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31. 发明授权

US4397787A Rhodium complexes containing chiral phosphine ligands useful as hydrogenation catalysts 失效
标题翻译：含有可用作氢化催化剂的手性膦配体的铑络合物
公开(公告)号：US4397787A
公开(公告)日：1983-08-09
申请号：US340443
申请日：1982-01-18
申请人： Dennis P. Riley
发明人： Dennis P. Riley
IPC分类号： B01J31/00 , B01J31/24 , C07C29/147 , C07C51/36 , C07D209/20 , C07F9/50 , C07F15/00
CPC分类号： C07F15/00 , B01J31/2291 , B01J31/2295 , B01J31/2409 , B01J31/2414 , C07C29/147 , C07C51/36 , C07D209/20 , C07F15/0073 , C07F9/5027 , B01J2231/645 , B01J2531/821 , B01J2531/822
摘要： Rhodium (1) complexes containing the chiral phosphine ligand (R)-1,2-bis(diphenylphosphino)-1-cyclohexylethane which are useful as chiral hydrogenation catalysts. These catalysts are especially useful in the chiral hydrogenation of alpha-acylamido acrylic acids.
摘要翻译：含有可用作手性氢化催化剂的手性膦配体（R）-1,2-二（二苯基膦基）-1-环己基乙烷的铑（1）络合物。这些催化剂特别可用于α-酰基酰氨基丙烯酸的手性氢化。

32. 发明授权

US4370488A Alkali metal complex compounds 失效
标题翻译：碱金属络合物
公开(公告)号：US4370488A
公开(公告)日：1983-01-25
申请号：US274947
申请日：1981-06-18
申请人： Borislav Bogdanovic
发明人： Borislav Bogdanovic
IPC分类号： C07C49/92 , B01J31/00 , B01J31/16 , B01J31/22 , C01B6/04 , C01B21/06 , C07C45/00 , C07C67/00 , C07C325/00 , C07C325/02 , C07C327/10 , C07C327/18 , C07D307/06 , C07D339/04 , C07D495/04 , C07F1/00 , C07F1/02 , C07F1/04 , C07F1/06 , C07C57/03 , C07C153/023
CPC分类号： B01J31/2204 , B01J31/1805 , B01J31/2291 , B01J31/2295 , C01B21/0607 , C01B21/061 , C01B6/04 , C07D339/04 , C07D495/04 , C07F1/005 , B01J2231/62 , B01J2531/10 , B01J2531/11 , B01J2531/12
摘要： The invention includes novel alkali metal complex compounds (and processes for their preparation) which are useful, inter alia for the hydrogenation of alkali metals at room temperature or below room temperature to form hydrides or nitrides.
摘要翻译：本发明包括新的碱金属络合物（及其制备方法），其特别用于在室温或低于室温下氢化碱金属以形成氢化物或氮化物。

33. 发明授权

US4243824A Zero-valent rhodium catalyst hydrogenation 失效
标题翻译：零价铑催化剂氢化
公开(公告)号：US4243824A
公开(公告)日：1981-01-06
申请号：US88242
申请日：1979-10-25
申请人： Jan G. Noltes , Gerard van Koten , Murray S. Cohen
发明人： Jan G. Noltes , Gerard van Koten , Murray S. Cohen
IPC分类号： B01J31/16 , B01J31/22 , C07C5/03 , C07C5/08 , C07C5/10
CPC分类号： C07C5/10 , B01J31/2291 , B01J31/2295 , C07C5/03 , C07C5/08 , B01J2231/645 , B01J2231/646 , B01J2531/822 , C07C2531/22
摘要： A process for the preparation of novel zero-valent rhodium catalysts. The catalysts are prepared by the reaction of a hydrocarbyl-lithium compound with a hydrocarbon-soluble complex of a rhodium halide and a ligand. The catalyst may, if desired, be deposited on a support such as alumina or silica. It is effective to catalyze the hydrogenation of organic compounds such as benzene, styrene and the like.
摘要翻译：一种制备新型零价铑催化剂的方法。催化剂通过烃基锂化合物与卤化铑和配体的烃溶性络合物的反应制备。如果需要，催化剂可以沉积在载体如氧化铝或二氧化硅上。催化苯，苯乙烯等有机化合物的氢化是有效的。

