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31. 发明授权

US6010974A Carbon and/or silicon bridged binuclear metallocene catalyst for styrene polymerization 失效
标题翻译：用于苯乙烯聚合的碳和/或硅桥联双核金属茂催化剂
公开(公告)号：US6010974A
公开(公告)日：2000-01-04
申请号：US844109
申请日：1997-04-28
申请人： Hyun-Joon Kim , Yi-yeol Lyu , Dong-ho Lee
发明人： Hyun-Joon Kim , Yi-yeol Lyu , Dong-ho Lee
IPC分类号： B01J31/22 , C07F17/00 , C08F12/04 , B01J31/00 , C07F7/00 , C07F7/28
CPC分类号： B01J31/146 , B01J31/1616 , B01J31/2295 , C07F17/00 , C08F12/04 , B01J2531/0205 , B01J2531/40 , B01J2531/46 , B01J2531/48 , C08F2410/03 , C08F4/65912 , C08F4/6592 , C08F4/65922 , Y10S526/943
摘要： An alkylene and/or silylene bridged binuclear metallocene catalyst for styrene polymerization is represented by the following formula (I): ##STR1## where M.sup.1 and M.sup.2 are the same or different transition metal of Group IVb of the Periodic Table; Cp.sup.1 and Cp.sup.2 are the same or different cyclopentadienyl; alkyl, alkoxy, silyl or halogen substituted cyclopentadienyl; indenyl; alkyl, alkoxy, silyl or halogen substituted indenyl; fluorenyl; or alkyl, alkoxy, silyl or halogen substituted fluorenyl, which is capable of .pi.-electron, .eta..sup.5 -bonding with M.sup.1 or M.sup.2 ; each of E.sup.1, E.sup.2 and E.sup.3, independently of one another, is a carbon atom or a silicon atom; m, p and q are integers of 0 to 15 and m+p+q.gtoreq.1; each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6, independently of one another, is a hydrogen, an alkyl, an aryl, an alkoxy or a halogen; X is a hydrogen, an alkyl, an alkoxy or a halogen; and n is 3. M.sup.1 and M.sup.2 may also be in cardin form by mixture of (I) with a compound which abstructs an X gray from each metal atom and substitution then with non-coordinating anions.
摘要翻译：用于苯乙烯聚合的亚烷基和/或亚硅烷桥连双核茂金属催化剂由下式（I）表示：其中M1和M2是周期表第IVb族的过渡金属相同或不同的过渡金属; Cp1和Cp2是相同或不同的环戊二烯基; 烷基，烷氧基，甲硅烷基或卤素取代的环戊二烯基; 茚基; 烷基，烷氧基，甲硅烷基或卤素取代的茚基; 芴基; 或与M1或M2键合的烷基，烷氧基，甲硅烷基或卤素取代的芴基，其能够π电子等; E1，E2和E3各自独立地为碳原子或硅原子; m，p和q是0至15的整数，m + p + q> / = 1; R 1，R 2，R 3，R 4，R 5和R 6彼此独立地为氢，烷基，芳基，烷氧基或卤素; X是氢，烷基，烷氧基或卤素; 并且n为3.M1和M2也可以通过（I）与从每个金属原子构成X灰的化合物的混合物以卡因形式，然后用非配位阴离子代替。

