/063 , C08G59/621 , C08G61/02 , C08G65/38 , C08L63/00 , Y10T428/31678 , Y10T428/31688
摘要： A solid resinous product useful for coatings, adhesives and molding materials which is obtained by polymerizing a by-product tar produced as by-product in manufacturing resorcinol or resorcinol and hydroquinone via hydroperoxide of m-diisopropylbenzene or of a combination of m- and p-diisorpopylbenzenes and containing m-substituted phenolic constituents or a combination of m- and p-substituted phenolic constituents as major constituents.
摘要翻译：用于涂料，粘合剂和成型材料的固体树脂产品，其通过聚合在制备间苯二酚或间苯二酚和氢醌中作为副产物生产的副产物焦油，其通过间二异丙基苯的氢过氧化物或m-和对 - 二异丙基苯并且含有m取代的酚成分或作为主要成分的m取代和对取代的酚成分的组合。

34. 发明授权

US4215210A Novel .alpha.-glycol resin composition and process for its preparation 失效
标题翻译：新型α-乙二醇树脂组合物及其制备方法
公开(公告)号：US4215210A
公开(公告)日：1980-07-29
申请号：US914161
申请日：1978-06-09
申请人： Kiyoaki Okayama , Yojiro Yamamoto
发明人： Kiyoaki Okayama , Yojiro Yamamoto
IPC分类号： C08G65/00 , C08G59/06 , C08G65/40 , C08G65/48 , C08L71/00 , C08L71/08 , C08G65/28
CPC分类号： C08G59/063
摘要： A novel resin composition which is composed of molecules having an epi-bis type main skeleton of the formula ##STR1## X.sub.1 -X.sub.4 : H, Cl or Br R: H, or CH.sub.3and has a Gardner-Holdt viscosity of C to Z.sub.8 determined at 25.degree. C. for a solution in butyl carbitol in a concentration of 40% by weight.At least 40% of the entire terminal groups of the molecules of the novel composition consists of .alpha.-glycol groups of the formula ##STR2## wherein R represents hydrogen or methyl. The composition is more rapidly curable at lower temperatures than known epoxy resins having an epi-bis type main chain skeleton, and is useful as a paint or adhesive and also as an adhesion improver for other resins.
摘要翻译：一种新型的树脂组合物，其由具有下式的外延双型主骨架的分子组成：具有下式的化合物：X1，X4：H，Cl或BrR：H或CH3，并具有加德纳 - 至Z8，在25℃下测定浓度为40重量％的丁基卡必醇溶液。新型组合物的分子的整个末端基团的至少40％由式“IMAGE”的α-二醇基团组成，其中R表示氢或甲基。该组合物在比具有外延双主链骨架的已知环氧树脂更低的温度下可更快固化，并且可用作涂料或粘合剂，并且还可用作其它树脂的粘合改进剂。

35. 发明授权

US4130549A Process for preparing epoxy resins from hydroxy benzoic acid and bisphenol 失效
标题翻译：由羟基苯甲酸和双酚制备环氧树脂的方法
公开(公告)号：US4130549A
公开(公告)日：1978-12-19
申请号：US879520
申请日：1978-02-21
申请人： Ryuzo Ueno , Hiroyasu Matsumoto
发明人： Ryuzo Ueno , Hiroyasu Matsumoto
IPC分类号： C08G59/00 , C08G59/02 , C08G59/06 , C08G59/12 , C08G59/24
CPC分类号： C08G59/063 , C08G59/02
摘要： A process for preparing an epoxy resin, which comprises reacting p-hydroxybenzoic acid and bisphenol A with an epihalohydrin in the presence of a base using a quaternary ammonium salt as a catalyst, the amount of the p-hydroxybenzoic acid being 10 to 90 mole% and the amount of the bisphenol A being 90 to 10 mole%, both based on the total amount of the hydroxybenzoic acid and bisphenol A.
摘要翻译：一种制备环氧树脂的方法，其包括使用季铵盐作为催化剂在碱的存在下使对羟基苯甲酸和双酚A与表卤代醇反应，对羟基苯甲酸的量为10至90摩尔％双酚A的量为90〜10摩尔％，均基于羟基苯甲酸和双酚A的总量。