34. 发明授权

US4195039A Heterogeneous phase oxidation of olefins to ketones 失效
标题翻译：烯烃异构相氧化成酮
公开(公告)号：US4195039A
公开(公告)日：1980-03-25
申请号：US966847
申请日：1978-12-05
申请人： Hubert Mimoun , Robert Charpentier
发明人： Hubert Mimoun , Robert Charpentier
IPC分类号： B01J27/06 , B01J31/16 , B01J31/18 , B01J31/22 , B01J31/30 , C07C45/34 , C07C45/35 , C07C27/12 , C07C45/04
CPC分类号： C07C45/35 , B01J27/06 , B01J31/1616 , B01J31/1805 , B01J31/2291 , B01J31/2295 , B01J31/30 , C07C45/34 , B01J2531/16 , B01J2531/72 , B01J2531/822 , B01J2531/824 , B01J2531/842 , B01J2531/845
摘要： Process for manufacturing solid catalysts, useful for oxidizing olefins containing from 2 to 16 carbon atoms per molecule to the corresponding carbonyl derivatives, comprising the step of impregnating a carrier with a substantially non-aqueous solution, containing at least two components [A] and [B] of the general formulas:[A]=M.sub.1 X.sub.n L.sub.m[B]=M.sub.2 Z.sub.p L'.sub.qwherein M.sub.1 is rhodium or palladium, X and Z are each an anionic group, n and p are integers selected from 1, 2 and 3, m being an integer selected from 1, 2, 3 and 6 or being O, M.sub.2 is a metal selected from iron, copper, manganese and cobalt, q is an integer selected from 1 to 6 or is equal to O and L and L' are each a coordinate selected from water or an organic compound, said impregnation being conducted in the presence of at least one halogen, a halohydric acid or an organic or inorganic halide.
摘要翻译：制备固体催化剂的方法，其用于将每分子含有2至16个碳原子的烯烃氧化成相应的羰基衍生物，其包括用至少两种组分[A]和[ B]的通式：[A] = M1XnLm [B] = M2ZpL'q其中M1是铑或钯，X和Z各自是阴离子基团，n和p是选自1,2和3的整数，m是选自1,2,3或6的整数或为O，M2为选自铁，铜，锰和钴的金属，q为选自1至6或等于0的整数，L和L'分别为选自水或有机化合物的坐标，所述浸渍在至少一种卤素，卤代酸或有机或无机卤化物存在下进行。

35. 发明授权

US4176085A Palladium-containing catalyst 失效
标题翻译：含钯催化剂
公开(公告)号：US4176085A
公开(公告)日：1979-11-27
申请号：US585227
申请日：1975-06-09
申请人： Jin S. Yoo , Ronald L. Milam
发明人： Jin S. Yoo , Ronald L. Milam
IPC分类号： B01J31/24 , C07C2/04 , B01J31/22
CPC分类号： B01J31/1616 , B01J31/122 , B01J31/143 , B01J31/2291 , B01J31/24 , C07C2/04 , C08F10/00 , C08F210/02 , B01J2231/12 , B01J2531/824 , C07C2521/12 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Solid .pi.-allyl complex catalysts comprising:(A) A palladium source;(B) A monotertiary phosphine electron donor ligand;(C) A combination of a reducing agent capable of reducing the palladium source to an oxidation state of less than 2 and a Lewis acid capable of forming a coordination bond with palladium; and(D) An acidic, solid, silica-based support material, are useful in the codimerization of a conjugated diene and a monoene. Preferably, the catalyst is activated by the additional presence of a conjugated diene. In a preferred embodiment, the solid .pi.-allyl palladium complex catalyst prepared from palladium acetylacetonate, triphenylphosphine, diethylaluminum chloride and a calcined silica-alumina support having a separate, distinct alumina phase is useful in the selective codimerization of 1,3-butadiene and ethylene to form trans-1,4-hexadiene.
摘要翻译：包括：（A）钯源; （B）单子膦电子供体配体; （C）能够将钯源还原成氧化态小于2的还原剂和能够与钯形成配位键的路易斯酸的组合; 和（D）酸性固体二氧化硅基载体材料可用于共轭二烯和单烯的共聚。优选地，通过额外存在共轭二烯活化催化剂。在优选的实施方案中，由乙酰丙酮钯，三苯基膦，二乙基氯化铝和具有单独的不同氧化铝相的煅烧二氧化硅 - 氧化铝载体制备的固体pi烯丙基钯配合物催化剂可用于1,3-丁二烯和乙烯的选择性同工化以形成反式-1,4-己二烯。