32. 发明授权

US5783715A Silylated ferrocenyldiphosphines, silylated ferrocenyldiphosphines bound to inorganic or polymeric organic supports and also metal complexes thereof, their preparation and uses 失效
标题翻译：甲硅烷基化二茂铁基二膦，与无机或聚合有机载体结合的甲硅烷基化二茂铁基二膦，以及它们的金属络合物，它们的制备和用途
公开(公告)号：US5783715A
公开(公告)日：1998-07-21
申请号：US767266
申请日：1996-12-13
申请人： Benoit Pugin
发明人： Benoit Pugin
IPC分类号： B01J31/16 , B01J31/22 , B01J31/24 , C07B53/00 , C07C213/08 , C07C231/18 , C07F7/08 , C07F17/02 , C08C19/26 , C08F8/42 , C08F12/00 , C08F16/02 , C08F16/38 , C08F18/02 , C08F20/12 , C08F30/08 , C08F36/00 , C08F116/06 , C08F212/00 , C08F216/00 , C08F216/06 , C08F216/38 , C08F218/02 , C08F218/04 , C08F218/08 , C08F220/10 , C08G18/83 , C08G63/68
CPC分类号： B01J31/1658 , B01J31/1608 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J31/2433 , B01J31/2476 , B01J31/248 , C07B53/00 , C07C213/08 , C07C231/18 , C07F17/02 , C08C19/26 , C08F8/42 , C08G18/838 , C08G63/68 , B01J2231/643 , B01J2531/0205 , B01J2531/0263 , B01J2531/822 , B01J2531/827 , B01J2531/842
摘要： The invention relates to ferrocenyldiphosphine ligands containing a silylene group, ferrocenyldiphosphines bound to inorganic or polymeric organic supports by this silylene group, their preparation and also their metal complexes with transition metals such as rhodium or iridium. The invention also relates to the use of these complexes for hydrogenating organic double or triple bonds, in particular olefinic double bonds and carbon-heteroatom double bonds. The complexes are particularly suitable for enantioselective hydrogenation using chiral diphosphines and prochiral unsaturated compounds.
摘要翻译：本发明涉及含有亚甲硅基的二茂铁基二膦配体，通过该亚甲硅基与无机或聚合有机载体结合的二茂铁基二膦，它们的制备方法以及它们与过渡金属如铑或铱的金属络合物。本发明还涉及这些配合物用于氢化有机双键或三键，特别是烯属双键和碳 - 杂原子双键的用途。配合物特别适用于使用手性二膦和前手性不饱和化合物的对映选择性氢化。

33. 发明授权

US5698755A Process for preparing aromatic olefins using palladacycle catalysis 失效
标题翻译：使用聚酰胺催化制备芳族烯烃的方法
公开(公告)号：US5698755A
公开(公告)日：1997-12-16
申请号：US493359
申请日：1995-06-21
申请人： Matthias Beller , Hartmut Fischer , Wolfgang Anton Herrmann , Christoph Brossmer
发明人： Matthias Beller , Hartmut Fischer , Wolfgang Anton Herrmann , Christoph Brossmer
IPC分类号： B01J31/12 , B01J31/24 , C07B37/04 , C07B61/00 , C07C2/86 , C07C15/44 , C07C15/50 , C07C22/08 , C07C25/24 , C07C25/28 , C07C37/11 , C07C39/20 , C07C39/24 , C07C43/20 , C07C45/68 , C07C47/52 , C07C49/20 , C07C49/76 , C07C63/64 , C07C67/343 , C07C69/618 , C07C69/73 , C07C69/732 , C07C69/734 , C07C69/738 , C07C201/12 , C07C205/06 , C07C205/34 , C07C209/68 , C07C211/44 , C07C255/50 , C07C303/22 , C07C303/30 , C07C309/29 , C07C309/65 , C07C315/04 , C07C317/14 , C07C2/68
CPC分类号： B01J31/2404 , B01J31/2447 , C07B37/04 , C07C45/68 , C07C67/343 , B01J2231/4261 , B01J2531/0205 , B01J2531/824 , B01J31/0235 , B01J31/04
摘要： The invention relates to a process for preparing monofunctional, bifunctional or polyfunctional aromatic olefins of the formula (I) ##STR1## by reaction of haloaromatics of the formula (II) ##STR2## with olefins of the formula (III) ##STR3## , wherein a palladium compound of the formula (IV) ##STR4## is used as the catalyst.
摘要翻译：本发明涉及通过式（Ⅳ）的式（II）的卤代芳族化合物的反应制备式（I）的单官能，双官能或多官能的芳族烯烃的方法。用作催化剂。