36. 发明授权

US3957832A Epoxy resins prepared from polyhydroxy-containing compounds 失效
标题翻译：由含羟基化合物制备的环氧树脂
公开(公告)号：US3957832A
公开(公告)日：1976-05-18
申请号：US529323
申请日：1974-12-04
申请人： Wilbur L. Bressler , Clyde G. Taylor
发明人： Wilbur L. Bressler , Clyde G. Taylor
IPC分类号： C07C43/295 , C07C45/46 , C07C49/84 , C07D303/24 , C07D303/30 , C08G59/06 , C08G59/32 , C07D303/26
CPC分类号： C08G59/3218 , C07C43/295 , C07C45/46 , C07C49/84 , C07D303/24 , C07D303/30 , C08G59/063
摘要： New polyhydroxy-containing compounds represented by the formula ##SPC1##Wherein A is --O-- or an alkylidene group having 1 to 4 carbon atoms, Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 are independently selected from --OH or ##SPC2##(wherein R is selected from hydrogen, a halogen atom and an alkyl group having 1 to 4 carbon atoms), X and X.sub.1 are independently selected from hydrogen, a halogen atom or the group ##SPC3##(wherein R is as defined above), R.sub.1 and R.sub.2 are selected from hydrogen, a hydroxyl group, and an alkyl group having from 1-4 carbon atoms, m is the number 0 or 1 and n and n.sub.1 are numbers independently selected from 1 to 20. A process for their preparation is disclosed as well as new epoxy resins prepared therefrom which may be represented by the formula ##SPC4##Wherein A, m, n, and n.sub.1 are defined above and Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 are independently selected from --OH and the group ##EQU1## (wherein R is selected from hydrogen, a halogen atom or an alkyl group having from 1 to 4 carbon atoms), R.sub.1 and R.sub.2 are selected from hydrogen, and alkyl group having from 1 to 4 carbon atoms and the group ##EQU2## X and X.sub.1 are independently selected from hydrogen, a chlorine group and the group ##EQU3## (wherein R is as defined above), m is a number selected from 0 and 1 and n and n.sub.1 are numbers independently selected from 1 to 20 wherein at least 2 of the groups selected from Y.sub.1, Y.sub.2, Y.sub.3, Y.sub.4, X and X.sub.1 are the group ##EQU4##

37. 发明授权

US3553165A Method for the preparation of poly-epoxy condensates 失效
标题翻译：聚环氧树脂的制备方法
公开(公告)号：US3553165A
公开(公告)日：1971-01-05
申请号：US3553165D
申请日：1966-04-28
申请人： CHIYODA CHEM ENG CONSTRUCT CO
发明人： KIRYU TOMOO
IPC分类号： C08G59/06 , C08G30/04
CPC分类号： C08G59/063
摘要： EPOXY RESINS HAVING A MAXIMUM SOFTENING POINT ABOVE 95-97*C. ARE PREPARED BY CONDENSATION OF B-METHYL EPICHLOROHYDRIN OR B-CHLOROMETHYL EPICHLOROHYDRIN WITH BISPHENOL-A IN A SINGLE REACTION STEP IN THE ABSENCE OF A SOLVENT OTHER THAN DIOXANE.

38. 发明授权

US3522210A Curable polyglycidyl ethers of a dihydric phenol,containing flexible linkages 失效
标题翻译：含有灵活连接的二羟基苯酚的可固化多羟基化合物
公开(公告)号：US3522210A
公开(公告)日：1970-07-28
申请号：US3522210D
申请日：1965-03-01
申请人： UNION CARBIDE CORP
发明人： SELLERS RALPH F , SMITH SAMUEL G JR
IPC分类号： C08G59/06 , C08G59/24 , C08G30/10
CPC分类号： C08G59/245 , C08G59/063

39. 发明授权

US3494939A Glycidoxy - bisnuclear - phenolic ethers of oxa-substituted aliphatic diols and triols 失效
标题翻译：甘氨酸 - 双酚 - 氧化替代二恶烷和三酚的酚醛
公开(公告)号：US3494939A
公开(公告)日：1970-02-10
申请号：US3494939D
申请日：1967-09-25
申请人： MINNESOTA MINING & MFG
发明人： SMITH CARL M
IPC分类号： C07D303/24 , C08F20/30 , C08G59/06 , C08G65/329 , C08G65/332 , C08G65/334 , C07D1/00 , C08G33/10
CPC分类号： C07D303/24 , C08F20/30 , C08G59/063 , C08G65/329 , C08G65/3322 , C08G65/3346

40. 发明授权

US3401147A Epoxy resins from bisphenols of 3, 9-divinyl spirobi 失效
标题翻译：来自3,9-二乙烯基螺的双酚的环氧树脂
公开(公告)号：US3401147A
公开(公告)日：1968-09-10
申请号：US58693166
申请日：1966-10-17
申请人： UNION CARBIDE CORP
发明人： SMITH JR SAMUEL G , SELLERS RALPH F , BURHANS ALLISON S
IPC分类号： C07D493/10 , C08G59/06 , C08G59/26
CPC分类号： C07D493/10 , C08G59/063 , C08G59/26

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