36. 发明授权

US4028384A Process for the preparation of organic silicon compounds 失效
标题翻译：制备有机硅化合物的方法
公开(公告)号：US4028384A
公开(公告)日：1977-06-07
申请号：US418793
申请日：1973-11-23
申请人： Hans-Joachim Vahlensieck , Claus-Dieter Seiler , Hans-Joachim Kotzsch
发明人： Hans-Joachim Vahlensieck , Claus-Dieter Seiler , Hans-Joachim Kotzsch
IPC分类号： B01J31/22 , C07F7/14 , C07F7/18 , C07D307/12 , C07F7/02
CPC分类号： C07F7/1804 , B01J31/2208 , B01J31/2291 , C07F7/14 , B01J2231/323 , B01J2531/828
摘要： The use of certain chloroplatinic complex compounds of the formula:[Pt R.sup.1 Cl.sub.2 ].sub.awherein a is 1 or 2 and R.sup.1 is an unsaturated ketone residue, to catalyze the addition of alkoxy, aryloxy or halo hydrogen silanes to aliphatically unsaturated compounds (carbon to carbon unsaturation such as olefins and/or acetylenes). The products of the reaction can be used as additives for plastics and synthetic resins.
摘要翻译：使用下列化学式的某些氯铂配合物：

37. 发明授权

US3962294A Olefin isomerization catalysts and process 失效
标题翻译： OLEFIN异构催化剂和方法
公开(公告)号：US3962294A
公开(公告)日：1976-06-08
申请号：US575872
申请日：1975-05-09
申请人： James E. Lyons
发明人： James E. Lyons
IPC分类号： B01J31/24 , C07F15/00
CPC分类号： B01J31/2291 , B01J31/20 , B01J31/24 , B01J31/2404 , C07F15/0046 , B01J2231/52 , B01J2531/821
摘要： The activity of olefin isomerization catalysts such as RuCl.sub.2 (Ph.sub.3 P).sub.3 may be substantially enhanced in the presence of compounds which are readily decarbonylated by RuCl.sub.2 (Ph.sub. 3 P).sub.3 to form carbonyl derivatives of said catalysts.

38. 发明授权

US3912786A Process for producing bicyclo-(3,3,0)-octene-(2) 失效
标题翻译：二（3,3,0） - 碳酸酯（2）的制备方法
公开(公告)号：US3912786A
公开(公告)日：1975-10-14
申请号：US44494974
申请日：1974-02-22
申请人： STUDIENGESELLSCHAFT KOHLE MBH
发明人： WILKE GUNTHER , BOGDANOVIC BORISLAV , NUSSEL HANS-GEORG
IPC分类号： B01J31/14 , B01J31/22 , B01J31/26 , C07C5/31 , C07C13/00
CPC分类号： B01J31/2226 , B01J31/143 , B01J31/2234 , B01J31/2291 , B01J31/2295 , B01J31/26 , B01J2231/52 , B01J2531/847 , C07C5/31 , C07C13/44
摘要： Bicyclo-(3,3,0)-octene-(2) is prepared with quantitative conversion and in high yields at substantially room temperature and high reaction rate with the use of a catalytic mixture of nickel compounds and aluminum compounds. The resulting bicyclooctene is a valuable monomer for the production of a high molecular weight polyolefin or a starting material for alicyclic dicarboxylic acids.