34. 发明授权

US5563308A Ferrocene diphosphines as ligands for homogeneous catalysts 失效
标题翻译：二茂铁二膦作为均相催化剂的配体
公开(公告)号：US5563308A
公开(公告)日：1996-10-08
申请号：US461349
申请日：1995-06-05
申请人： Felix Spindler , Amina Wirth-Tijani , Heidi Landert
发明人： Felix Spindler , Amina Wirth-Tijani , Heidi Landert
IPC分类号： B01J31/22 , B01J31/24 , C07B61/00 , C07C67/31 , C07C69/732 , C07C213/08 , C07C231/14 , C07C231/18 , C07C233/54 , C07F15/02 , C07F17/02 , C07C5/02 , C07F17/00
CPC分类号： C07F17/02 , B01J31/2291 , B01J31/2295 , B01J31/2409 , B01J31/2471 , C07C213/08 , C07C231/18 , C07C67/31 , B01J2231/643 , B01J2231/645 , B01J2531/0205 , B01J2531/822 , B01J2531/827 , B01J2531/842 , Y10S526/943
摘要： Compounds of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.8 alkyl, phenyl or phenyl which is substituted by 1 to 3 C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy groups; R.sub.2 and R.sub.3 are each independently of the other typically C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl, or C.sub.1 -C.sub.4 alkyl- or C.sub.1 -C.sub.4 alkoxy-substituted C.sub.5 -C.sub.12 cycloalkyl, or phenyl which is substituted by one to three identical or different members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen;R.sub.10 and R.sub.11 are identical and are typically C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.1 -C.sub.4 alkyl- or C.sub.1 -C.sub.4 alkoxy-substituted C.sub.5 -C.sub.12 cycloalkyl or phenyl which is substituted by 1 to 3 identical or different members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen; or R.sub.10 and R.sub.11 are different and are C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.1 -C.sub.4 alkyl- or C.sub.1 -C.sub.4 alkoxy-substituted C.sub.5 -C.sub.12 cycloalkyl, phenyl or phenyl which is substituted by 1 to 3 identical or different members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, and * denotes a stereogenic carbon atom, in the form of their racemates and diastereoisomers or mixtures of diastereoisomers.Rhodium and iridium complexes with these ligands are suitable for use as homogeneous enantioselective catalysts for the hydrogenation of prochiral compounds containing carbon double bonds or carbon/hetero atom double bonds.
摘要翻译：式I的化合物其中R 1是C 1 -C 8烷基，苯基或被1至3个C 1 -C 4烷基或C 1 -C 4烷氧基取代的苯基; R 2和R 3各自独立地为其它通常为C 1 -C 12烷基，C 5 -C 12环烷基，苯基或C 1 -C 4烷基 - 或C 1 -C 4烷氧基取代的C 5 -C 12环烷基或被一至三个相同或不同的选自由C 1 -C 4烷基，C 1 -C 4烷氧基或卤素组成的基团; R 10和R 11是相同的，并且通常是C 1 -C 12烷基，C 5 -C 12环烷基，C 1 -C 4烷基 - 或C 1 -C 4烷氧基取代的C 5 -C 12环烷基或被1至3个相同或不同的选自C1- C4烷基，C1-C4烷氧基或卤素; 或R 10和R 11不同，为C 1 -C 12烷基，C 5 -C 12环烷基，C 1 -C 4烷基 - 或C 1 -C 4烷氧基取代的C 5 -C 12环烷基，苯基或苯基，其被1至3个相同或不同的选自以下的基团取代： C1-C4烷基，C1-C4烷氧基或卤素，和*表示立体异构碳原子，以其外消旋体和非对映异构体的形式或非对映异构体的混合物。与这些配体的铑和铱配合物适合用作含碳双键或碳/杂原子双键的前手性化合物氢化的均匀对映选择性催化剂。

35. 发明授权

US5442020A Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers 失效
标题翻译：双金属茂金属铝氧烷催化剂体系及其在制备乙烯-α烯烃和乙烯-α烯烃非共轭二烯烃弹性体中的应用
公开(公告)号：US5442020A
公开(公告)日：1995-08-15
申请号：US298495
申请日：1994-08-30
申请人： Stephen C. Davis
发明人： Stephen C. Davis
IPC分类号： B01J31/14 , B01J31/22 , C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： B01J31/143 , B01J31/2295 , C08F10/00 , B01J2531/0205 , B01J2531/48 , C08F210/18 , C08F2410/03 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A catalyst system comprising certain bimetallic metallocenes and an alumoxane is provided together with a process for the preparation of high molecular weight ethylene-alpha olefin elastomers and ethylene-alpha-olefin nonconjugated diolefin elastomers wherein the requisite monomers are polymerized in the presence of the bimetallic metallocene/alumoxane catalyst system.
摘要翻译：提供包含某些双金属茂金属和铝氧烷的催化剂体系以及制备高分子量乙烯-α-烯烃弹性体和乙烯-α-烯烃非共轭二烯烃弹性体的方法，其中所需单体在双金属茂金属存在下聚合 /铝氧烷催化剂体系。

36. 发明授权

US5223631A Bimetallic complexes as catalysts in an oxidation process 失效
标题翻译：双金属络合物作为氧化过程中的催化剂
公开(公告)号：US5223631A
公开(公告)日：1993-06-29
申请号：US906576
申请日：1992-06-30
申请人： Cheu P. Cheng , Yaw H. Hwang , Ching C. Liu
发明人： Cheu P. Cheng , Yaw H. Hwang , Ching C. Liu
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22 , C07D301/06 , C07D303/04 , C07D303/08 , C07F15/02 , C07F15/06
CPC分类号： C07F15/065 , B01J31/2243 , C07D301/06 , C07D303/04 , C07D303/08 , C07F15/025 , B01J2231/72 , B01J2531/0205 , B01J2531/0238 , B01J2531/16 , B01J2531/82 , B01J2531/842 , B01J2531/845
摘要： Disclosed is an olefin epoxidation process that contacting an olefinically unsaturated substrate with oxygen in the presence of catalytic amount of a bimetallic complex under the reaction conditions such that the olefin is at least partially oxidized. The metals introduced in the bimetallic complex are independently selected from vanadium, chromium, manganese, iron, cobalt, nickel, copper, molybdenum, ruthenium, rhodium, palladium, tungsten, rhenium, osmium, iridum or platinum.
摘要翻译：公开了一种在催化量的双金属络合物存在下在反应条件下使烯属不饱和基质与氧接触的烯烃环氧化方法，使得烯烃至少部分被氧化。引入双金属络合物中的金属独立地选自钒，铬，锰，铁，钴，镍，铜，钼，钌，铑，钯，钨，铼，锇，铱或铂中的金属。

37. 发明授权

US5198563A Chromium compounds and uses thereof 失效
标题翻译：铬化合物及其用途
公开(公告)号：US5198563A
公开(公告)日：1993-03-30
申请号：US698515
申请日：1991-05-10
申请人： William K. Reagen , Brian K. Conroy
发明人： William K. Reagen , Brian K. Conroy
IPC分类号： B01J23/26 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , B01J37/02 , C07C2/32 , C07F11/00 , C08F10/00
CPC分类号： C08F10/00 , B01J23/26 , B01J31/1616 , B01J31/181 , B01J31/2208 , B01J31/2226 , B01J37/0203 , C07C2/32 , C07F11/005 , B01J2231/20 , B01J2531/0205 , B01J2531/62 , B01J31/143 , C07C2531/12 , C07C2531/22 , Y02P20/588
摘要： Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support to trimerize and/or polymerize olefins.
摘要翻译：通过形成铬盐，金属酰胺和电子对供体溶剂（例如醚）的混合物来制备新的含铬化合物，例如吡咯化铬。这些新颖的含铬或铬吡咯化合物可以无支撑的或负载在无机氧化物载体上以使烯烃三聚和/或聚合。

38. 发明授权

US4943644A Olefin and alkane oxidations, ruthenium carboxylate catalyst therefor and method of preparation thereof 失效
标题翻译：烯烃和烷烃氧化，其羧酸钌催化剂及其制备方法
公开(公告)号：US4943644A
公开(公告)日：1990-07-24
申请号：US274837
申请日：1988-11-23
申请人： Russell S. Drago , Shannon Davis
发明人： Russell S. Drago , Shannon Davis
IPC分类号： B01J31/04 , B01J31/22 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/36 , C07D301/08 , C07D303/04 , C07F15/00
CPC分类号： C07F15/0053 , B01J31/2239 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/36 , C07D301/08 , C07D303/04 , B01J2231/70 , B01J2531/0205 , B01J2531/821 , B01J2540/225 , C07C2101/14 , C07C2101/16
摘要： A method of oxidizing olefins or alkanes by contacting with oxygen and a catalyst composition of the formula:Ru.sub.3 O[OCO(CF.sub.2).sub.y CF.sub.3 ].sub.6 LWherein: Ru are reuthenium atoms having a formal oxidation state of +2 or +3,L is a neutral or anionic ligand,Y is an integer from 0 to 6, andx is an integer from 1 to 3; and an anion.
摘要翻译：通过与氧接触氧化烯烃或烷烃的方法和下式的催化剂组合物：Ru 3 O [OCO（CF 2）y CF 3] 6 L其中Ru是具有+2或+3形式氧化态的钌原子，L是中性或阴离子配位体，Y为0〜6的整数，x为1〜3的整数。和阴离子。