39. 发明授权

US3867343A Catalysts and use thereof 失效
标题翻译：催化剂及其用途
公开(公告)号：US3867343A
公开(公告)日：1975-02-18
申请号：US41116673
申请日：1973-10-30
申请人： ICI LTD
发明人： GARDEN WILLIAM DAVID
IPC分类号： B01J31/22 , B01J31/24 , C07F7/08 , C08L83/04 , C08F11/04
CPC分类号： B01J31/124 , B01J31/0237 , B01J31/0247 , B01J31/1805 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/22 , B01J31/226 , B01J31/2291 , B01J31/2295 , B01J31/24 , B01J31/2404 , B01J2531/828 , C08G77/08 , C08G77/12 , C08G77/16 , C08L83/04 , C08L83/00 , C08L2666/52
摘要： New catalysts consisting of a platinum complex and ammonia or derivative thereof, use of such catalysts to confer longer bath lives on compositions containing siloxanes containing SiOH groups and siloxanes containing SiH groups and solventless catalysed compositions.
摘要翻译：由铂络合物和氨或其衍生物组成的新型催化剂使用这种催化剂使含有SiOH基团的硅氧烷和含有SiH基的硅氧烷和无溶剂催化组合物的组合物具有更长的浴寿命。

40. 发明授权

US3840612A Disproportionation of olefins 失效
标题翻译：油脂的分解
公开(公告)号：US3840612A
公开(公告)日：1974-10-08
申请号：US23619972
申请日：1972-03-20
申请人： ICI LTD
发明人： THOMAS H , ATTRIDGE C , MORRIS A
IPC分类号： B01J31/22 , C07C6/04 , C07F11/00 , C07F13/00 , C07C3/62
CPC分类号： B01J31/2295 , B01J21/04 , B01J21/08 , B01J31/122 , B01J31/1608 , B01J31/1625 , B01J31/2291 , B01J2231/543 , B01J2531/0211 , B01J2531/64 , B01J2531/66 , B01J2531/74 , C07C6/04 , C07C2531/12 , C07C2531/22 , C07F11/00 , C07F13/00 , Y10S585/906 , Y10S585/951 , Y10S585/953
摘要： 1. A PROCESS FOR THE DISPROPORTIONATION OF ALIPHATIC OLEFINICALLY UNSATURATED HYDROCARBON IN WHICH THE ALIPHATIC OLEFINICALLY UNSATURATED HYDROCARBON IS CONTACTED WITH AN INITIATOR WHICH IS THE PRODUCT OF REACTING UNDER ANHYDROUS AND OXYGEN-FREE CONDITIONS A TRANSITION METAL COMPLEX OF EMPIRICAL FORMULA

RMMXP

WITH A SUBSTANTIALLY INERT INORGANIC OXIDE MATRIX MATERIAL HAVING A HYDROXYLIC SURFACE WHICH IS FREE FROM ADSORBED WATER AND WHICH IS CAPABLE OF REACTING WITH THE TRANSITION METAL COMPLEX, WHEREIN M IS MOLYBDENUM, TUNGSTEN OR RHENIUM, R IS HYDROCARBON GROUP OR A SUBSTITUTED HYDROCARBON GROUP, X IS A MONOVALENT LIGAND AND M AND P ARE INTEGERS, M HAVING A VALUE OF FROM 2 UP TO THE HIGHEST VALENCE OF THE METAL M AND P HAVING A VALUE FROM 0 UP TO 2 LESS THAN THE VALENCE OF THE METAL M.

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