39. 发明授权

US4547595A Method of reactivating Group VIII anionic hydroformylation catalysts 失效
标题翻译：第VIII族阴离子加氢甲酰化催化剂的再生方法
公开(公告)号：US4547595A
公开(公告)日：1985-10-15
申请号：US600437
申请日：1984-04-16
申请人： Biau-Hung Chang
发明人： Biau-Hung Chang
IPC分类号： B01J31/16 , B01J31/20 , B01J31/40 , C07C29/16 , C07C45/49 , C07C45/50 , C07F15/00 , C07F15/02
CPC分类号： C07F15/025 , B01J31/20 , B01J31/4023 , B01J31/403 , B01J31/4053 , C07C29/16 , C07C45/49 , C07C45/50 , C07F15/0026 , C07F15/0053 , B01J2231/321 , B01J2531/0205 , B01J2531/821 , B01J2531/825 , B01J2531/842 , Y02P20/584 , Y10S502/514
摘要： A method of reactivating anionic Group VIII hydroformylation catalysts to maintain high selectivity towards linear products. In the process of manufacturing aldehydes and alcohols from olefins, hydrogen, carbon monoxide and a catalyst, the selectivity for linear products is extremely high when an anionic Group VIII catalyst is used. This selectivity, after prolonged use of a catalyst, falls off along with the turnover number. The catalyst is reactivated to increase the selectivity towards linear products as well as the turnover number by subjecting the catalyst to a reducing agent which is strong enough under treatment conditions to reduce the anionic Group VIII catalyst. Reactivation of anionic iron, ruthenium, osmium, and mixed transition metal complex catalysts are particularly described and claimed.
摘要翻译：一种使阴离子VIII族加氢甲酰化催化剂再活化以维持对线性产物的高选择性的方法。在从烯烃，氢气，一氧化碳和催化剂制备醛和醇的过程中，当使用阴离子VIII族催化剂时，线性产物的选择性非常高。长时间使用催化剂后，这种选择性随周转数而下降。通过使催化剂经受处理条件足够强的还原剂以还原阴离子VIII族催化剂，使催化剂再活化以提高对线性产物的选择性以及周转数。特别描述和要求保护阴离子铁，钌，锇和混合过渡金属络合物催化剂的再活化。

40. 发明授权

US3793355A Compounds of ruthenium 失效
标题翻译：钌的化合物
公开(公告)号：US3793355A
公开(公告)日：1974-02-19
申请号：US3793355D
申请日：1972-08-08
申请人： JOHNSON MATTHEY CO LTD
发明人： WILKINSON G
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07F9/02 , C07F15/00
CPC分类号： C07F15/0053 , B01J31/181 , B01J31/223 , B01J31/2404 , B01J2531/0205 , B01J2531/821 , C07F9/02
摘要： WHEREIN M1, M2 AND M3 ARE THE SAME OR DIFFERENT TRANSITION METALS SELECTED FROM THE SECOND OR THIRD SERIES OF THE PERODIC TABLE; X IS OXYGEN, SULPHUR, NITROGEN, PHOSPHORUS OR BORON; AN IS ANIONIC ELEMENT OR GROUP AND L1, L2 OR L3 ARE NEUTRAL OR ANIONIC LIGANDS.

M1M2M3XAN6L1L2L3

THIS INVENTION RELATES TO A COMPOSITION OF MATTER HAVING THE GENERAL FRMULA

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